HELIX SENSE-SELECTIVE COPOLYMERIZATION OF TRIPHENYLMETHYL METHACRYLATE WITH CHIRAL ANIONIC INITIATORS

Optically active copolymers of pairs of three monomers, triphenyl (methyl methacrylate)and one or two pyridyl substituted methyl methacrylate homologues, were obtained by helix-sense-selective copolymerization using complexes of organolithium with chiral ligand as anionicinitiators in toluene at low temperature. The copolymers obtained with (-)-sparteine (Sp) and(S,S)-(+)-and (R, R)-(-)-2, 3-dimethoxy-1, 4-bis (dimethylamino) butanes((+)-and (-)-DDB) complexes of organolithium showed low optical activity, but PMP complex with N, N-diphenylethyleneamine monolithium amide (PMP-DPEDA-Li) was effective in synthesizingcopolymers of high optical rotation ([α]_D~(25) about+320～1370°)which were comparable to thoseof relative homopolymers with one-handed helical structure.     

利用预失真条纹校正PMP系统投影仪畸变的研究

依据摄像机畸变模型提出了一种投影条纹相位畸变校正方法来简化相位-高度映射关系.该方法首先通过投两套互相垂直的相移正弦条纹,以相位值代替投影仪像素坐标,将投影仪当成摄像机看待,标定出投影仪的内参量.然后根据标定出的投影仪镜头畸变参量对理想相位施加反向的畸变,在投影时反向畸变的光栅通过镜头畸变,又成为理想的光栅,从而简化了相位-高度映射关系.实验中,虽然由于测量误差的影响,校正后的投影仪径向畸变系数还是比原来小了1个数量级.     

Theoretical Studies on the Reaction Mechanism of Hydroxyl Radical with 1,1,1-Trichloroethane

Ab initio and density functional theory calculations have been carried out to investigate the reaction of hydroxyl radical (OH) and 1,1,1-trichloroethane (CH3CCl3). The potential energy surface has been given according to the relative energies calculated at the MP2/cc-pVTZ level after the spin projection (PMP2). Five reaction channels were identified and the intramolecular hydrogen bonding was observed in some transition state structures. The barrier heights and reaction enthalpies calculated for all possible channels show that the hydrogen abstraction channel is predominant kinetically and thermodynamically. The contribution from other channels was predicted to be minor.