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991.
A superconducting oxide with a stoichiometry La3CaBa3Cu7O15.5+x, in which x = 0.75, was prepared. It had a tetragonal triple-perovskite structure with lattice parameters a = 3.879 Å and c = 11.637 Å. According to resistivity measurements, a sharp superconducting transition, ΔTc(10-90%) = 1.5 K, and Tc(zero) = 80 K were observed. When it was measured at a small magnetic field (10-20 gauss) with field cooling, the sintered pellet showed a positive magnetic susceptibility, but the powdered sample exhibited (he diamagnetism of a typical superconductor. However, no peculiar shielding effect was found in both the sintered and powdered samples. 相似文献
992.
江和安 《广东微量元素科学》1995,2(7):40-43
选择5~6岁儿童64名,随机分为两组,分别服用太阳神奶(A组)和一般乳酸奶(B组),每天服用100mL。连服9周,检测全血中微量元素锌、铁、铜、钙、锰的变化。经检测,服用太阳神奶A组经统计学分析,微量元素锌、铁、锰呈显著或非常显著变化。 相似文献
993.
本文通过分子动力学模拟研究了纳米铜团簇的自扩散性质,结果表明Nc8949铜团簇自扩散系数随温度的升高而增大,在温度为1000 K时纳米铜团簇的扩散系数随团簇半径的倒数基本呈线性增加.同时指出在常温下团簇几乎无扩散行为,而某些文献中关于常温下晶粒扩散分子动力学模拟结果是模拟体系宏观转动造成的虚假现象.? 相似文献
994.
995.
In this paper we report experimental studies of nonvolatilephotorefractive holographic recording in doping In(3mol%), which exceed the so-called threshold, in Ce:Cu:LiNbO3 crystals. The In:Ce:Cu:LiNbO3 crystal was grown by the Czochralski method and oxidized. The OH− absorption band of In:Ce:Cu:LiNbO3 crystal is 3507cm−1. The nonvolatile holographic recording in In:Ce:Cu:LiNbO3crystal is realized by two-photon fixed method. From the experiment, we found that the recording time of In:Ce:Cu:LiNbO3 crystal is lower than that of Ce:Cu:LiNbO3 crystal and there are a little lose of nonvolatile diffraction efficiencies between In:Ce:Cu:LiNbO3 and Ce:Cu:LiNbO3 crystals. In this paper, the mechanism of OH− absorption band shifting and two-photon fixed was discussed, too. 相似文献
996.
M. Karppinen M. Arai T.S. Chan J.M. Chen H. Yamauchi 《Journal of solid state chemistry》2005,178(5):1705-1711
Essentially single-phase Cu(Ba0.67Eu0.33)2(Ce0.33Eu0.67)2Cu2O9±δ samples of the Cu-1222 phase with a fluorite-structured (Ce,Eu)-O2-(Ce,Eu) block between the superconductive CuO2 planes were synthesized in O2 atmosphere to exhibit superconductivity with Tc around 25 K. Wide-range tuning of oxygen content and thereby the overall hole-doping level of the phase was found possible through (i) temperature-controlled oxygen-depletion (TCOD) annealing carried out in a thermobalance in N2 at various temperatures (for reduction), and (ii) high-pressure oxygenation (HPO) treatments carried out in a cubic-anvil-type high-pressure apparatus in the presence of various amounts of Ag2O2 as an excess oxygen source (for oxidation). For the HPO samples a record-high Tc value of 62 K was achieved. On the other hand, deoxygenation to the oxygen content less than 9±δ≈8.9 was found to kill superconductivity. The degree of hole doping (both in overall and for the CuO2 plane and CuO1±δ charge reservoir separately) in the samples is discussed on the bases of Cu L-edge and O K-edge XANES data. 相似文献
997.
