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排序方式: 共有419条查询结果,搜索用时 15 毫秒
11.
F. Thibault K.A. Grabow C.I. Marcus L.A. Robertson M.C. Stoffel 《Journal of Molecular Spectroscopy》2009,256(1):17-2081
Theoretical and experimental values have been determined for the pressure broadening of the ν1 + ν3 band of acetylene by hydrogen and deuterium at 195 K, and experimental values of the pressure shifts have been determined. Theoretical values have been calculated on the basis of a recent potential energy surface using the close coupling scheme. We discuss the detailed contribution of the various rotational angular momenta of the perturbing gas and the ortho and para contribution to the total pressure broadening cross-sections. We give routes to circumvent the computational cost of such calculations. Experimental values have been measured using a tunable diode laser spectrometer assuming a Voigt line shape. These pressure broadening parameters are compared with measurements performed recently at room temperature and with present measurements performed at 195 K in the ν1 + ν3 band of acetylene. A satisfactory agreement is obtained with the present results and available ones at 295 K. 相似文献
12.
Thermal, structural and optical properties of Nd3+ ions in tellurite glass (TeO2-ZnO-Na2O-Li2O-Nb2O5) have been investigated. Differential thermal analysis revealed reasonably good forming tendency of the glass composition. FTIR spectra were used to analyze the functional groups present in the glass. Judd-Ofelt intensity parameters were derived from the absorption spectrum and used to calculate the radiative lifetime, branching ratio and stimulated emission cross-section of the 4F3/2→4I9/2, 11/2, 13/2 transitions. The quantum efficiency of the 4F3/2 level is comparable as well as higher than the typical value of the other tellurite based glasses. The decay from the 4F3/2 level is found to be single exponential for different concentrations of Nd3+ ions with a shortening of lifetime with increasing concentration. The experimental values of branching ratio and saturation intensity of 4F3/2→4I11/2 transition indicate the favourable lasing action with low threshold power. 相似文献
13.
利用北京同步辐射装置(BSRF)?3W1B光束线产生的单色软X射线分别测定了Al和Fe薄膜在L2?,3吸收边附近的光吸收截面.测量值与理论值比较在远离吸收边时偏差较小,并逐渐趋于一致,在吸收边附近有较大偏差,这主要归因于理论计算所采用的独立电子近似方法在吸收边附近是无效的.测量结果与若干文献中的实验结果也进行了对比.虽然由于光束线分辨率和高次谐波的影响,实验结果和理论结果在实验能区有一定的偏差,但测量结果说明用薄膜透过率测定金属薄膜光吸收截面的方法是可行的. 相似文献
14.
A theory has been given for the scattering of neutrons by anharmonic crystals, for which terms of the typeV
(3) (k
1j1; —k
1j1;o
j) which contribute to the sublattice displacements are not neglected. Using the standard perturbation theory in the interaction
picture or Green’s function method, an expression has been derived for the differential scattering cross-section which brings
in the shift and the width of the phonons in one-phonon energy exchange processes. It is shown that the sublattice displacements
will modify the phase factor arising from the scattering by any atom in the unit cell, and the Debye-Waller factor also gets
altered both by the sublattice displacements as well as by higher order terms arising from anharmonicity. It is shown that
the differential scattering cross-section contains a term linearly depending on the third order anharmonicity coefficientV
(3) (k
1j1;k
2j2;k
3j3) and neutron scattering by crystals should provide a useful method for evaluating the third order anharmonicity coefficients. 相似文献
15.
Nazakat Ullah 《Pramana》1976,7(5):316-318
An exact differential equation is given to evaluate the energy average of the scattering function. The advantage of the differential
equation as compared to the earlier methods based on series expansion is that one has to evaluate only single sums over the
complex poles of the S-matrix. Using Wigner’s semicircle law for the distribution of the real parts of the poles of the scattering
matrix, the earlier expression for the energy average of the scattering function is rederived. 相似文献
16.
: Multiple electron transfer processes are studied for Arq+n- Ne (q= 8, 9, 11, 12) collisions by using multi-parameter coincidence techniques. Various electron transfer processes are identified experimentally and the related cross-sections are measured. The dependence of transfer ionization cross-sections on the recoil charge states is compared with the results from the modified molecular classical overbarrier model. It is found that the modified model described the experimental results reasonably. 相似文献
17.
采用分子动力学方法模拟了固态氩的纳米变截面结构的导热性质,研究发现纳米变截面材料的热阻和热流的大小与方向都相关:当纳米结构沿热流的方向为渐缩时,纳米结构的热阻随热流的增加而增大,而当纳米结构沿热流的方向为渐扩时,纳米结构的热阻随热流的增加呈减小的趋势;当热流较大时,热流沿渐缩方向时的热阻明显大于热流沿渐扩方向时的热阻,但当热流较小时纳米变截面结构的热阻和热流方向的关系不大.最后依据热质的运动和传递理论的动能效应对该现象进行了分析解释. 相似文献
18.
脉动热管的毛细管结构和尺度效应实验研究 总被引:3,自引:0,他引:3
脉动热管的毛细管结构变化如何影响其性能是研究者关注的问题.本文对毛细管截面为正方形和正三角形,水力直径范围为1 mm左右的回路型脉动热管的传热性能进行了实验研究.结果表明,角管脉动热管的倾角变化时,底加热明显优于顶加热;三角形截面脉动热管的热阻比正方形截面脉动热管的热阻更低.脉动热管在水力直径为1.5 mm时比1mm时的性能要好.实验研究为理论分析打下了基础. 相似文献
19.
为探讨膨胀石墨作为3 mm波干扰材料的消光、散射特性及其影响因素, 基于有限长度、有限电导率圆柱状导体的电磁散射, 利用矩量法建立了膨胀石墨的消光、散射、吸收及后向散射截面(雷达散射截面RCS)的计算式. 运用Mathematica编程计算并分析了膨胀石墨长度、半径、电导率、磁导率等因素与膨胀石墨消光、散射、吸收截面及RCS的关系. 结果表明: 当膨胀石墨的长度为1.5 mm、半径为0.05 mm时, 具有较好的消光、散射效果; 适当增大膨胀石墨的电导率、磁导率, 有利于提高其消光、散射能力. 本研究为探索增强膨胀石墨干扰3 mm波效果的技术途径提供了有价值的参考.
关键词:
膨胀石墨
石墨层间化合物
消光截面
矩量法 相似文献
20.
本文假定等离子体局部压强梯度由理想磁流体高n气球模所限定,讨论了非圆截面环流器的最佳压强剖面。分析了椭圆及三角变形的效应,发现三角变形对提高稳定性很有利;q剖面对平均比压值及中心比压值都有强烈影响,而沿半径下降的q剖面对提高比压值很有利。 相似文献