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101.
F. Honda A.V. Andreev V. Sechovský Y. Homma Y. Shiokawa 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(3):313-318
Single crystals of U(Ni1-xPdx)2Si2 with x = 0.05, 0.09 and 0.135 have been grown. Magnetization and electrical resistivity measurements were performed in a wide range
of temperatures and magnetic fields in order to study stability of magnetic phases in the solid solutions between UNi2Si2 and UPd2Si2 with a special emphasis on the type of ground state. In UPd2Si2 the simple AFI-type antiferromagnetic structure of U moments is observed at low temperatures. UNi2Si2 adopts the uncompensated AF structure (UAF) with the + + - stacking of U moments along the c-axis and consequently this compound exhibits a spontaneous magnetization corresponding to 1/3 of the U moment. The substitution
of Pd for Ni leads to a rapid decay of the spontaneous magnetization. The evolution of magnetization and electrical resistivity
behavior with Pd doping is tentatively attributed to the coexistence of the AF-I and UAF phases in the ground state of U(Ni0.91Pd0.09)2Si2 and U(Ni0.865Pd0.135)2Si2. In this scenario, the volume fraction of the AF-I phase rapidly grows with Pd doping on account of the UAF. At lowest temperatures
an irreversible transition to the UAF phase is observed when a sufficiently high magnetic field is applied along the c-axis.
Received 28 March 2002 / Received in final form 8 August 2002 Published online 19 December 2002
RID="a"
ID="a"e-mail: sech@mag.mff.cuni.cz 相似文献
102.
The effect of the grain boundary microstructure on the anisotropy and coercivity was investigated in an HDDR Nd-Fe-B permanent
magnetic alloy. Considering the special microstructure of its magnetic powder grain, an anisotropic theoretical model influenced
simultaneously by the structure defect at the grain boundary and the exchange coupling interaction was put forward. The variations
of the structure defect factors based on the nucleation and pinning mechanism with 2r
0/lex (where r
0 and lex are the defect thickness and the length of exchange coupling, respectively) were calculated. The results show that the coercivity
mechanism of an HDDR Nd-Fe-B permanent magnetic alloy is greatly related to its microstructure defect at the grain boundary.
For a fixed lex, when 2r
0/lex < 1.67, the coercivity is controlled by the pinning mechanism; when 2r
0/lex > 1.67, it is determined by the nucleation mechanism. The coercivity reaches the maximum when 2r
0/lex = 1.67. The calculation result is consistent well with the experimental result given by Morimoto et al.
Supported by the National Natural Science Foundation of China (Grant No. 50671055) 相似文献
103.
Fundamental theory presented in Part (I)[8] is used to analyze anisotropic plane stress problems. First we construct the generalized variational principle to enter Hamiltonian
system and get Hamiltonian differential operator matrix; then we solve eigen problem; finally, we present the process of obtaining
analytical solutions and semi-analytical solutions for anisotropic plane stress problems on rectangular area. 相似文献
104.
The purpose of this paper is to investigate the interplay between the chemical shielding anisotropy and quadrupole interaction in MQMAS spectra.
in the compounds Na3Co(NO2)6 and trans-Co[(en2)(NO2)2]NO3 provides model systems for such an investigation. Furthermore, only few results have been reported on the application of the MQMAS method to a spin I=7/2. The possibilities of the MQMAS spectroscopy for determining the relative orientation of the two tensors and its advantage over previous techniques are discussed. Reported experimental spectra at different spinning speeds of Na3Co(NO2)6 are accurately reproduced by our theoretical simulations. The calculations are based on a recent approach, summarized in the present paper, which allows one to perform efficient simulations of MQMAS spectra including all interactions and their time-dependence throughout the experiment. This is necessary for calculating accurate MQMAS spectra including the spinning sideband pattern. In the case of trans-Co[(en2)(NO2)2]NO3 where the quadrupolar interaction and chemical shielding are stronger and their axes are non-coincident, the MQMAS spectrum is strongly distorted due to the unsufficient spinning speed and RF power. In this case, MAS at different spinning speeds is shown to provide valuable information. 相似文献
105.
There are two main contributions influencing the relative line intensities in a hyperfine pattern of a polycrystalline material:
1) Lattice vibrational anisotropy-Goldanskii-Karyagin effect (GKE) and 2) preferred orientation of the crystallites (texture).
We present the results of experiments and computer calculations of the line-intensity ratios for various orientation distributions.
