Charge carrier decay and diffusion in organic–inorganic CH3NH3PbI3–xClx perovskite based solar cell

In recent years, organic–inorganic lead halides attracted widespread interest, mainly due to their impressive photoconversion properties and low‐cost solution processing. In this study, we employed small amplitude transient photovoltage and photocurrent spectroscopy to investigate charge transport and recombination properties of perovskite CH₃NH₃PbI_3–xCl_x solar cell under realistic light harvesting conditions (<1 sun). Cell structure resembles outlay commonly found in organic photovoltaics, with perovskite absorber being sandwiched between two thin layers of organic polymers. Tested device displayed high power conversion efficiency (10.3%), good fill factor and negligible hysteresis effect. Fundamental device parameters were characterized at various open‐circuit voltages (V_oc) by examination of small voltage and current perturbations created by the low intensity pulsed laser excitations. The obtained results exhibit long charge carrier lifetimes and fast charge transport over the full range of applied optical bias, as well as remarkable diffusion lengths exceeding 1 μm. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

A combined transient and steady state approach for robust lifetime spectroscopy with micrometer resolution

We present the combination of two complementary micro‐photoluminescence spectroscopic techniques operating in transient and steady state condition, respectively. Introducing the time domain into the well‐established micro‐photoluminescence mapping approach operating under steady state conditions demonstrates a distinct improvement of the robustness and reliability in the determination of charge carrier lifetime measured with micrometer spatial resolution. Lifetimes from 50 ns to above ms are accessible. We elaborate a calibration procedure and apply the combined all‐photoluminescence setup to high‐performance multicrystalline silicon. A lifetime image obtained from the established photoluminescence imaging technique is reconstructed from the microscopic map by considering lateral diffusion and optical blurring, revealing a more detrimental influence of small angle grain boundaries as well as a higher lifetime within grains as may be deduced from the standard imaging technique. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

Interphases in Polymer Solid-Contacts and Nanocomposites Probed by Positron Annihilation Lifetime Spectroscopy

At polymer-solid contacts with thermoplastic polymers, the chain characteristics can deviate from the bulk on a length-scale of several nanometer in the so-called interphase. Such an interphase depends on the interaction between respective macromolecule and substrate, and affects the free volume in the polymer. Here, we review our experiments on the characterization of the free volume by positron lifetime spectroscopy at planar and curved interfaces. For Teflon AF on silicon, we identify a layer of increased density, corresponding to an interphase width of some 10 nm. PEP based nanocomposites with functionalized silica show no interphase, whereas for functionalized POSS an interphase is detected.     

Influence of Gd doping on the absolute quantum efficiency and lifetime of EuxGd1-x（TTA）3phens

Absolute quantum yield （Ф） is one of the most important parameters to evaluate the potential of novel materials. Lanthanide complexes EuxGd1-x（TTA）3phens are synthesized with the ratio of Gd3＋ dopant concentration ranging from 10% to 90% to improve the absolute quantum yield. EuxGd1-x（TTA）3phens possess similar infrared and ultraviolet spectra, showing that they have similar molecular structures. The absolute emission quantum yields of EuxGd1-x（TTA）3phens are determined using a fluoromax-4 spectrofluorometer equipped with an integrating sphere. The fluorescence lifetimes of the EuxGd1-x（TTA）3phens are measured in the same experiment. It was found that both absolute quantum yields and fluorescence lifetimes of EuxGd1-x（TTA）3phens are of quasi-periodic variation with the change of the Gd3. dopant concentrations. The absolute quantum efficiency and fluorescence lifetime vary with respect to the Gd content in an opposite fashion, indicating that the rate of energy absorption by the EuxGd1-x（TTA）3phens and the conversion to light energy is critical for the absolute quantum efficiency. The radiative rate constant Kr and non-radiative rate constant Knr are calculated. The dependence of Kr and Knr on the Gd3＋ dopant concentrations is very similar to that of absolute quantum efficiency. The radiation rate constant Kr and absolute quantum efficiency have a linear relationship.     

