波导管中微波波长测量方法的研究

基于微波测量线中驻波分布公式,采用测量驻波强度沿着 x轴分布的数据,拟合得到了波导管中微波的波长,不仅误差得到减小,而且可以绕过驻波比测量,用拟合参量计算微波反射率。     

基于光谱解调的对称波导型表面等离子体共振传感研究

表面等离子体共振(SPR)传感系统有角度谱、光谱、强度、相位等解调方式,其中光谱型的(SPR)传感系统因可以使用光纤导光,将传感部分独立出来,可进行远距离传感和现场检测,并能有效缩小系统的体积。对称光波导型(SOW)SPR因金属膜层两边的折射率完全相同,表面等离子体波传播距离更长,穿透深度更深,比传统的SPR系统具有更高的灵敏度和分辨率。对对称波导型(SOW)SPR进行光谱解调研究,以MgF₂-Au-MgF₂结构的SOW-SPR为传感单元,同时以光纤输出的卤素灯为光源, 搭建了一套光谱解调的SOW-SPR检测系统,以不同浓度的葡萄糖溶液对系统折射率分辨率进行测量,得到2.8×10-7 RIU的分辨率。为SOW-SPR系统小型化、现场检测以及远距离探测提出一种可能实现的手段,具有很好的应用前景。     

Formation of a crosslinked POSS network by an unusual hydrosilylation: Thermo‐oxidative stabilization of the α‐cristobalite phase in its amorphous regions

A semicrystalline inorganic–organic hybrid crosslinked network containing polyhedral oligomeric silsesquioxane (POSS) cores was constructed by the unusual hydrosilylation of the terminal vinyl groups of an internal acetylene‐containing silane linker by a POSS monomer. Products from the thermal treatments of this network in either argon or air at 250, 550, and 1000 °C, respectively, were characterized by Fourier transform infrared, Solid‐state ¹³C and ²⁹Si magic angle spinning NMR, X‐ray diffraction and XPS analyses. The highly symmetrically functionalized POSS silica clusters, in the fluorite silica phase, in the network were found to remain unchanged on thermal treatment possibly due to the shielding of the silica core by the functionalities and a cancellation of thermal stresses on the silica core. Stabilization of the metastable α‐cristobalite phase, which is typically formed on cooling by a β‐ to α‐transition of the β‐cristobalite phase formed above 1400 °C, was observed in the amorphous regions in the network sample treated only to 1000 °C in air. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012