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101.
本文系统研究了MFX体系中Eu3+荧光光谱特征,着重讨论了X-,M2+及杂质缺陷(主要为O2-)对Eu3+发光的影响. 相似文献
102.
1引言大粘度(大r)和大系数(ss和sc)法是处理流动区域中障碍物的常用方法山。但当流动区域中障碍物数量较多时,宜采用空隙率来模拟障碍物,如模拟反应堆流动传热的商用程序COMMIX[’]。我们根据空隙率模拟的基本概念,针对采用交错网格的压力校正法,自行编制了多障碍物流动传热三维计算的全部源程序代码,应用于某核反应堆钠池流动传热的数值模拟,获得了比较合理的结果。2数学模型和数值方法2.1控制方程空隙率修整的质量、动量、能量及湍流动能与耗散率的守恒方程通式的三维柱坐标形式为其中中一1,。,。,。,T,k,。分别表… 相似文献
103.
Kevin Houston 《Inventiones Mathematicae》2002,147(3):471-485
The disentanglement of certain augmentations is shown to be the topological join of a disentanglement and a Milnor fibre.
The kth disentanglement of a finite map is defined and for corank 1 maps from ℂ
n
to ℂ
n
+1 it is shown that they are homotopically equivalent to a wedge of spheres. Applications to the Mond conjecture are given.
Oblatum 24-VII-2000 & 5-VII-2001?Published online: 12 October 2001 相似文献
104.
105.
Several α-ketoalcohols of synthetic value were resolved using lipase as a catalyst. Lipoprotein lipase (LPL) provided the best rate of hydrolysis and kinetic differentiation. One of these optically pure α-ketoalcohol was converted to (5)-ibuprofen in good optical purity. The stereospecific inversion of (R)-alcohol to (S)-alcohol is described. 相似文献
106.
107.
锰结核中硅,铝,铁,镁,磷,钾,锰,钛的XRFA 总被引:1,自引:0,他引:1
本文叙述了用XRF分析锰结核中Si、Al、Fe、Mg、P、K、Mn和Ti的方法。按照通常锰结核的主次成分制备6个人工合成标准,根据Sherman方程计算了已知成分(二元系统)的相对强度。用L-T方求得了互致元素校正的理论α系数(基本的、混合的、修正的),用DATAFLEX151B计算机以BASIC语言汇了“PRA,APU”计算机程序。然后进行非线性回归分析了锰结核样品得到了满意的结果。 相似文献
108.
Semi-empirical molecular orbital calculations were carried out for the compounds (C2H5)3As, (C2H5)3Ga and RAsH2 (R = C2H5, i-C3H7, i-C4H9, and t-C4H9) by using the CNDO/2-U program, and their capability of β-elimination reaction is compared on the basis of the torsion energy to the transition state, electrostatic interactions and orbital overlapping between the central atom and the β-hydrogen, and bond order of the metal-carbon, and carbon-hydrogen bond. In the comparison of (C2H5)3As with (C2H5)3Ga, we found that the β-elimination of (C2H5)3As could hardly be expected to take place in the thermal decomposition. The capability of β-elimination would be smaller in C2H5AsH2 than that in (C2H5)3As. Moreover when the ethyl group is replaced by a t-butyl group in RAsH2, the β-elimination reaction appears to become more difficult and a large possibility for a radical process is suggested. 相似文献
109.
The response to Hg(II) of a thin all-solid-state Te-doped silver chalcogenide membrane, described by the general formula Ag2 + δSe1 − xTex, which has been electrochemically prepared following a previously proposed approach, has been investigated. The kinetics of formation of the membrane's secondary dynamic response to Hg(II) has been successfully combined with the precise timing and transient signal, typical for flow-injection (FI) measurements, in developing a sensitive and reliable mercury FI detector. Under optimized stream conditions it exhibits a linear Nernstian response, with a double slope of the calibration graph of 59 mV dec−1, over the mercury(II) concentration range 10−6 − 10−3 M, the typical sample throughput amounting to about 70 samples per hour. The observed chemical amplification of the signal is due to the specificity of the processes dominating the initial step in formation of the steady-state signal of the membrane to mercury. The analytical performance of the Hg(II) FI detector, as regards sensitivity, reproducibility, selectivity and long-term stability has been thoroughly investigated. The exact procedure for membrane electrodeposition is given and the potential of the proposed approach as a cost-effective way for preparing chalcogenides of unique structure and properties has been outlined in the above context. 相似文献
110.
The electrochemical oxidation of 1, 3-benzenedithiol was investigated in a 0. 100 mol/L tetrabutylammonium perchlorate/acetonitrile electrolyte. The electrochemical techniques used were potential sweep, bulk electrolysis, rotating disc and the potential step method. The combination of the techniques yielded the number of electrons transferred per molecule, the reaction order, the transfer coefficient, the diffusion coefficient and concentration of dithiol anions, the standard heterogeneous rate constant as well as the formal potential and equilibrium constant of the preceeding dissociation reaction. This paper also illustrates the methods for studying the electrode kinetics of reactions which (a) involve a chemical reaction preceeding the electron-transfer process, (b) have insoluble polymer products, and (c) are totally irreversible. 相似文献