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111.
Sakhaii P Haase B Bermel W 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,191(2):291-303
A new scheme for obtaining HSQC spectra with improved resolution or in a shorter time called SHARC (Shaped Arrayed data aCquisition protocol) is proposed, which uses region selective RF pulses and allows the sweep width to be adjusted individually for each region. It thus bypasses the problems with the Nyquist theorem associated with other method suggested for this purpose. Assignment of the cross-peaks to their respective region is achieved by manipulating the phases of the RF pulses and/or their frequencies. SHARC NMR can be applied without any previous knowledge of the chemical shift distribution, but can be further optimized on the basis of a quick overview spectrum. 相似文献
112.
Froncisz W Camenisch TG Ratke JJ Anderson JR Subczynski WK Strangeway RA Sidabras JW Hyde JS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,193(2):297-304
A reference arm W-band (94 GHz) microwave bridge with two sample-irradiation arms for saturation recovery (SR) EPR and ELDOR experiments is described. Frequencies in each arm are derived from 2 GHz synthesizers that have a common time-base and are translated to 94 GHz in steps of 33 and 59 GHz. Intended applications are to nitroxide radical spin labels and spin probes in the liquid phase. An enabling technology is the use of a W-band loop-gap resonator (LGR) [J.W. Sidabras, R.R. Mett, W. Froncisz, T.G. Camenisch, J.R. Anderson, J.S. Hyde, Multipurpose EPR loop-gap resonator and cylindrical TE011 cavity for aqueous samples at 94 GHz, Rev. Sci. Instrum. 78 (2007) 034701]. The high efficiency parameter (8.2 GW−1/2 with sample) permits the saturating pump pulse level to be just 5 mW or less. Applications of SR EPR and ELDOR to the hydrophilic spin labels 3-carbamoyl-2,2,5,5-tetra-methyl-3-pyrroline-1-yloxyl (CTPO) and 2,2,6,6,-tetramethyl-4-piperidone-1-oxyl (TEMPONE) are described in detail. In the SR ELDOR experiment, nitrogen nuclear relaxation as well as Heisenberg exchange transfer saturation from pumped to observed hyperfine transitions. SR ELDOR was found to be an essential method for measurements of saturation transfer rates for small molecules such as TEMPONE. Free induction decay (FID) signals for small nitroxides at W-band are also reported. Results are compared with multifrequency measurements of T1e previously reported for these molecules in the range of 2–35 GHz [J.S. Hyde, J.-J. Yin, W.K. Subczynski, T.G. Camenisch, J.J. Ratke, W. Froncisz, Spin label EPR T1 values using saturation recovery from 2 to 35 GHz. J. Phys. Chem. B 108 (2004) 9524–9529]. The values of T1e decrease at 94 GHz relative to values at 35 GHz. 相似文献
113.
Automatic phasing of MR images. Part I: linearly varying phase 总被引:1,自引:1,他引:0
Larry Bretthorst G 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,191(2):184-192
In spin-echo and well shimmed gradient-echo images, the phase of the complex image often varies linearly in both the readout and phase-encode directions. Thus, in principle, it is possible to display an image in absorption mode. However, manually determining the two first-order and one zero-order phase parameters needed to display an absorption-mode image is a formidable task. In this paper, the Bayesian calculations needed to automatically determine these parameters are presented, and the calculations are illustrated using spin-echo images. 相似文献
114.
Náfrádi B Gaál R Sienkiewicz A Fehér T Forró L 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,195(2):206-210
We present a newly-developed microwave probe for performing sensitive high-field/multi-frequency electron spin resonance (ESR) measurements under high hydrostatic pressures. The system consists of a BeCu-made pressure-resistant vessel, which accommodates the investigated sample and a diamond microwave coupling window. The probe’s interior is completely filled with a pressure-transmitting fluid. The setup operates in reflection mode and can easily be assembled with a standard oversized microwave circuitry. The probe-head withstands hydrostatic pressures up to 1.6 GPa and interfaces with our home-built quasi-optical high-field ESR facility, operating in a millimeter/submillimeter frequency range of 105–420 GHz and in magnetic fields up to 16 T. The overall performance of the probe was tested, while studying the pressure-induced changes in the spin-relaxation mechanisms of a quasi-1D conducting polymer, KC60. The preliminary measurements revealed that the probe yields similar signal-to-noise ratio to that of commercially available low-frequency ESR spectrometers. Moreover, by observing the conduction electron spin resonance (CESR) linewidth broadening for KC60 in an unprecedented microwave frequency range of 210–420 GHz and in the pressure range of up to 1.6 GPa, we demonstrate that a combination of high-pressure ESR probe and high-field/multi-frequency spectrometer allows us to measure the spin relaxation rates in conducting spin systems, like the quasi-1D conductor, KC60. 相似文献
115.
