全文获取类型
收费全文 | 7090篇 |
免费 | 773篇 |
国内免费 | 653篇 |
专业分类
化学 | 3642篇 |
晶体学 | 36篇 |
力学 | 466篇 |
综合类 | 84篇 |
数学 | 545篇 |
物理学 | 3743篇 |
出版年
2024年 | 12篇 |
2023年 | 90篇 |
2022年 | 192篇 |
2021年 | 268篇 |
2020年 | 270篇 |
2019年 | 274篇 |
2018年 | 202篇 |
2017年 | 339篇 |
2016年 | 355篇 |
2015年 | 316篇 |
2014年 | 521篇 |
2013年 | 566篇 |
2012年 | 508篇 |
2011年 | 505篇 |
2010年 | 373篇 |
2009年 | 419篇 |
2008年 | 449篇 |
2007年 | 491篇 |
2006年 | 345篇 |
2005年 | 328篇 |
2004年 | 326篇 |
2003年 | 222篇 |
2002年 | 189篇 |
2001年 | 153篇 |
2000年 | 143篇 |
1999年 | 122篇 |
1998年 | 116篇 |
1997年 | 76篇 |
1996年 | 58篇 |
1995年 | 56篇 |
1994年 | 38篇 |
1993年 | 44篇 |
1992年 | 32篇 |
1991年 | 26篇 |
1990年 | 15篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1973年 | 4篇 |
1959年 | 1篇 |
排序方式: 共有8516条查询结果,搜索用时 15 毫秒
41.
New Schiff bases of 2,4‐dihydroxybenzaldehyde with siloxane‐α,ω‐diamines having different numbers of siloxane units in the chain have been synthesized and characterized by spectroscopy, elemental and thermal analyses. These azomethines were found to form complexes readily with copper(II), nickel(II), cobalt(II), cadmium(II) and zinc(II). From IR and UV–Vis studies, the phenolic oxygen and imine nitrogen of the ligand were found to be the coordination sites. Thermogravimetric analysis (TGA) data indicate the chelates to be more stable than the corresponding ligands. The melting points increase with shortening of the siloxane segment from azomethine, as well as the result of complexation. The chelates obtained were covalently inserted in polymeric linear structures by polycondensation through the OH‐difunctionalized ligand with 1,3‐bis(carboxypropyl)tetramethyldisiloxane. Direct polycondensation, assisted either by acetic anhydride or N,N′‐dicyclohexylcarbodiimide as dehydrating agent and the complex 4‐(dimethylamino)pyridinium 4‐toluenesulfonate as catalyst, was used for the synthesis of these compound types. The structures of the polymers obtained were confirmed by IR, UV and 1H NMR. Characterization was undertaken by TGA, solubility tests and viscosity measurements. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
42.
Huseyin Bekir Yildiz Jaime Castillo Dmitrii A. Guschin Levent Toppare Wolfgang Schuhmann 《Mikrochimica acta》2007,159(1-2):27-34
An amperometric biosensor for the detection of phenolic compounds was developed based on the immobilization of tyrosinase
within an Os-complex functionalized electrodeposition polymer. Integration of tyrosinase within the redox polymer assures
efficient catechol recycling between the enzyme and the polymer bound redox sites. The non-manual immobilization procedure
improves the reproducibility of fabrication process, greatly reduces the desorption of the enzyme from the immobilization
layer, and, most importantly prevents fast inactivation of the enzyme by its substrate due to fast redox cycling.
A two-layer sensor architecture was developed involving ascorbic acid oxidase entrapped within an electrodeposition polymer
in a second layer on top of the redox polymer/tyrosinase layer. Using this sensor architecture it was possible to eliminate
the current interference arising from direct ascorbate oxidation up to a concentration of 630 μM ascorbic acid. The effects
of the polymer thickness, the enzyme/polymer ratio, and the applied potential were evaluated with respect to optimal sensor
properties. The sensitivity of the optimized sensors for catechol was 6.1 nA μM−1 with a detection limit of 10 nM, and for phenol 0.15 nA μM−1 with a detection limit of 100 nM. 相似文献
43.
44.
45.
46.
Daniel E. Vogler Ana Lorencak Julien M. Rey Markus W. Sigrist 《Optics and Lasers in Engineering》2005,43(3-5):527
A novel sensitive technique for the determination of losses in fiber cavities is presented. The method is based on the cavity ringdown scheme implemented in silica-based single-mode fibers. Bending losses of fiber cavities of different lengths have been measured showing all an oscillating behavior with respect to the curvature radius of the fiber as predicted by a theoretical model. The best minimum detectable absorbance per cavity pass achieved by this new method is 1.72×10−3 dB within a 10 m-long cavity. This limit suffices well for an accurate determination of optical bending losses even in bend-insensitive fibers. Furthermore, the comparison of the measured bending losses with a theoretical model allows the extraction of different fiber parameters. Good agreement has been found between the experimentally derived parameters and literature data. 相似文献
47.
Differential FBG sensor for temperature-compensated high-pressure (or displacement) measurement 总被引:2,自引:0,他引:2
A differential fiber Bragg grating (FBG) sensor with a free active element bulk-modulus for high-pressure (or displacement) measurement is presented. Based on the differential measurement method and an isosceles triangle cantilever structure, problems of cross-sensitivity and chirped signal in FBG sensor are improved both theoretically and experimentally. Preliminary experiments indicate that temperature-compensated measurement results agree well with the theoretical analysis. Displacement measurement sensitivity is 1.75 pm/μm, and the estimated pressure measurement resolution can reach 0.27 MPa in case the wavelength shift measurement resolution is 0.01 nm. 相似文献
48.
49.
50.
The noise of hybrid soliton pulse source (HSPS) with linearly chirped Gaussian apodized fiber Bragg grating is analyzed by couple-mode equations including spontaneous emission noise when the HSPS is mode-locked. Relative intensity noise is calculated using numerical solutions of these equations. It is shown that transform limited pulses are generated over a wide tuning range around the fundamental mode-locking frequency with low spontaneous noise. However, a high noise level affects the operation of device, and therefore transform-limited pulses are not obtainable over a wide tuning range. It is also shown that noise is extremely sensitive to the RF and DC currents, linewidth enhancement factor, gain saturation parameter and spontaneous coupling factor. 相似文献