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31.
用射频等离子体方法在玻璃基底上制备的类金刚石(DLC)薄膜,采用离子注入法掺氮,并对掺氮DLC薄膜紫外(UV)辐照前后的性能变化进行了研究。研究结果表明:随氮离子注入剂量及UV辐照时间的增加,位于2 930cm-1附近的SP
3C-H吸收峰明显变小,而位于1 580cm-1附近的SP2C-H吸收峰则明显增强,薄膜的电阻率明显呈下降趋势;随UV辐照时间的增加,位于1 078cm-1附近的Si-O-Si键数量及位于786cm-1附近的Si-C键数量明显增加。即氮离子注入和UV辐照明显改变了DLC薄膜的结构与特性。 相似文献
32.
LI Shufeng LI Qian YANG Xinlin HUANG Wenqiang** State Key Laboratory of Functional Polymer Materials for Adsorption Separation Institute of Polymer Chemistry Nankai University Tianjin China 《Chinese Journal of Reactive Polymers》2004,(Z1)
1. INTRODUCTION The development of efficient polymer-supported catalysts has attracted much attention [1]. For obtaining polymeric catalysts, catalytically active groups were introduced onto polymers mostly by copolymerization of the appropriate monomers bearing the desired catalyticfunctionalities (e.g. imidazole, OH, and COOH) or by modification of preformed polymers.Another possibility involves the attachment of side chains, containing the desired arrangement of functional groups, o… 相似文献
33.
We give a criterion to decide if a given w-homogeneous derivation on A?k[X1,X2,X3] is locally nilpotent. We deduce an algorithm which decides if a k-subalgebra of A, which is finitely generated by w-homogeneous elements, is the kernel of some locally nilpotent derivation. 相似文献
34.
Phenomena accompanying electrochemical doping of solid fullerene films with potassium were studied by sputter ion depth profiling
(XPS and SIMS). The potassium distribution was determined, and artifacts associated with possible damage of the layer composition
caused by ion impact were investigated and discussed. To compare the charge transfer while reductive doping is taking place
at fullerene/solution interface with doping from gas phase, model layers were prepared and doped by potassium under UHV conditions.
It was found that sputtering by Ar+ primary ions yields both accurate information on the alkaline metal distribution and on its concentration. Sputtering by
O+ ions led to an enrichment of potassium, apparently due to the reactivity of oxygen with the fullerene matrix. It is shown
that the reductive doping starts at the fullerene/solution interface. The concentration of potassium in the doped films was
found to be lower than expected from the charge transferred during the electrochemical reduction. Other phase transformations
such as hydrogenation are discussed.
Received March 4, 2002; accepted July 26, 2002 相似文献
35.
36.
Hiromichi Kurosu Mizuyo Kikuchi Isao Ando 《Journal of Polymer Science.Polymer Physics》1995,33(5):769-775
The solid-state 15N CP/MAS NMR spectra and 15N spin-lattice relaxation times (T1) of doped and dedoped 15N-labeled polypyrroles prepared by electrochemical polymerization, have been measured by means of high-resolution solid-state 15N NMR. The 15N signal of polypyrrole consists of four peaks decomposed by line shape analysis. The four peaks obtained have been assigned to the various structures of polypyrrole. Further, the half-width of the 15N NMR spectra of polypyrroles is discussed as related to the electrical conductivity. © 1995 John Wiley & Sons, Inc. 相似文献
37.
Summary We prove convergence and error estimates in Sobolev spaces for the collocation method with tensor product splines for strongly elliptic pseudodifferential equations on the torus. Examples of applications include elliptic partial differential equations with periodic boundary conditions but also the classical boundary integral operators of potential theory on torus-shaped domains in three or more dimensions. For odd-degree splines, we prove convergence of nodal collocation for any strongly elliptic operator. For even-degree splines and midpoint collocation, we find an additional condition for the convergence which is satisfied for the classical boundary integral operators. Our analysis is a generalization to higher dimensions of the corresponding analysis of Arnold and Wendland [4]. 相似文献
38.
39.
A Pair of Dimeric Stilbene Epimers from Gnetum Montanum 总被引:1,自引:0,他引:1
GnetummontanumofgnetaceaisdistributedinsouthernChina.AsaChinesefOlkmedicine,itslianasareusedtotreatbronchitisandarthritis'.Previousinvestigationofthisspeciesledtotheisolationofsomealkaloidsanddibenzyletherde,i.ati.es2.lnourstudies,tenknowncomponentsincludingresveratrol,isohapontigenin,daucosterol,6-sitosterol,stearicacid,gnetifolinE,gnetol,isorhapontigenin-3-O-6-glucopyra(-)E-viniferinandgnetifolinCwereisolatedfromthesameresource.Atthesametime,apairoftraceepimerswereobtained.Thisisthefirste… 相似文献
40.
In this paper, we present a numerical scheme for solving the coupled system of compressible miscible displacement problem in porous media. The flow equation is solved by the mixed finite element method, and the transport equation is approximated by a discontinuous Galerkin method. The scheme is continuous in time and a priori hp error estimates is presented. 相似文献