电感耦合等离子体原子发射光谱法及离子选择电极法测定荧光级氧化钇中痕量铈的研究

文章描述了荧光级氧化钇中痕量稀土铈的测定方法,在溴酸钾存在下,5摩尔/升HNO_3介质中,以P507萃取微量铈,然后有机相用硝酸、过氧化氢反萃取、再将水相浓缩定容,然后以电感耦合等离子体原子发射光谱法分析。同时用铈的离子选择电极以二次标准加入法作第二种手段分析。样品溶液以乙醇预去溶方式引入等离子体,测定下限为2微克/克,方法简单、快速、准确。离子选择电极法测定铈离子下限1×10～(-5)摩尔/升,回收率为94-101%,方法简单,结果满意、价格便宜。     

Dynamics of oscillators with periodic dichotomous noise

The dynamics of bistable oscillators driven by periodic dichotomous noise is described. The stochastic differential equation governing the flow implies smooth trajectories between noise switching events. The dynamics of the two-branched map induced by this flow is a Markov process. Harmonic and quartic models of the bistable potential are studied in the overdamped limit. In the linear (harmonic) case the dynamics can be reduced to a stochastic one-dimensional map with two branches. The moments decay exponentially in this case, although the invariant measure may be multifractal. For strong damping, relaxation induces a cascade leading to a Cantor set and anomalous decay of the density in this case is modeled by a Markov chain. For the physically more realistic case of a quartic potential many additional features arise since the contraction factor is distance dependent. By tuning the barrier-height parameter in the quartic potential, noise-induced transition rates with the characteristics of intermittency are found.     

流动注射-电感耦合等离子体发射光谱法测定天然水中的钙和镁

本文采用流动注射－电感耦合等离子体发现光谱联用技术测定了天然水中的钙、镁元素。考察了试液的雾化和曝光时间及载气压力等因素对分析信号的影响。通过与气动连续进样的对比，测出了钙、镁在流动注射进样下的分散系数。本法在测定钙、镁含量高的水性时，不需对试样进行稀释处理。对五个水样中钙、镁的分析结果与EDTA络合滴定法相吻合。     

Comparison of CEPA and CP-MET methods

The known CEPA variants CEPA (v) withv = 0,1,2,3 and two new ones withv = 4, 5 are compared both formally and for various numerical examples with CP-MET. The main conclusions are: 1. In those situations where both CP-MET and the CEPA variants are justified (i.e. for “good” closed shell states) the correlation energies obtained with the 7 different schemes differ very little (by something like ±2%), with CEPA (1) closest to CP-MET (difference usually a fraction of 1%) and CEPA (4) nearly as close; this is rather insensitive to whether one uses canonical or localized orbitals. Even CEPA (3) is not too far from CP-MET, which confirms an earlier suggestion of Kelly. 2. In those cases where one of the 7 schemes fails (e.g. due to near degeneracy as in covalent molecules at large internuclear distances) the other 6 usually fail as well, though CEPA (0) is then somewhat poorer than the other schemes. Then no longer CEPA (1) but rather CEPA (3) is closest to CP-MET and then all schemes converge much better in a localized representation. 3. CEPA (2) usually leads to best agreement with experiment since it simulates to some extent triple substitutions. In none of the studied examples does CP-MET show a significant superiority as compared to the other schemes. Possible improvements to extend the domain of applicability of these methods are discussed.     

