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41.
V. V. AntiĆ M. P. AntiĆ M. N. Govedarica P. R. DvorniĆ 《Journal of polymer science. Part A, Polymer chemistry》2007,45(11):2246-2258
The kinetics of the formation of poly(carbosiloxane), as well as of alkyl-substituted poly(siloxane), by Karstedt's catalyst catalyzed hydrosilylation were investigated. Linear poly(carbosiloxane), poly[(1,1,3,3-tetramethyldisiloxanyl)ethylene], (PTMDSE), was obtained by hydrosilylation of 1,3-divinyltetramethyldisiloxane (DVTMDS) and 1,1,3,3-tetramethyldisiloxane (TMDS), while alkyl-substituted poly(siloxane), poly(methyldecylsiloxane), (PMDS), was synthesized by hydrosilylation of poly(methylhydrosiloxane) (PMHS) and 1-decene. To investigate the kinetics of PTMDSE formation, two series of experiments were performed at reaction temperatures ranging from 25 to 56 °C and with catalyst concentrations ranging from 7.0 × 10−6 to 3.1 × 10−5 mol Pt/mol CHCH2. A series of experiments was performed at reaction temperatures ranging from 28 to 48 °C, with catalyst concentrations of 7.0 ×10−6 mol of Pt per mol of CHCH2, when kinetics of PMDS formation was investigated. All reactions were carried out in bulk, with equimolar amounts of the reacting Si H and CHCH2 groups. The course of the reactions was monitored by following the disappearance of the Si H bands using quantitative infrared spectroscopy. The results obtained showed typical first order kinetics for the PTMDSE formation, consistent with the proposed reaction mechanism. In the case of PMDS an induction period occurred at lower reaction temperatures, but disappeared at 44 °C and the rate of Si H conversion also started to follow the first-order kinetics. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2246–2258, 2007 相似文献
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43.
给出目标信息系统学习的多准则决策方法,建立多准则决策的规则学习模型,讨论该模型的性质。该模型优于Z.Pawlak方法,将规则提取与信息融合为一体。也优于AHP等模型,具有简洁性.通过实例计算,取得了满意结果。 相似文献
44.
范跃祖,宁文如,刘剑.光纤陀螺随机误差的滤波方案的探讨.数理统计与管理,1997,16(4),29~32.光纤陀螺是新一代的光学陀螺仪,它的性能决定着惯性参照系统的精度。光纤陀螺的误差分为两大类。一类是有规律的,另一类是随机的。本文提出了两种新的用于光纤陀螺随机误差补偿的Kalman滤波方案,考虑了两种随机模型:(Ⅰ)角速度变化为等随机的;(Ⅱ)角速度变化为等随机加速的。仿真结果表明,第二种方案对噪声起到了很好的抑制作用和滤波效果 相似文献
45.
聚醚醚酮链结构与反应的模型化合物的量子化学研究 总被引:1,自引:1,他引:0
利用AM1方法对聚醚醚酮模型化合物全优化,结果为:芳环平均相互扭转角为33.0度,桥键角117.0-118.0度,其分子结构拓扑图形表明:所有苯环(核)为平面构型,但其内角扭曲;其氢原子对苯环构型无实质性贡献,在更长链的计算中,冻结苯核与氢原子也得出满意结果,根据Mulliken键序与电荷讨论了醚交换与磺化反应。 相似文献
46.
47.
Dichang Zhang 《Journal of Thermal Analysis and Calorimetry》1995,45(1-2):141-150
A cracking catalyst designatedSRNY was manufactured from a commercialSRNY molecular sieve (M.S.). The support consisted of kaolin, clay and SiO2. The coking behaviour of theSRNY M.S., the support and the catalyst were examined with light diesel oil (LDO) as feedstock in a microreactor. The physico-chemical properties of both fresh and aged samples, subjected to or not subjected to the cracking reaction ofLDO, were sequentially characterized by means of pore structure determination and thermal analysis. The pore structure included the specific surface area and the pore volume or porosity. Thermal analysis methods used included TG and DSC. The results indicated that all coked samples exhibited obvious changes in surface pore structure and acidity in comparison with non-coked samples. Their specific surface area and acid amount decreased with increase in the coke content of the samples. The apparent activation energy data obtained from decoking samples in an air flow, using the temperature-programmed oxidation (TPO) method, showed that the kinetic parameters of theSRNY M.S. differed from those of theSRNY catalyst and its support. 相似文献
48.
用紧耦合方法研究C4+和O6+与He原子碰撞 总被引:2,自引:0,他引:2
用双中心原子轨道紧耦合方法计算了C4+-He以及O6+-He碰撞的单俘获总截面,入射离子的能量范围为10~100keV/amu,所得计算结果在实验误差范围内与实验值很好符合.对满壳层入射离子,研究了单俘获截面随入射离子电荷态的变化,并讨论了原子轨道展开波函数数目对计算结果的影响.p 相似文献
49.
M. H. Sadr S. Astaraki S. Salehi 《Archive of Applied Mechanics (Ingenieur Archiv)》2007,77(11):795-807
In developing a neural network technique for a finite element model updating, researchers have been shown that the number
of training samples and their quality, significantly affect the accuracy of the NN predication. In this study, based on the
genetic algorithm (GA) method, we reduce the number of analyses required to develop the training pairs and reduce the amount
of time for training the NN. In the other words, a uniform distribution of design points inside the design space will be obtained
by means of this approach. To validate the efficiency of GA sample selection, random generation (RG) method is used for comparison.
Two comparisons are made based on a numerical and experimental example. One is updated from 10 degrees of freedom lumped parameters
system and the other is updated from a free–free beam using test data. The results indicate that the GA sample selection can
reduce the number of training samples without affecting the accuracy of the NN predication. In our present study, also, the
advantages of using frequency response function (FRF) data as input to the NN are kept and the drawback of having too many
frequency points is overcome by the application of principal component analyses (PCA). 相似文献
50.