Simple model for the ionization of helium atoms by fully and partially stripped ions in the strong interaction region

Theoretical calculations employing the modified over-barrier model to investigate single and double ionization cross sections of helium in collisions with highly charged ions are presented in the strong perturbation region. It shows the velocity and charge state dependences of cross sections, which coincides with the available experimental data. In order to determine the reliability of this model for partially stripped projectiles, the cross-section ratios have been measured for CZp+, OZp+-He (Zp=1-4) by the coincidence technique in the velocity range of 1-4.5 a.u. The calculated results are approximately in agreement with the experimental data.     

Diffusivity of adatoms on plasma-exposed surfaces determined from the ionization energy approximation and ionic polarizability

Microscopic surface diffusivity theory based on atomic ionization energy concept is developed to explain the variations of the atomic and displacement polarizations with respect to the surface diffusion activation energy of adatoms in the process of self-assembly of quantum dots on plasma-exposed surfaces. These polarizations are derived classically, while the atomic polarization is quantized to obtain the microscopic atomic polarizability. The surface diffusivity equation is derived as a function of the ionization energy. The results of this work can be used to fine-tune the delivery rates of different adatoms onto nanostructure growth surfaces and optimize the low-temperature plasma based nanoscale synthesis processes.     

Non-existence of a minimizer to the magnetic Hartree-Fock functional

In the presence of an external magnetic field, we prove absence of a ground state within the Hartree-Fock theory of atoms and molecules. The result is established for a wide class of magnetic fields when the number of electrons is greater than or equal to 2Z + K, where Z is the total charge of K nuclei. Positivity properties are instrumental in the proof of this bound for the maximal ionization.      

Determination of ionization constants of saccharides by capillary zone electrophoresis with amperometric detection

Summary A method based on a linear model enabling the efficient determination of the ionization constants (K _a) of saccharides by capillary zone electrophoresis with amperometric detection has been demonstrated. TheK _a values obtained from the plots of the reciprocal effective mobility against the inverse concentration of sodium hydroxide were in agreement with literature values.     

紫激光作用下四甲基硅的MPI和硅原子的(1+1)电离

本文利用平行板电极装置及飞行时间质谱仪相结合的方法对四甲基硅进行了多光子电离光谱及飞行时间质谱的研究得到了激光激发波长在390.6nm处硅原子的一个单光子共振峰,获得了该分子在这个波长点处的飞行时间质谱,并据此讨论了四甲基硅MPI可能的机理.     

Freeman离子源的特性与改进研究

此文简要叙述用于离子束材料改性装置的Ｆｒｅｅｍａｎ离子源的特性，其主要参数：灯丝电流、孤压、磁场、气流量和吸极电压与引出离子束流强的关系。对源体内部因微漏冷却水（真空度由３．９×１０－４降至４．２×１０－４Ｐａ）致使气体分子电离、起弧困难和等离子体不稳作了实验研究；对灯丝与弧室间的氮化硼绝绝物上沉积被溅射出的Ｗ、Ｍｏ原子导致绝缘下降、灯丝寿命缩短进行了部份结构改进。结果表明，提高加工工艺，确保真空系统密封性能和输入气体纯度对弧室内气体分子碰撞电离和等离子体的稳定至关重要；在ＢＮ绝缘物上放置钼制屏蔽罩有效地屏蔽掉Ｗ、ＭＯ原子沉积使灯丝寿命延长一倍，达到了４０小时。     

Crosstalk between two-photon and two-color (two-photon) excitation in optical beam induced current generation with two confocal excitation beams

We analyze the influence of residual two-photon excitation (2PE) in two-color (two-photon) optical beam induced current (2CE-OBIC) generation in wide band gap semiconductor samples. 2CE-OBIC generation is accomplished with two confocal excitation beams of separation angle θ and wavelengths λ₁ and λ₂ where , λ_e = hc/E_b, h is the Planck’s constant, c is speed of light in vacuum, and E_b is the energy band gap. Because the conduction band of the sample is a continuum, at least one excitation beam would also contribute an undesirable 2PE-OBIC signal that degrades the signal-to-noise ratio of the measured 2CE-OBIC response and broadens the effective OBIC distribution in the sample particularly when θ ≠ 0 or π. We show that the deleterious effects of crosstalk are reduced by a careful selection of λ₁ and λ₂ and the relative excitation beam intensities. λ₁ and λ₂ should be chosen to minimize the ratio of the two-photon absorption coefficients (β₁, β₂) to the 2CE absorption coefficient β₁₂ or at least satisfy the constraint: β₁ + β₂  β₁₂. Keeping the two excitation intensities equal is beneficial only when β₁ = β₂. Otherwise, it is advantageous to bias the intensity ratio towards the wavelength with a lower 2PE absorption coefficient.     

Solving Multiphoton Jaynes–Cummings Model with Field Nonlinearity by Supersymmetric Unitary Transformation

We introduce a supersymmetric unitary transformation, to diagonalize the multiphoton Jaynes–Cummings model Hamiltonian based on supersymmetric quantum mechanics theory, that includes any forms of intensity-dependent coupling and field nonlinearity. On doing so, we obtain its eigenvalue and eigenstates, and the time evolution of state vector.     

金激光等离子体冕区电离态特性研究

 提出一种测量金激光等离子体电荷态分布与平均电离度的X射线光谱学诊断方法。该方法基于稳态碰撞-辐射近似，考虑电子离子直接碰撞激发与双电子复合两种激发态布居方式，建立了金M带5f-3d跃迁组辐射总强度与离子态分布的耦合方程。根据实验测量的金平面靶激光等离子体冕区辐射的5f-3d跃迁线系的强度分布，诊断得到了金激光等离子体的电荷态分布与平均电离度。此外，还分析了电子温度、电子密度以及双电子复合过程对电荷态分布及平均电离度诊断的影响，并将实验诊断结果与辐射流体力学理论模拟结果及离化平衡动力学计算结果进行了对比分析。结果表明：实验诊断结果与基于CRE近似的离化平衡动力学计算结果近似；当电子温度高于1.5 keV时，双电子复合过程对电离度的诊断结果影响较小。     

飞秒脉冲作用下氯丙烯的多光子解离和电离动力学

The dissociation and photoionization dynamics of C₃H₅Cl were studied at 200, 400, and 800 nm with femtosecond laser pulses. The time-of-flight mass spectra, laser power index and photoelectron images were recorded. At short wavelength (200 nm), ionization of the parent molecule was found to be the dominant channel, while other ions were generated by the dissociation of C₃H₅Cl⁺. With the shift to long wavelength (e.g., 800 nm), fragment ions became dominant, and were generated through the multiphoton ionization of neutral fragments after the photodissociation of C₃H₅Cl. These results imply that photodissociation plays a significant role at long wavelength, because neutral fragments are supposed to be generated from the intermediate states reached by 800 nm photons. At 400 nm, the dissociation on the intermediate states is also critical, but is not as high as that at 800 nm. Taken together, our results demonstrate that the dissociation/ionization behaviors of allyl chloride are wavelength-dependent, and reveal the complex dynamics of allyl chloride at 200, 400 and 800 nm.