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排序方式: 共有373条查询结果,搜索用时 938 毫秒
51.
In this work, a high photocatalytic activity was attained by intercalating a Pt layer between SnO2 and TiO2 semiconductors, which yielded a TiO2/Pt/SnO2 - type heterostructure used in the discoloration of blue methylene (MB) solution. The porous films and platinum layer were obtained by electrophoretic deposition and DC Sputtering, respectively, and were both characterized morphologically and structurally by FE-SEM and XRD. The films with the Pt interlayer were evaluated by photocatalytic activity through exposure to UV light. An increase in efficiency of 22% was obtained for these films compared to those without platinum deposition. Studies on the reutilization of the films pointed out high efficiency and recovery of the photocatalyst, rendering the methodology favorable for the construction of fixed bed photocatalytic reactors. A proposal associated with the mechanism is discussed in this work in terms of the difference in Schottky barrier between the semiconductors and the electrons transfer and trapping cycle. These are fundamental factors for boosting photocatalytic efficiency. 相似文献
52.
Xingxing Zhang Qingmei Su Gaohui Du Bingshe Xu Shun Wang Zhuo Chen Liming Wang Wenhuan Huang Huan Pang 《Angewandte Chemie (International ed. in English)》2023,62(39):e202304947
Pursuing high power density lithium metal battery with high safety is essential for developing next-generation energy-storage devices, but uncontrollable electrolyte degradation and the consequence formed unstable solid-electrolyte interface (SEI) make the task really challenging. Herein, an ionic liquid (IL) confined MOF/Polymer 3D-porous membrane was constructed for boosting in situ electrochemical transformations of Janus-heterarchical LiF/Li3N-rich SEI films on the nanofibers. Such a 3D-Janus SEI-incorporated into the separator offers fast Li+ transport routes, showing superior room-temperature ionic conductivity of 8.17×10−4 S cm−1 and Li+ transfer number of 0.82. The cryo-TEM was employed to visually monitor the in situ formed LiF and Li3N nanocrystals in SEI and the deposition of Li dendrites, which is greatly benefit to the theoretical simulation and kinetic analysis of the structural evolution during the battery charge and discharge process. In particular, this membrane with high thermal stability and mechanical strength used in solid-state Li||LiFePO4 and Li||NCM-811 full cells and even in pouch cells showed enhanced rate-performance and ultra-long life spans. 相似文献
53.
Dr. Wei-Hua Deng Prof. Qiao-Hong Li Jie Chen Chuan-Zhe Wang Dr. Zhi-Hua Fu Dr. Xiao-Liang Ye Prof. Guan-E Wang Prof. Gang Xu 《Angewandte Chemie (International ed. in English)》2023,62(31):e202305977
The electronic conductivity (EC) of metal–organic frameworks (MOFs) is sensitive to strongly oxidizing guest molecules. Water is a relatively mild species, however, the effect of H2O on the EC of MOFs is rarely reported. We explored the effect of H2O on the EC in the MOFs (NH2)2-MIL-125 and its derivatives with experimental and theoretical investigations. Unexpectedly, a large EC increase of 107 on H2SO4@(NH2)2-MIL-125 by H2O was observed. Brønsted acid–base pairs formed with the −NH2 groups, and H2SO4 played an important role in promoting the charge transfer from H2O to the MOF. Based on H2SO4@(NH2)2-MIL-125, a high-performance chemiresistive humidity sensor was developed with the highest sensitivity, broadest detection range, and lowest limit of detection amongst all reported sensing materials to date. This work not only demonstrated that H2O can remarkably influence the EC of MOFs, but it also revealed that post-modification of the structure of MOFs could enhance the influence of the guest molecule on their EC to design high-performance sensing materials. 相似文献
54.