Self-assembled monolayers and chemical derivatization of Ba0.5Sr0.5TiO3 thin films: Applications in phase shifter devices

Thin films of barium strontium titanate (Ba_1−xSr_x TiO₃ (BSTO)) have been used in coupled microstrip phase shifters (CMPS) for possible insertion in satellite and wireless communication platforms primarily because of their high dielectric constant, low loss, large tunability, and good structural stability. In an attempt to improve the figure of merit K (phase shift °/dB of loss) of phase shifters, modification of the metal/BSTO interface of these devices has been done through surface modification of the BSTO layer using a self-assembled monolayer approach. The impact of this nanotechnology promises to reduce RF losses by improving the quality of the metal/BSTO interface. In this study, compounds such as 3-mercaptopropyltrimethoxysilane (MPS), 16-mercaptohexadecanois acid (MHDA) and 3-mercaptopropionic acid (MPA) were used to form the self-assembled monolayers on the BSTO surface. As a result of the previous modification, chemical derivatization of the self-assembled monolayers was done in order to increase the chain length. Chemical derivatization was done using 3-aminopropyltrimethoxysilane (APS) and 16-mercaptohexadecanoic acid. Surface chemical analysis was done to reveal the composition of the derivatization via X-ray photoelectron spectroscopy (XPS) and Fourier Transform Infrared (FT-IR). Low and high frequencies measurements of phase shifters were done in order measure the performance of these devices for insertion in antennas. X-ray photoelectron spectroscopy characterization of modified BSTO thin films with MPS showed a binding energy peak at 162.9 eV, indicative of a possible SO interaction: sulfur of the mercapto compound, MPS, used to modify the surface with the oxygen site of the BSTO thin film. This interaction is at higher binding energies compared with the thiolate interaction. This behavior is observed with the other mercapto compounds such as: MHDA and MPA. An FT-IR analysis present a band at 780 cm⁻¹, which is characteristic of an OSC stretching and reveals the modification of the BSTO thin film by the coupling of the O of the BSTO with the S of the mercapto compound. All the modification using mercapto compounds is through sulfur to the BSTO thin film. MHDA SAM on BSTO thin film was chemically derivatized using APS shown by XPS and FT-IR. The SAMs modified phase shifters showed an improvement in performance with respect to those phase shifters fabricated with standard methods.     

Finite Lifetime Eigenfunctions of Coupled Systems of Harmonic Oscillators

We consider a vector-valued Hermite-type basis for which the eigenvalue problem associated to the operator H _A,B :=B(; _x ² )+Ax ² acting on becomes a three-terms recurrence. Here A and B are 2 × 2 constant positive definite matrices. Our main result provides an explicit characterization of the eigenvectors of H _A,B that lie in the span of the first four elements of this basis when AB BA.This revised version was published online in March 2005 with corrections to the cover date.     

ICP-AES测定Ni-Cr合金在人工唾液中析出的Ni离子

在模拟口腔环境下用人工唾液浸泡Ni-Cr桥,150h后采用ICP-AES测定Ni-Cr桥在人工唾液中的Ni离子析出量.镍在0.01-7.5μg/mL内有良好的线性关系,相关系数为0.9998;方法检出限为0.0059μg/mL;标准加入法测定镍的回收率为92.3%-99.8%.     

QED corrections and chemical properties of Eka-Hg

In this paper, we present a family of coupled higher-order nonlinear Schr?dinger equation describing the optical soliton pulse propagating in inhomogeneous optical fiber media. The exact N-soliton solution and its characteristics of stabilities and novel elastic collision properties are studied in detail. As an example, we give the relative numerical evolutions by a soliton control system to discuss the pulses propagation characteristics.     

Combination of two basic types of synchronization in a coupled semiconductor laser system

Combination of two basic types of synchronization, anticipatory synchronization and lagged synchronization, is investigated numerically between two coupled semiconductor lasers. It is found that lagged synchronization produced by a backward coupling with a suitable delay can combine with the originally hidden anticipatory synchronization and produce a type of synchronization overcoming the original lagged synchronization produced by a forward coupling. We study the combination synchronization phenomenon when the delay of the backward coupling is different from that of the original anticipatory synchronization. Our results suggest that the synchronization combination phenomenon might allow an interpretation of an experimental observation by Sivaprakasam et al. [Phys. Rev. Lett. 87, 154101 (2001)] that the anticipating time is irrespective of the external-cavity round trip time, which to date remains to be understood.