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121.
Thin Ca films were evaporated on Si(1 1 1) under UHV conditions and subsequently annealed in the temperature range 200–650 °C. The interdiffusion of Ca and Si was examined by ex situ Auger depth profiling. In situ monitoring of the Si 2p core-level shift by X-ray photoemission spectroscopy (XPS) was employed to study the silicide formation process. The formation temperature of CaSi2 films on Si(1 1 1) was found to be about 350 °C. Epitaxial growth takes place at T≥400 °C. The morphology of the films, measured by atomic force microscopy (AFM), was correlated with their crystallinity as analyzed by X-ray diffraction (XRD). According to measurements of temperature-dependent I–V characteristics and internal photoemission the Schottky-barrier height of CaSi2 on Si(1 1 1) amounts to qΦBn=0.25 eV on n-type and to qΦBp=0.82 eV on p-type silicon. 相似文献
122.
以金属钇和异丙醇为原料,以HgCl2/I2为复合催化剂,通过对金属钇的机械加工以增加其比表面,并将异丙醇脱水使其含水量降低至0.05%,体系在82℃回流5h,经过滤、减压蒸馏,得到了白色海绵状异丙醇钇,其产率高达83%,合成时间比文献报道的缩短了19h,产率提高了8%。文章确定了催化剂的最佳用量为20gY加入60mg HgCl2/I2,研究了合成产率与HgCl2/I2催化剂和HgCl2催化剂的依赖关系及异丙醇中含水量对合成产率的影响,并对HgCl2/I2的催化作用机理进行了初步探讨。 相似文献
123.
Nuclear Magnetic Resonance (NMR) was used to investigate the extrusion behaviour of PTFE pastes in a ram extruder. By means
of 1H-NMR imaging (MRI) it is possible to determine the local proton density and therefore, the local fluid concentration. The
19F-MRI provides the local solid concentration. Thus the local saturation and the local porosity can be calculated with the
information of the local fluid and solid concentration. Furthermore displacement profiles can be derived from NMR images by
means of correlation techniques without any preparation or marking of the pastes.
Received: 8 May 2000 Accepted: 1 May 2001 相似文献
124.
A. M. Vinogradov 《Acta Appl Math》1989,15(1-2):3-21
The main notions and results which are necessary for finding higher symmetries and conservation laws for general systems of partial differential equations are given. These constitute the starting point for the subsequent papers of this volume. Some problems are also discussed. 相似文献
125.
Yevhen Zelenyuk 《Topology and its Applications》2006,153(14):2382-2385
We introduce the notion of a partially selective ultrafilter and prove that (a) if G is an extremally disconnected topological group and p is a converging nonprincipal ultrafilter on G containing a countable discrete subset, then p is partially selective, and (b) the existence of a nonprincipal partially selective ultrafilter on a countable set implies the existence of a P-point in ω∗. Thus it is consistent with ZFC that there is no extremally disconnected topological group containing a countable discrete nonclosed subset. 相似文献
126.
在充分调研和分析SN方法粒子输运计算程序自动建模方法的基础上,对建模过程中的模型文件格式识别、属性编辑、空腔处理及自动划分离散网格等关键技术问题进行了研究,并提出了合理可行的解决方法。通过对SNAM程序建模部分功能测试,验证了这些方法的正确性和有效性。This paper presents two approaches to enhance the geometry modeling ability of SN particle transport simulation codes and focus on the key issues that lie in the processing from CAD model to SN code geometry model, e.g. CAD file format support, void modeling, mesh generation and model-editing. SNAM (SN Automatic Modeling system) has been developed as an interface code between commercial CAD software and SN particle transport simmulation codes. The testing results have shown that the algorithm and implementation used in SNAM are efficient and capable of all the necessary processing from CAD model to SN geometry model. 相似文献
127.
(S)-2-[2-(p-Tolylsulfinyl)phenyl]acetaldehyde reacts with different O-silylated ketenethioacetals in the presence of Yb(OTf)3 yielding β-hydroxythioesters in high yields and diastereoselectivities. The obtained compounds were readily transformed into β-hydroxyacids and their corresponding diols. These Mukaiyama aldol reactions are a direct evidence of the ability of the sulfinyl group to control 1,5- and 1,6-asymmetric induction processes. 相似文献
128.
A Volterra type integral equation in a Hilbert space with an additional linear operator L and a spectral parameter depending
on time is considered. If the parameter does not belong to the spectrum of L unconditional solvability of the considered problem
is proved. In the case where the initial value of the parameter coincides with some isolated point of the spectrum of the
operator L sufficient conditions for solvability are established. The obtained results are applied to the partial integral
equations associated with a contact problem of the theory of elasticity. 相似文献
129.
M.F. Al-Kuhaili 《Journal of luminescence》2006,117(2):209-216
Thin films of sodium salicylate were deposited by spin coating from a solution prepared by dissolving sodium salicylate in methanol. The films were characterized by X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscopy, UV-visible spectroscopy and spectrofluorometry. The films were crystalline with a strong blue fluorescence peak at an emission wavelength of 419.3 nm. The influence of solution concentration, spin speed and annealing temperature on the fluorescence intensity was studied. Optimum results were obtained with a solution whose concentration was 2.5 M. It was found that lower spin speed resulted in higher fluorescence intensity. Moreover, the fluorescence intensity decreased as the annealing temperature was increased. The durability of the films over a period of 30 days was also investigated, and films annealed at higher temperatures were found to be less degraded with time. 相似文献
130.
GAO Jing ZHOU Xiaohua CHEN Xun Chongqing University Chemical Engineering Department Chongqing China 《Chinese Journal of Reactive Polymers》2006,(2)
1. INTRODUCTION In the process of coking plant, about 30%~35% sulfur is transformed to H2S and some other sulfide, which form impurity in coal gas together with NH3 and HCN. Only 0.1% H2S containing in air can lead to die, so it is very important to carry on desulphurization and decyanation with coal gas [1~3]. Currently desulphurization and decyanation craft technique have Dry Oxidation Technology, Wet Oxidation Technology and Liquid Absorption Technology [2] three main kinds. The… 相似文献