三核铁甲酸簇合物[Fe_3(μ_3-O)(μ-O_2CH)_6(H_2O)_2(O_2CH)]·2H_2O在乙炔、水汽体系中的反应行为

本文研究了[Fe_3(μ_3-O)(μ-O_2CH)_6(H_2O)_2(O_2CH)]·2H_2O(简称)在乙炔、水汽体系中的反应行为。发现当温度高于220℃,脱落部分配体的具有活化乙炔进行加成反应的性能。采用原位红外光谱法和气相色谱法对此反应过程进行了跟踪探索,报道了产物的定性及半定量结果。     

The p-Blocks of the Mackey Algebra

Let p be a prime number. This paper describes the primitive idempotents and prime spectrum of the crossed Burnside algebra of a finite group over a p-local ring. The main application is a formula for the block idempotents of the p-local Mackey algebra of the group, in terms of the corresponding bloks of the group algebra.     

Dynamics of Backscattering of Human Tissue on Exposure to a Low-Intensity Optical Radiation

The results of in vivo experiments on the spectral response of a human organism to the action of low–intensity optical radiation are presented. The dynamics of backscattering of diagnostic radiation in infrared and red spectral regions was recorded. The characteristic types of response to exposure have been revealed: a sudden increase or decrease in the value of the relative coefficient of backscattering accompanied by saturation.     

Eu(p-PBA)_3phen1/2H_2O的高分辨光谱和Raman光谱Eu(p-PBA)3phen1/2H2O的高分辨光谱和Raman光谱*张颖唐波金林培(北京师范大学化学系,北京100875)吕少哲黄世华(中国科学院激发

配合物Ｅｕ（ｐ－ＰＢＡ）３ｐｈｅｎ１／２Ｈ２Ｏ（ｐ－ＰＢＡ：对苯基苯甲酸酸根离子；ｐｈｅｎ：邻菲咯啉）在紫外光激发下，能发出很强的红色荧光．以Ｅｕ（Ⅲ）离子为光谱探针，７７Ｋ下测得其高分辨激发和发射光谱，选择激发配合物的５Ｄ０能级，得到两组不同的发光光谱，表明配合物中Ｅｕ（Ⅲ）离子有两种不同的化学环境．配合物的喇曼光谱中，羧基阴离子的反对称伸缩振动和对称伸缩振动谱带是明显分裂和带肩峰的宽带，说明配合物中羧基同时存在多种配位方式     

Study of absorption spectra of gasolines and other hydrocarbon mixtures in the second overtone region of the CH<Subscript>3</Subscript>, CH<Subscript>2</Subscript>, CH groups

We have obtained experimental and model absorption spectra for individual hydrocarbons (toluene, benzene, n-heptane, and iso-octane) and their mixtures in the near IR range (λ = 1080–1220 nm). We model the spectra of nonsynthetic gasolines obtained under the same conditions by combining the spectra of three pure hydrocarbons. We show that the octane number of the studied gasoline is linearly related to the toluene (or benzene) concentrations in the model mixture. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 2, pp. 157–161, March–April, 2007.     

铯原子蒸气薄池中的透射光谱

对单光束通过蒸气薄池中的铯原子6S1/2→6P3/2跃迁的透射光谱进行了实验研究，其透射光谱呈现出亚多谱勒特性。利用频率调制技术提高信号的灵敏度，同时研究了激光强度对信号的影响。     

Absolutely continuous spectrum of Schrödinger operators with potentials slowly decaying inside a cone

For a large class of multi-dimensional Schrödinger operators it is shown that the absolutely continuous spectrum is essentially supported by [0,∞). We require slow decay and mildly oscillatory behavior of the potential in a cone and can allow for arbitrary non-negative bounded potential outside the cone. In particular, we do not require the existence of wave operators. The result and method of proof extends previous work by Laptev, Naboko and Safronov.     

高温高压下SrB4O7：Eu2+玻璃的晶化

 利用X射线衍射和Eu²⁺发射光谱方法研究了非晶玻璃SrB₄O₇在高温高压下的晶化。结果表明：在5.0 GPa压力下，200 ℃仍为玻璃态，只有几个强度极低的小峰，表明有晶化的迹象；600 ℃时已基本晶化，但为SrB₄O₇正交相与SrB₄O₇高压立方相二相共存；当温度提高到1 000 ℃时，晶化成了近单相的与常压SrB₄O₇粉末晶体相同的正交结构。伴随晶化度的加强，Eu²⁺发射强度增强，与Ｘ射线衍射结果相一致。     

宽带光纤耦合器的特性研究

应用局部耦合模理论，对非对称臂宽带光纤耦合器熔锥的形成及耦合发生过程作了较为精确的分析，计算得出了这类耦合器的熔锥特性曲线及光谱特性曲线，本文理论的进一步简化可得到一个特例，它与其它文献所用理论一致     

多元探测器在玫瑰扫描红外亚成像系统中的应用

玫瑰扫描红外亚成像系统是利用玫瑰扫描机构和红外单元探测器构成的一种亚成像系统。提出了一种利用多元小面阵来替代单元探测器的红外亚成像系统 ,可以提高成像系统的空间分辨率和帧频。分析了系统的原理 ,并给出了系统的构成框图。此外 ,就玫瑰扫描成像系统中应用多元探测器可能出现的问题进行了讨论 ,并提出了解决方案。结果表明 ,这种多元小面阵玫瑰扫描成像系统的成本远低于焦平面阵列探测器红外成像系统 ,在性能改善后是诸如末制导炮弹等低成本应用场合的理想红外成像系统