Singlet relaxation dynamics and long triplet lifetimes of thiophene-coupled perylene diimides dyads: New insights for high efficiency organic solar cells

In the active layer of organic solar cells (OSCs), the lifetime of triplet excitons is one of the decisive factors in the diffusion length and therefore has important impact on the power conversion efficiency of the devices. Herein, we have investigated singlet excited state relaxation dynamics and their triplet exciton lifetimes of two thiophene-coupled perylene diimides (PDI) dyads (2PDI-Th and fused-2PDI-Th), in order to provide a unique explanation in depth on their different performances in OSC devices. From the transient absorption (TA) spectra, the singlet excitons of 2PDI-Th form excimers in the time scale of 1.5 ps. Then the excimers go into the triplet state via intersystem crossing (ISC). In fused-2PDI-Th, triplet excitons are generated directly from the singlet excited excitons via the efficient ISC. Density functional theory (DFT) calculations further support the formation of excimers. DFT results indicate that 2PDI-Th exhibits an H-typed molecular configuration which is beneficial to form the excimers, while fused-2PDI-Th gives a twisted X-shaped configuration in the optimized ground and excited state. In steady-state emission spectra, 2PDI-Th shows abroad and featureless spectral characteristics of the excimers with a decay time of 840 ps, which is much shorter than those of PDI (5.5 ns) and fused-2PDI-Th (3.3 ns). The triplet lifetime (67 μs) of fused-2PDI-Th is factor of 3 longer than that of 2PDI-Th (22 μs). These results demonstrate that ring-fused structure is an efficient strategy to eliminate excimer formation and prolong the lifetime of triplet excitons, which provides a new insight for design of optoelectronic molecules for high efficiency organic solar cells.     

Near‐Infrared Multipurpose Lanthanide‐Imaging Nanoprobes

Optical imaging plays a growing role in modern biomedical research and clinical applications due to its high sensitivity, superb spatiotemporal resolution and minimal hazards. Lanthanide‐doped nanoparticles (LDNPs), as a classical category of luminescent materials, exhibit promising photostability, near‐infrared (NIR)‐excited frequency up‐/down‐converting capabilities, emission fine‐tuning and multispectral features, which have greatly promoted the endeavors of deeper and clearer diagnostics in complex living conditions. This review focuses on the recent advances of LDNP‐based multipurpose imaging studies using upconversion, downshifting, lifetime, photoacoustic and multimodal nanoprobes in the NIR (650–1000 nm) and the second near‐infrared window (NIR‐II, 1000–1700 nm). The principle and design of various functional, activatable, multiplexing or multimodal lanthanide‐imaging nanoprobes (LINPs) as well as representative biophotonic applications are summarized in detail. In addition, the future perspectives and challenges for facilitating LINPs to clinical translations are discussed.     

Time resolved spectroscopy in laser grade organic dyes

Time resolved spectroscopy is discussed along with the theoretical and experimental methods used to measure the fluorescence lifetimes in various laser grade organic dyes. The role of solvents and their viscosities in the fluorescence life time is also discussed. Different photophysical parameters have been obtained in rigid and non-rigid dye molecules.     

Energy Levels and Band Intensities of Neodymium Organic Acid Complexes

Abstract

The optical absorption spectra of Nd³⁺ ion in glutamic, L-aspartic and maleic acids in UV-VIS and NIR regions have been recorded. From the spectral data thus obtained, various spectroscopic parameters are evaluated. The radiative lifetimes (γ_R) and branching ratios (β) for the excited states of Nd³⁺ ion in three acids have been computed. The relationship between the environment sensitive Judd-Ofelt parameter (ω₂) and the intensities of hypersensitive level (⁴G_5/2) is in good coincidence following the Judd-Ofelt theory.