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151.
许多物理现象可以在数学上描述为受曲率驱动的自由界面运动,例如薄膜和泡沫的演变、晶体生长,等等.这些薄膜和界面的运动常依赖于其表面曲率,从而可以用相应的曲率流来描述,其相关自由界面问题的数值计算和误差分析一直是计算数学领域中的难点.参数化有限元法是曲率流的一类有效计算方法,已经能够成功模拟一些曲面在几类基本的曲率流下的演化过程.本文重点讨论曲率流的参数化有限元逼近,它的产生、发展和当前的一些挑战. 相似文献
152.
Hui Jin Yan-bing Hou Xian-guo Meng Feng Teng 《高分子科学》2006,(6):553-558
In this paper, photoexcitation processes in the bilayer devices based on inorganic materials and poly(N-vinylcarbazole) (PVK) were investigated. In order to clarify the roles of inorganic materials in photoconductive properties of bilayer devices, TiO2 and ZnS were chosen to combine with PVK. A model for generation of photocurrent (Iph) in single layer device of PVK was obtained. It is deduced that the recombination rate constant (Pcomb) and the ionization rate constant (y) ofexcitons should be considered as the most important factors for Iph. For inorganic materials (TiO2 or ZnS)/PVK bilayer devices, in reverse bias of-4 V, the photocurrent of 115 mA/cm^2 in the TiO2/PVK device was observed, but the photocurrent in the ZnS/PVK device was only 10 mA/cma under the illumination light of 340 nm and the light intensity of 14.2 mW/cm^2. The weaker photocurrent is attributed to the absorption of ZnS within UV region and the energy offset at the interface between PVK and ZnS, which impedes the transport of charge carriers. 相似文献
153.
Summary We describe an approach to protein structure comparison designed to detect distantly related proteins of similar fold, where the procedure must be sufficiently flexible to take into account the elasticity of protein folds without losing specificity. Protein structures are represented as a series of secondary structure elements, where for each element a local environment describes its relations with the elements that surround it. Secondary structures are then aligned by comparing their features and local environments. The procedure is illustrated with searches of a database of 468 protein structures in order to identify proteins of similar topology to porcine pepsin, porphobilinogen deaminase and serum amyloid P-component. In all cases the searches correctly identify protein structures of similar fold as the search proteins. Multiple cross-comparisons of protein structures allow the clustering of proteins of similar fold. This is exemplified with a clustering of /- and -class protein structures. We discuss applications of the comparison and clustering of three-dimensional protein structures to comparative modelling and structure-based protein design. 相似文献
154.
本文测定了新疆产新疆党参,新疆元胡等12种中草药中十种微量金属元素的含量.结果表明这些中草药中具有显著生理活性的Zn、Fe、Cu、Mn等元素.它们的含量除了个别样品外均大于或接近于国内其它地区所产的同种中草药、根据冠心病病因的Zn/Cu值假说和微量金属元素的含量关系,新疆产12种中草药也可用于防治冠心病. 相似文献
155.
广山药中16种元素的分析比较 总被引:21,自引:1,他引:21
用原子吸收法和分光光度法测定了5个产地的广山药及怀山药中16种元素的含量,并进行了比较。发现广山药及怀山药中均含有Mn,Fe,Zn,Ca,Cu,Mg,P,Se等元素,5个产地的广山药中的Cu/Zn值均低于正常人血清的Cu/Zn,这些元素可能是怀山药,广山药具有补脾养胃,生津益肺,补肾涩精,治疗糖尿病等功效的物质基础之一;广山药长期作为山药的一个品种同等入药,食用是有科学根据的;广山药,怀山药中含有一定量的As,Hg。 相似文献
156.
An analytical method for the simultaneous determination of some trace elements (Au, Fe, Mg, Li, Sr, Zn) in human serum by inductively coupled plasma atomic emission spectrometry (ICP-AES) with flow injection is described. Physical interference caused by the change of sample viscosity is discussed. When 100 μl of serum was injected, the relevant recoveries of > 99% for Li, > 98% for Cu and Mg, > 95% for Fe were obtained for an NIST SRM with R.S.D. > 1.3% using optimized flow injection parameters. The prepared lyophilized control serum for routine analysis in clinical laboratories was analyzed and verified for the validity of the technique employed in this experiment using NIST SRM 909 as a primary reference material. 相似文献
157.
CHARACTERIZATIONOFRADIATIONGRAFTCOPOLYMEROFINORGANICCOMPOUNDONTOALKENEZhangWanxi;CheJitai;YanMeilan(ChangchuninstituteofAppli... 相似文献
158.
Different stationary phases were prepared by mixing a series of inorganic salts with dimethylsiloxane polymer (SE-30) and then tested by capillary gas chromatography. It was demonstrated that the polarity (as evaluated by measurement of Rohrschneider constants) of the mixed stationary phases, which is inferior or equal to that of a medium-polar OV-25 phases, reached even lower values than SE-30 alone. The influence of NaF, NaCl, NaBr, AgNO3, and other inorganic salts on the polarity of capillaries is reflected by a better resolution and shorter retention time of cis/trans isomers of fatty acid methyl esters (FAMES) as well as positional isomers of triglycerides. 相似文献
159.
A home made column of commercially available iminodiacetate resin, Muromac A-1 (50–100 mesh) was used to concentrate rare earth elements (REEs) (15 elements: Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) in seawater. An automated low pressure flow analysis method with on-line column preconcentration/inductively coupled plasma mass spectrometry (ICP-MS) is described for the determination of REEs in seawater. Sample solutions (adjusted to pH of 3.0) passed through the column. After washing the column with water, the adsorbed elements were subsequently eluted into the plasma with 0.7 M nitric acid. Calibration curves were accomplished by means of purified artificial seawater with a sample loading time of 120 s. Detection limits (DLs) of the on-line column preconcentration/ICP-MS by eight replicate operations were between 0.040 and 0.251 pg ml−1 for REEs in the artificial seawater. The precision was less than 8.9% for REEs and one sample can be processed in 7 min using a 7 ml of sample. The proposed method was applied to determine REEs in coastal seawater of Hiroshima Bay, Japan. 相似文献
160.
Kim WS Park M Lee DW Moon MH Lim H Lee S 《Analytical and bioanalytical chemistry》2004,378(3):746-752
Fly ash has been regarded as hazardous because of its high adsorption of toxic organic and/or inorganic pollutants. Fly ash is also known to have broad distributions of different chemical and physical properties, such as size and density. In this study, fly ash emitted from a solid waste incinerator was pre-fractionated into six sub-populations by use of gravitational SPLITT fractionation (GSF). The GSF fractions were then analyzed by sedimentation field-flow fractionation (SdFFF) and ICP–AES. SdFFF analysis showed the fly ash has a broad size distribution ranging from a few nanometers up to about 50 µm. SdFFF results were confirmed by electron microscopy. Inductively coupled plasma–atomic emission spectroscopy (ICP–AES) analysis of the GSF fractions showed the fly-ash particles contain a variety of inorganic elements including Ca, Si, Mg, Fe, and Pb. The most abundant in fly ash was Ca, followed by Si then Mg. No correlations were found between trace element concentration and particle size. 相似文献