聚合物负载磺酸催化的三组分反应合成1-酰胺烷基-2-萘酚

聚合物负载磺酸，一种环境友好的固体酸催化剂，可以有效地催化2-萘酚、脲或酰胺和醛的三组分“一锅”反应生成1-酰胺烷基-2-萘酚。该方法得率高，操作简单。     

多光子技术及其应用研究进展

本文对多光子技术及其应用研究进展进行了较全面综述，介绍了多光子技术的基本原理，重点评述了多光子技术在生命科学、化学、物理学和材料科学领域的应用研究进展，并对多光子技术的发展趋势作了概括。     

激光回射束干涉相移效应的研究

激光回射束干涉相移效应的研究邓延倬，何金兰（武汉大学分析测试科学系，武汉，４３００７２）关键词激光，折射指数，干涉相移效应，毛细管电泳基于激光回射束干涉相移效应，曾首次用于光热测量［１］和微体积样品检测［２］．本文讨论这种效应的基本原理及其用于分析化...     

Amperometric biosensors employing an insoluble oxidant as an interference-removing agent

A strong oxidant membrane is introduced to amperometric biosensors in order to solve the problem associated with interference from readily oxidizable species. The proposed biosensors are in planar format, and are composed of four components, i.e. a base amperometric transducer, an enzyme layer, a protecting membrane, and an oxidant membrane. In this sensor format, interfering species are removed by an oxidation reaction during their diffusion through the oxidant membrane. The oxidant membrane is introduced by dispensing a mixture of an oxidant and a polymer matrix as dissolved in an organic solvent, and thus, could be easily adapted to mass fabrication of miniature biosensors. In this work, several different reagents are examined as oxidants: BaO₂, CeO₂, MnO₂ and PbO₂. Of these, PbO₂ is shown to yield biosensors with the best performance, in terms of reducing interfering signals. Two different matrix systems are devised for use in formulating oxidant membranes: hydrophilic polyurethane (HPU) and cellulose acetate incorporating poly(ethylene glycol) (CA/PEG). While the CA/PEG-type sensor displays better sensitivity and faster response behavior, the HPU-type is shown to exhibit more pronounced interference-removing ability. The analytical utility of the proposed oxidant membrane is demonstrated by fabricating amperometric glucose and creatinine sensors as the model biosensor systems, and by investigating their response characteristics.     

N2O／C2H2FAAS法测定铝的干扰研究

本文研究了４０种单个无机离子、混和无机离子及２４种有机物在Ｎ２Ｏ／Ｃ２Ｈ２火焰中对铝吸收信号的干扰情况。并从物理干扰、光谱干扰和化学干扰等角度对它们的干扰机理作了解释。     

四能级系统中ac-Stark分裂研究

提出一双光场作用下的四能级系统,并对四能级模型的共振荧光谱作了详尽的研究.原子的共振荧光谱随Rabi频率的变化展示出能级的acStark分裂,且在很大参量范围内光谱具有这一特性.但当只有一个激发通道时不产生acStark分裂.在一定的条件下原子的共振荧光谱出现了两条黑线(darkline).可以认为acStark分裂的产生是多通道量子干涉的结果.利用缀饰态理论对acStark分裂给出很好的解释 关键词： 四能级系统模型 ac-Stark分裂 黑线(darkline) 多通道量子干涉     

NMR波谱学中的高温近似的有效性及其相关问题

高温近似(HTA)是NMR波谱学和MRI技术中久经考虑且应用最广的一个近似. 最近几年有一大批引人注目的文章断言对高场下的浓溶液，如水的质子COSY谱，该近似会 失效. 与声称的HTA失效同样令人惊讶的是其副产品之一，即认为在低粘度液体如水里，存 在分子间的多量子相干(MQC). 根据理论分析及实验结果，本文将对液体中HTA和分子间MQC 作一仔细考查. 结论是：(1)室温下，常规NMR样品如水，不是一个宏观量子系统；(2)室温下，HTA仍然是NMR里最值得信赖的近似；(3)质子COSY谱(如水)中所观察到的多重自旋回波( MSE)峰并不意味存在分子间的量子力学自旋相互作用.     

Unstable resonator alignment based on the fringe analysis

The existing cavity mirrors alignment method aligns cavities according to the symmetry of the near-field interference fringes of the guided lights by the unstable resonator. Its precision is restricted due to the lack of objective criterion for the fringe symmetry. This article proposes a high-precision cavity mirrors alignment method using the grey projection of fringe patterns as a solution to the problem. First, vertical and horizontal grey projection on the concerned fringe patterns; then an evaluation function for the cavity mirrors alignment is established using the distances between peak/valley values of all the levels in the projection curve as variables; finally, the function value is employed to characterize the fringe symmetry and thus to provide an objective criterion for the alignment effect of the stable resonator cavity mirrors. Experiments show that the proposed method is able to give effective evaluation for the symmetry of the near-field interference fringes of the guided lights and improve the alignment precision greatly.     

Combined effects of particle interaction and nonlinear sweep on Landau-Zener transition

We investigate the Landau-Zener transition (LZT) of a two-level system with two types of nonlinearity: particle interaction and nonlinear time-dependent energy sweep, both numerically and analytically. Due to the interplay between these two types of nonlinearity, many interesting phenomena in different parameter regions occur, including breakdown of adiabaticity, fade-out of interference phenomenon, and asymmetry of transition probability. The potential experimental observation of transition dynamics in this system is suggested.     

外场多光轴平行性测试的光学系统设计

针对外场条件下因大气环境影响导致多光轴平行性误差的问题,设计了一种可见光、1.06μm激光及812μm的长波红外多光轴平行性测试的光学系统,系统采用卡塞格林系统为共光路并以可见光为基准光轴.卡塞格林系统的主次镜均采用双曲面校正球差及慧差,添加校正透镜减小了轴外像差.设计结果表明,该光学系统成像质量达到了衍射极限,在大气...