The two competing effects are hard to distinguish from an experimental point of view, and this evaluation should enable one
to appreciate the magnitude of their respective contributions. A variety of textures is selected and discussed: For instance,
the interesting case where the GKE and the texture produce the same effect on the relative line intensities. Generally speaking,
it seems that in many qualitative discussions of quadrupole line asymmetries the influence of texture is underestimated, especially
for small deviations from randomness. Conversely, the asymmetry in the spectra is often explained by making the ad hoc assumption
of a GKE without realizing that this would require an unrealistic lattice vibration anisotropy.
This work was done in partial fulfillment of the requirement for the degree “Dr. rer. nat.”. 相似文献
106.
The functions of the main indices of refraction n(ν) and absorption κ(ν) of uniaxial thin polyethylene terephthalate films
have been calculated by the experimental spectra of frustrated total reflection of s-and p-polarized radiation in the 700–760-cm−1 range. The κo(ν) maximum falls at the the 727-cm−1 frequency and the maximum of κe(ν) falls at the the 724-and 732-cm− 1 frequencies.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 756–759, November–December, 2005. 相似文献
107.
Barzda V Ionov M van Amerongen H Gussakovsky EE Shahak Y 《Journal of fluorescence》2004,14(2):207-216
Circularly polarized luminescence (CPL) is a powerful technique to study the macroorganization of photosynthetic light-harvesting apparatus in vivo and in vitro. It is particularly useful for monitoring environmental stress induced molecular re-organization of thylakoid membranes in green leaves. The current study focuses on two questions which are important to perform and interpret such experiments: how does CPL depend on the excitation wavelength and how on the orientation of the granal thylakoids. CPL and circular dichroism (CD) of pea chloroplasts were complementarily applied when chloroplasts were either in suspension or trapped in a polyacrylamide gel (PAAG) after alignment in a magnetic field. In contrast to the CD spectrum, the CPL signal was found to be independent of the excitation wavelength in both the Soret and the Qy absorption region for chloroplasts in both suspension and PAAG. The improved resolution of luminescence measurements revealed a relatively small negative CPL band in addition to the previously described large positive band. No effect of photoselection upon excitation on the CPL spectra was detected. The CPL intensity at 690 nm at the edge of the granal thylakoids was found to be higher than at the face of the grana suggesting the CPL anisotropy. 相似文献
108.
We describe a new experiment for measuring homonuclear-decoupled anisotropic chemical shift patterns in doubly 13C-labeled compounds under magic-angle spinning. The experiment combines a pair of selective and non-selective 180 degrees pulses to suppress the 13C-13C scalar and dipolar interactions. This is combined with the recently developed SUPER technique to recouple the chemical shift anisotropy. Demonstrations on 13Calpha and 13CO-labeled amino acids and peptides show that accurate chemical shift powder patterns can be obtained. This permits the use of chemical shift anisotropy for conformational studies of suitably extensively 13C-labeled peptides and proteins. 相似文献
109.
V. A. Tolkachev 《Journal of Applied Spectroscopy》2001,68(2):308-313
It is shown that the magnetic fieldinduced optical activity in the luminescence of complex molecules in vapors in the presence of rotational anisotropy in the ensemble of luminescent molecules provides information also on the intramolecular orientation of the initiating dipole moments of transitions, including borrowed ones. The relationships between the rotational force of the optical activity and this orientation in the case of anisotropy induced by a linearly polarized exciting light are obtained. 相似文献
110.
Highly emissive Re(I) complexes, hydrophobic cis-Re(CO)2(c-dppene)(dpphen) and water-soluble cis-Re(CO)2(c-dppene)(SO3-dpphen) with a negative charge, were synthesized [where c-dppene is cis-(bis(diphenylphosphino)ethylene, dpphen is 4,7-diphenyl-1,10-phenanthroline, and SO3-dpphen is its disulfonate derivative]. These Re(I) complexes have significantly higher molar absorption in the 350- to 490-nm region compared to their tricarbonyl Re(I) counterparts and their emission spectra are similar to those of Ru(II) polypyridyl complexes. The luminescence lifetimes of these Re(I) complexes approach 10 s in the absence of oxygen in both aqueous and less polar solvents. The complexes have limiting anisotropy values exceeding 0.3. As both ligands, the diimine and the bidentate phosphine, can be modified by adding different substituents, it should be possible to make cis-Re(CO)2(diimine)(P-P) derivatives which are capable of labeling biomacromolecules for biochemical and biophysical studies. 相似文献