Justina Jovaišaitė Sven Kirschner Steponas Raišys Gediminas Kreiza Paulius Baronas Saulius Juršėnas Matthias Wagner 《Angewandte Chemie (International ed. in English)》2023,62(4):e202215071
Organic ultralong room temperature phosphorescence (RTP), or organic afterglow, is a unique phenomenon, gaining widespread attention due to its far-reaching application potential and fundamental interest. Here, two laterally expanded 9,10-dimesityl-dihydro-9,10-diboraanthracene (DBA) derivatives are demonstrated as excellent afterglow materials for red and blue-green light emission, which is traced back to persistent thermally activated delayed fluorescence and RTP. The lateral substitution of polycyclic DBA scaffold, together with weak transversal electron-donating mesityl groups, ensures the optimal molecular properties for (reverse) intersystem crossing and long-lived triplet states in a rigid poly(methyl methacrylate) matrix. The achieved afterglow emission quantum yields of up to 3 % and 15 %, afterglow lifetimes up to 0.8 s and 3.2 s and afterglow durations up to 5 s and 25 s (for red and blue-green emitters, respectively) are attributed to the properties of single molecules. 相似文献
55.
LLDPE was blended with esterified styrene-maleic anhydride (ESMA) to improve the environmental degradation characteristics of LLDPE. ESMA was synthesized by esterifying styrene maleic anhydride (SMA) with n-decanol. LLDPE was blended with ESMA (EDP blends) and SMA separately in a single screw extruder by melt mixing. Composition of ESMA was varied from 20 to 40 wt% in the blends. LLDPE grafted with glycidyl methacrylate (LLDPE-g-GMA) was used as compatibilizer to improve the compatibility. Scanning electron photomicrograph (SEM) of cryofractured impact specimens showed significant reduction in domain size and uniform distribution of ESMA in LLDPE matrix in presence of compatibilizer in 70/30 blends. Environmental degradability was assessed by subjecting the films to soil burial test and exposure to buffer solution of different pH. Environmental degradation was followed by measuring the periodic change in weight of the blend samples. Films were exposed to accelerated and natural weathering and photodegradation was assessed by noting the embrittlement time of the film. Films of compatibilized blends fragmented at a faster rate than the films of uncompatibilized blend. Carbonyl index of films subjected to natural weathering was also found to be higher than that for the virgin LLDPE films. 相似文献
56.
金膜组分的ICP-AES法分析 总被引:2,自引:0,他引:2
研究了在室温下用王水溶解金膜,ICP-AES法测定金膜组分银,铜,铁,铅,锑,铋等的方法,该方法简便,实测样品获得了满意结果。 相似文献
57.
L. Szybisz 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,14(4):733-746
Density functionals proposed in the literature for describing the behaviour of liquid helium at T
=0 K are examined. In so doing, several properties of the ground states of free films of superfluid
4
He are calculated by using zero- and finite-range density functional theories and these results are compared to that computed
with Monte Carlo simulations. We mainly focus the attention on the energy per particle of the slabs, the surface tension and
the width of the liquid-vacuum interfaces, all as a function of the inverse of coverage. The largest differences are found
in the case of the surface widths.
Received 26 July 1999 相似文献
58.
L. Fleischmann J. Bonn B. Bornschein P. Leiderer E.W. Otten M. Przyrembel Ch. Weinheimer 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,16(3):521-529
The dewetting dynamics of solid films of hydrogen isotopes, quench-condensed on a graphite substrate, was measured at various
temperatures below desorption by observing the stray light from the film. A schematic model describing the dewetting process
by surface diffusion is presented, which agrees qualitatively with our data. The activation energies of different hydrogen
isotopes for surface diffusion were determined. The time constant for dewetting of a quench-condensed film at the working temperature of 1.86 K of the mainz neutrino mass experiment was extrapolated.
Received 30 December 1999 相似文献
59.
A novel roundish objects were observed directly by means of atomic force microscopy to be formed on dimyristoylphosphatidylcholoine (DMPC) Langmuir-Blodgeet bilayer films. The roundish structure may be resulted from the aggregation of DMPC molecules because of the collapse of DMPC liposomes formed on the interface of water/organic phase when they lose the water support. 相似文献
60.
1,1,4,4-Tetraphenyl-1,3-butadiene (TPB) was successfully introduced into the polymer multilayerfilms by means of Langmuir-Blodgett (LB) technique. Results of UV-VIS spectra and X-ray diffractionshowed that the uniform films had a layer structure similar to the superlattice of organic multiple quantumwells. The electroluminescence (EL) devices fabricated from the doped polymer LB films emitted blue light.Compared with the casting films, the photoluminescence (PL) and EL spectra showed that the exciton energyshifts to higher and the half-width of the emission peak becomes narrower due to exciton confinement effect. 相似文献