Wei Han Wan-Guo Zheng Yi-Sheng Yang Ding-Xiang Cao Qi-Hua Zhu Lie-Jia Qian 《Optik》2008,119(3):122-126
In this paper, we studied efficient second-harmonic generation (SHG) of femtosecond pulses in both phase- and group-velocity-matched structures. Obtained results show that phase matching becomes more critical under conditions required for high levels of conversion efficiency. And the imperfect phase mismatch caused by mismatched group-velocity dispersion (GVD) will limit conversion efficiency as well as bandwidth of generated second-harmonic (SH) pulses. The spectral characteristics of the generated SH pulses and its conversion efficiency in the strong pump regime are investigated in detail. The acceptance bandwidth of nonlinear crystal in the high-efficiency SHG is redefined in the paper, and the definition is much closer to the practical application of design. 相似文献
116.
A modified Fourier transform profilometry (FTP) based on a fringe pattern with two frequency components is proposed, which provides a larger measuring range than that of the traditional FTP. We analyze the maximum measuring range and give an expression to describe the measurable slope of the height variation limitation of this method. The modified FTP provides us another approach to eliminate frequency overlapping. When the spectra distribution of a measured object is not spherical symmetry, we can avoid the frequency aliasing through projecting a fringe pattern with two frequency components, instead of increasing the density of the projected fringe and the resolution of a CCD camera. The theoretical analysis and primary experiments verified the method. 相似文献
117.
Pinpin Yan Wei Hong Jixin Chen 《International Journal of Infrared and Millimeter Waves》2008,29(3):282-290
A millimeter wave phase locked and frequency multiplying source is proposed in this paper. The design includes an X-band phase
locked loop (PLL) frequency synthesizer as the base frequency source, and a monolithic millimeter wave frequency tripler,
which is developed by using OMMIC 0.18μm pHEMT process. The PLL and the tripler are integrated in a single circuit board to
make a low-cost and compact frequency source with the size of 6cm × 5cm. Measurement shows an output power of more than 4.8dBm
at the frequency range from 35 to 36.7GHz. A phase noise of about -92dBc/Hz at 100kHz offset is achieved. 相似文献
118.
利用ANSYS有限元软件计算了声波测井中使用的偶极子换能器在不同机械边界条件下的振动模态和频率响应。计算结果显示,偶极子换能器在一定的频率范围内有多个振动模态,不同的机械边界条件不仅影响振动模态的个数而且还影响同一振动模态的谐振频率;从频率响应曲线上还可以看出此结构的偶极子换能器在做弯曲振动时的频带较窄,这对在不同地层井眼中进行的偶极子声波测井非常不利。通过多个不同主频的偶极子换能器组合工作可以从根本上拓宽偶极声波换能器的频带宽度。 相似文献
119.
注入锁定激光器的边带锁频技术稳频系统优化分析 总被引:1,自引:0,他引:1
介绍了边带锁频技术稳频方法,推导出鉴频曲线,对稳频控制过程进行了分析.建立了注入锁定激光器的边带锁频技术稳频系统理论模型,讨论了相关参量对稳频效果的影响并且进行了优化.结果表明,增加入射光强,采用窄线宽的法布里-珀罗以及对法布里-珀罗进行高准确度温控都可以增强稳频效果.提出适用于注入锁定激光器的两种稳频方案并进行比较. 相似文献
120.
This New Views article will highlight some recent advances in high sensitivity gas detection using direct infrared absorption frequency comb laser spectroscopy, with a focus on frequency comb use in chemical reaction kinetics and our own contribution to this field. Our recently implemented detection technique uses a combination of a 12.9?GHz free spectral range virtually imaged phased array and diffraction grating to spatially disperse the mid-infrared frequency comb onto a camera. Individual frequencies or ‘comb teeth’ of a 250?MHz repetition-rate frequency comb are able to be resolved. High molecular sensitivity is achieved by increasing the interaction path length using a Herriott multipass cell. High spectral resolution, broadband spectral coverage, and high molecular sensitivity are all achieved on an adjustable 1–50 µs timescale, making this frequency comb apparatus ideal for measuring chemical reaction kinetics where multiple absorbing species can be monitored simultaneously. This New Views article will also discuss some of the challenges and decisions that chemists might face in implementing this advanced physics technology in their own laboratory. Spatially dispersed 250 MHz mid-infrared frequency comb laser, with absorption of some frequencies by a dilute sample of methane. 相似文献