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991.
Reactivity ratio is a traditional parameter quantifying the reaction kinetics in copolymerization, which is important for potentially controlling microstructures of polymers and guiding the copolymerization process. Our recent experiments using tube-NMR technique enable us to in situ monitor the concentration profiles of the co-monomers during the anionic copolymerization process. This motivates us to revisit the Mayo-Lewis(ML) equation, which is the basis for derivation of reactivity ratio and has been extensively utilized in addition copolymerization. We found that although an explicit ML expression is desirable for ease of calculation and correlation with experimental data, it fails in our anionic copolymerization experiment as well as some data available in the literature. The origin is ascribed to the validity of the steady state assumption which is essential in the ML equation. This assumption can be released in anionic copolymerization and replaced by the fact that the overall concentration of the living chain ends keeps constant throughout the copolymerization. Alternative numerical method has been utilized to obtain the rate constants and consequently the reactivity ratios. Our work suggests that the ML equation should be applied with caution. 相似文献
992.
Speech intelligibility in classrooms affects the learning efficiency of students directly, especially for the students who are using a second language. The speech intelligibility value is determined by many factors such as speech level, signal to noise ratio, and reverberation time in the rooms. This paper investigates the contributions of these factors with subjective tests, especially speech level, which is required for designing the optimal gain for sound amplification systems in classrooms. The test material was generated by mixing the convolution output of the English Coordinate Response Measure corpus and the room impulse responses with the background noise. The subjects are all Chinese students who use English as a second language. It is found that the speech intelligibility increases first and then decreases with the increase of speech level, and the optimal English speech level is about 71 dBA in classrooms for Chinese listeners when the signal to noise ratio and the reverberation time keep constant. Finally, a regression equation is proposed to predict the speech intelligibility based on speech level, signal to noise ratio, and reverberation time. 相似文献
993.
This paper characterized the observed low frequency acoustic signals generated by rock falls, thunderstorm, and wind turbulence in large rocky landslide. A digital infrasonic recording system was deployed on site to capture real-time low frequency acoustic signals associated with rock falls. An advanced non-stationary signal analysis method, i.e. Empirical Mode Decomposition (EMD), was applied to get insight to the characteristics of the low frequency acoustic signals induced by the hazards. Joint time–frequency distribution spectra technique was used to detect distinctive features of the events. The study shows that the low frequency acoustic signals can be excited by rock falls, thunderstorm and wind turbulence in the field environment, but the signal varies in both time domain and frequency domain with different patterns depending on the physical processes. The results demonstrated that the EMD-based signal processing technique is capable of extracting distinctive features to differentiate acoustic signals in real environment. 相似文献
994.
Polyetherimide hybrid films containing 5–40% silica were prepared through a sol-gel process and thermal imidization by using methyltriethoxysilane as precursor of the inorganic network and a poly(amic acid) resulting from polycondensation reaction of 2,2-bis[4-(4-aminophenoxy)phenyl]propane with 2,2-bis[(3,4-dicarboxyphenoxy)phenyl]propane dianhydride. The properties of these films, morphology, water vapor sorption capacity, free surface energy, mechanical, thermal and electrical characteristics, were studied. The films exhibited good thermal stability, having an initial decomposition temperature above 470 °C and glass transition temperature in the range of 187–200 °C. They showed low dielectric constant and low dielectric loss in a large frequency field. Gas permeation tests using small molecules (He, N2, O2 and CO2) at 6 bar and 30 °C indicated that the hybrid films containing higher silica content showed higher permeability for all the tested gases. 相似文献
995.
A trifluoroacetic acid derivatization combined with 1H NMR spectroscopy method for determining the molar ratio of primary, secondary, and tertiary amines in small molecules and polymers was discussed. Amines reacted with trifluoroacetic acid to form their salts RNH3+, R2NH2+, and R3NH+. The 1H NMR signals of these protonated amines (NH3+, NH2+, and NH+) were separated well in the spectra. Based on the integration of these protonated amine signals, the molar ratio of primary, secondary, and tertiary amines can be calculated. 相似文献
996.
Flexible and lead-free piezoelectric nanocomposites were synthesized with BaTiO3 nanowires (filler) and poly(vinylidene fluoride) (PVDF) (matrix), and the piezoelectric performances of the composites were systematically studied by varying the aspect ratio (AR) and volume fraction of the nanowire and poling time. BaTiO3 nanowires with AR of 18 were synthesized and incorporated into PVDF to improve the piezoelectric performance of the composites. It was found that high AR significantly increased the dielectric constant up to 64, which is over 800% improvement compared to those from the composites containing spheroid shape BaTiO3 nanoparticles. In addition, the dielectric constant and piezoelectric coefficient were also enhanced by increasing the concentration of BaTiO3 nanowires. The piezoelectric coefficient with 50-vol% BaTiO3 nanowires embedded in PVDF displayed 61 pC/N, which is much higher than nanocomposites with spheroid shape BaTiO3 nanoparticles as well as comparable to, if not better, other nanoparticle-filled polymer composites. Our results suggest that it is possible to fabricate nanocomposites with proper mechanical and piezoelectric properties by utilizing proper AR fillers. 相似文献
997.
In this work, a novel and simple analytical method using capillary electrophoresis (CE) with capacitively coupled contactless conductivity detection (C4D) is proposed for the determination of the polyols erythritol, maltitol, xylitol, and sorbitol in sugar‐free chocolate. CE separation of the polyols was achieved in less than 6 min, and it was mediated by the interaction between the polyols and the borate ions in the background electrolyte, forming negatively charged borate esters. The extraction of the polyols from the samples was simply obtained using ultra‐pure water and ultrasonic energy. Linearity was assessed by calibration curves that showed R2 varying from 0.9920 to 0.9976. The LOQs were 12.4, 15.9, 9.0, and 9.0 μg/g for erythritol, maltitol, xylitol, and sorbitol, respectively. The accuracy of the method was evaluated by recovery tests, and the obtained recoveries varied from 70 to 116% with standard deviations ranging from 0.2 to 19%. The CE‐C4D method was successfully applied for the determination of the studied polyols in commercial samples of sugar‐free chocolate. 相似文献
998.
The amide A band of protein is sensitive to the hydrogen bands of amide groups of proteins. However, it is hard to distinguish the amide A band of aqueous protein in situ directly, since it overlaps with O-H stretching vibration of water. In this work, we presented a new analytical method of Raman ratio spectrum, which can extract the amide A band of proteins in water. To obtain the Raman ratio spectrum, the Raman spectrum of aqueous protein was divided by that of pure water. A mathematical simulation was employed to examine whether Raman ratio spectrum is effective. Two kinds of protein, lysozyme and α-chymotrypsin were employed. The amide A bands of them in water were extracted from Raman ratio spectra. Additionally, the process of thermal denaturation of lysozyme was detected from Raman ratio spectrum. These results demonstrated the Raman ratio spectra could be employed to study the amide A modes of proteins in water. 相似文献
999.
1000.
Mostafa Nasri 《Optimization》2016,65(2):467-478
The analysis of the principal-agent problem usually requires the classical first-order approach (FOA). However, the validity of the FOA makes restrictive assumptions on the problem under consideration such as the convexity of the distribution function condition. The main aim of this paper is to compute the optimal wages and characterize a closed form solution to the risk-neutral principal-agent problem with limited liability constraints. The development in this paper mainly invokes certain techniques in the semi-infinite programming rather than the FOA. 相似文献