SiO_2@Fe_3O_4@C胶体纳米颗粒的制备及其光学性质

制备了SiO_2@Fe_3O_4@C核壳结构颗粒,粒径可控,形貌均一.研究了在电场调控下,不同粒径,不同浓度的SiO_2@Fe_3O_4@C纳米颗粒悬浮液在不同溶剂下的光学性质,结果表明:150nm SiO_2@Fe_3O_4@C颗粒在质量分数10%浓度下得到的反射光谱可调节范围最宽,从735nm蓝移到540nm;随着颗粒悬浮液浓度的增加,反射光谱会整体蓝移.将粒径为150nm的粒子分散到不同的溶剂中,其电场响应性具有溶剂依赖性,溶剂折射率越大,反射波长越大.悬浮液的响应时间为150ms,当撤去电场后,悬浮液具有一定的回复性.     

Low reflectance sputtered vanadium oxide thin films on silicon

Vanadium oxide thin films on silicon (Si) substrate are grown by pulsed radio frequency (RF) magnetron sputtering technique at RF power in the range of 100–700 W at room temperature. Deposited thin films are characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) techniques to investigate microstructural, phase, electronic structure and oxide state characteristics. The reflectance and transmittance spectra of the films and the Si substrate are recorded at the solar region (200–2300 nm) of the spectral window. Substantial reduction in reflectance and increase in transmittance is observed for the films grown beyond 200 W. Further, optical constants viz. absorption coefficient, refractive index and extinction coefficient of the deposited vanadium oxide films are evaluated.     

X-ray photoelectron (XPS) and Diffuse Reflectance Infra Fourier Transformation (DRIFT) study of Ba0.5Sr0.5CoxFe1−xO3−δ (BSCF: x=0-0.8) ceramics

The X-ray photoelectron spectra (XPS) of sintered BSCF ceramics (Ba_0.5Sr_0.5Co_xFe_1-xO_3-δ,0≤x≤0.8) were measured at room temperature (RT). Peak areas of Fe_2p1, Fe_2p3, Fe_3p and Co_3p increased systematically with increasing cobalt concentration, while their binding energies (BEs) remained the same (723.3, 710.0, 55.0 and 60.9 eV, respectively). However, the BEs of lattice oxygen in O_1s (528.1 eV) and Ba_4d for the BaO bond (87.9V and 90.2 eV) increased with increasing cobalt concentration. The shoulder peak of Ba_3d/Co_2p increased from 778.0 to 778.7 eV, which implies that this peak can be attributed to another Ba XPS peak (described as Ba_2nd in this study) due to the overlapping area between barium cations and oxygen anions. The overall peak areas of Ba_4d increased up to x=0.4, and then decreased, which coincides with the behavior of the Diffuse Reflectance Infrared Fourier Transform (DRIFT) bands representing adsorbed CO₃²⁻ (νCO₃²⁻) and structurally bonded CO₃²⁻ (ν₂, ν₃) (800-1200 and 862/1433 cm⁻¹, respectively).     

A fluoride selective dipyrromethane-TCNQ colorimetric sensor based on charge-transfer

A colorimetric sensor based on dipyrromethane(donor)-7,7′,8,8′-tetracyanoquinodimethane (acceptor) charge-transfer compound depicts excellent selectivity for naked-eye as well as spectrophotometric determination of F⁻ even in co-existence with other halide ions (Cl⁻, Br⁻ and I⁻). The sensing mechanism is ascribed to the interrupted charge-transfer between donor-acceptor in the presence of F⁻. The sensing on solid support mimics the solution sensing process supported by the reflectance values. Thus this compound has potential for practical applications.     

Direct Solid-Phase Optical Measurements in Flow Systems: A Review

Measurements based on absorption, reflectance, or luminescence of molecular species or complex ions can be carried out directly on a solid support simultaneously to the retention of the analyte. The use of this strategy in flow-based systems is advantageous in view of the reproducible handling of solutions in retention and elution steps of the analyte. This approach can be exploited to increase sensitivity, minimize reagent consumption as well as waste generation, improve selectivity or for simultaneous determination based on selective retention or differences in sorption rates of the analytes. This review focuses on the main characteristics of direct solid-phase measurements in flow systems, including the discussion of advantages and limitations and practical guidelines to the successful implementation of this approach. Selected applications in diverse fields, such as pharmaceutical, food, and environmental analysis are discussed.     

遮光罩内壁蜂窝结构单元的双向反射特性

内壁蜂窝结构是决定遮光罩杂散光抑制性能的主要因素,掌握其各向异性辐射传输特性对遮光罩的杂散光分析和优化设计具有重要意义.针对蜂窝结构单元,建立辐射传输模型,导出了表面双向反射分布函数的离散表达式;通过蒙特卡罗法模拟蜂窝结构单元的辐射传输过程,分析了几何参量和涂层反射率对等效面反射特性的影响;根据模拟所得双向反射分布函数数据库,建立了用于遮光罩杂散光分析的蜂窝结构等效面的反射特性概率模型.分析结果表明,蜂窝结构对杂散光呈现很强的后向散射特征,等效面的反射特性概率模型与直接模拟结果符合很好,可用于遮光罩杂散光分析和设计.     

一维光子晶体的反射率特性

基于平面波展开法,设计九层一维光子晶体结构,通过改变结构中介质层的厚度,运用MATLAB编程计算一维光子晶体反射率特性,厚度差值变小时,不存在反射波的区域将增加变大。研究结果为一维光子晶体器件的设计提供理论参考。     

光谱测定黑河上游土壤有机质的预测模型

地面高光谱遥感光谱分辨率高,能详细地反映地物波谱特征;多光谱遥感时域宽,覆盖范围广,对较大时空区域的地物特征反演具有更大的优势。探求以不同反射率指标的土壤有机质含量预测模型,及其敏感波段,可以结合两种光谱数据的优点,为研究土壤有机质含量的时空变化规律提供新途径。本研究选取黑河上游223个土壤样品测定其有机质含量和高光谱曲线,应用原始光谱曲线反射率(λ)、倒数(REC)、倒数之对数(LR)、归一化(CR)和一阶微分(FRD)五种指标,采用逐步线性回归分析方法建立预测模型。通过统计检验,结果表明,以反射率指标为自变量的模型预测效果最佳,其相关系数(r)和均方根误差(RMSE)分别为：0.863和4.79。最优模型中得出的敏感波段有TM1内的474 nm、TM3内的636 nm和TM5内的1 632 nm。研究结果可为使用TM遥感数据反演黑河上游土壤有机质含量提供参考。     

四溴荧光黄反射散射光度法测定血清白蛋白

在pH=3.0的B-R缓冲介质中,人血清白蛋白(HSA)与四溴荧光黄(TBF)结合,形成TBF-HSA复合物并被石蜡微晶吸萃,以试剂空白参比,在555nm处产生一灵敏的反射散射吸收峰。HSA的浓度在0.0—1.2mg/L范围内与555nm处的反射散射吸收值呈良好的线性关系。方法对HSA的检出限为0.058mg/L,本方法灵敏,可用于人血清样品中蛋白质的测定。     

Plasmon–phonon contribution in the permittivity of ZnP2 single crystals in FIR at low temperatures

The permittivity model for ZnP₂ crystals has been determined by reflectance measurements in the far infrared region. The dielectric permittivity is presented in the framework of the Drude–Lorentz model containing both plasmon and phonon contributions for two polarizations of incident light (E||c and Ec) at different temperatures. The temperature dependence of the oscillator parameters has been determined as well.