H. Fjellvåg Y. Morita J.-M. Lee R.-S. Liu V.P.S. Awana Y. Matsui M. Karppinen 《Journal of solid state chemistry》2006,179(3):632-645
In this work, the first three members (s=1, 2, 3) of the Co-12s2 homologous series of multi-layered copper oxides are gradually doped with holes through high-pressure oxygenation (HPO). The phases differ from each other only by thickness of the fluorite-structured layer block, (Ce,Y,Ca)-[O2-(Ce,Y)]s−1, between two identical CuO2 planes. High-resolution transmission-electron microscopy (HRTEM) and electron diffraction (ED) analyses together with both synchrotron X-ray and neutron powder diffraction data, reveal that as a consequence of HPO the charge-reservoir CoO4-tetrahedra chains get broken and the lattice symmetry of the Co-12s2 phases changes from orthorhombic to tetragonal. Oxygen contents are analyzed for the samples with wet-chemical and thermogravimetric techniques. The valence state of copper in the CuO2 plane is determined from Cu L-edge X-ray absorption near-edge structure (XANES) spectra to be compared with the values estimated through bond-valence-sum (BVS) calculations from the crystal structure data. The positive charge induced by oxygen loading (or aliovalent CaII-for-YIII substitution in CoSr2YCu2O7+δ) is found not to be completely accommodated in the CuO2 planes but be rather effectively trapped at the charge-reservoir Co atoms. Superconductivity appears in the Co-1212 (CoSr2YCu2O7+δ) samples with the copper valence of 2.13 or higher, whereas in the Co-1222 (CoSr2(Ce0.25Y0.75)2Cu2O9+δ) and Co-1232 (CoSr2(Ce0.67Y0.33)3Cu2O11+δ) samples Cu valence does not increase high enough to induce superconductivity. 相似文献
998.
IntroductionDimericcopper(II)carboxylatescontainingavarietyofoxygenandnitrogen donorligandshavebeenextensivelyinvestigatedandtheirpreparations ,magneticandspectralpropertieshavebeenreviewed .1 5Differentkindsofcopper(II)carboxylateadductshavebeensynthesizedandalsodinuclearcopper(II)complexeshavebeenearlystud iedasusefulmodelstoestablishmagneto structuralcorre lationsforspinexchangebetweenmetalions .Inparticu lar,theoccurrenceofdicopperionsattheactivesiteofthevariousformsoftheoxygencarrierpro… 相似文献
999.
Nano-Copper and Cu/UDD (ultradispersed diamond) nanocomposites were separately prepared by reduction of CuCl2 aqueous solution and that doped with 0.7%(weight percent) of ultra-dispersed diamond. The as prepared nano-crystals were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FTIR) and electron paramagnetic resonance techniques (EPR). It was found that homogeneous nucleation dominated the aqueous reduction reaction at high concentration and the diameter of nano-copper decreased as the reaction time shortened, yet at lower concentration heterogeneous nucleation predominated and the doped UDD functioned as heterogeneous nucleation. Otherwise large number of free-radicals existed in the nano-composites. Both of nano-copper and Cu/UDD nanocomposites were strong catalysts for AP decomposition, with Cu/UDD being a more effective one. The higher decomposition temperature for AP was 119 ℃ lower than that without catalyst. And the exothermic quantity of decomposition was from 590 J·g-1 to 1 400 J·g-1 by mix 2% of the Cu/UDD nanocomposites. 相似文献
1000.
V. de la Mota F. Sébille B. Rémaud P. Schuck 《Zeitschrift für Physik A Hadrons and Nuclei》1992,343(4):417-427
Theoretical analyses of heavy-ion reactions are performed in the framework of the semi-classical Landau-Vlasov approach. The incident energies are investigated in the range from intermediate to low energy regimes, where transverse collective motion has been experimentally evidenced. The influence of the equation of state (E.O.S.) parameters on various collective observables is studied in relation with the action of the residual interactions. From the sensitivity to both aspects, and taking into account the experimental biases limitations, our investigation indicates that E.O.S. signatures should be more expected at energies below 100 MeV per nucleon. 相似文献