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61.
《Journal of separation science》2017,40(6):1283-1292
Ultra high performance liquid chromatography coupled with mass spectrometry and combining a tissue‐smashing extraction technique was developed for the simultaneous quantitative analysis of 12 compounds in the roots of Pulsatilla chinensis . Among them, compound 6 was characterized and accurately quantified in this herb for the first time. The parameters of extraction condition were simultaneously optimized with a Box–Behnken design and Derringer's function. The optimized conditions were as follows: sample quantity of 0.5 g, ethanol concentration of 70%, and extraction time of 200 s. Multiple‐reaction monitoring scanning was employed for the quantification between positive and negative mode in a single run of 6 min. Full validation of the method was carried out, and the results indicated that the method was rapid, specific, and reliable. The developed method was successfully applied to quantify the 12 compounds in 33 batches of P. chinensis from different provinces. Moreover, the principal component analysis was performed to compare the P. chinensis collected from different provinces of China based on quantitative data and the results indicated that the content of compounds could be used to differentiate the origins of P. chinensis . These results demonstrated that this method is feasible and reliable for the quality control of P. chinensis . 相似文献
62.
Xuefei Lei Guoshun Shan Fan Zhang Pengpeng Liu Li Meng 《Natural product research》2020,34(9):1337-1340
AbstractPhellodendri Chinensis Cortex is widely used in the clinic of traditional Chinese medicine. In order to enlarge the range of application, it is necessary to processed with honey, salt-water, and rice-wine, respectively. We hope to elucidate the connotation of processing, an UPLC-QqQ-MS method was used for determination and comparison the tissue distribution of alkaloids and triterpenes after oral administration water-extracts of crude and processed products. The results showed that the berberine, phellodendrine, magnoflorine, limonin, and obacunone in crude and processed products were distributed in all tissues, especially in the small intestine and stomach. In this study, we can provide a scientific basis for explaining the processing connotation of Phellodendri Chinensis Cortex processed with salt-water and rice-wine, respectively. 相似文献
63.
Inthecourseofourstudiesonnewbiologicallyactivesaponinsofnaturalmedicines,wehaveisolatedescinsla.fo.IVa.IVb,IVc,andIVdtyolnseedsof.4e'v"11/llSchinensisBee.(Hippocastanaceae),andsinglecrystalX-raydiffractionanalysiswasundertakenonescinla'.whichconfirmstheabsoluteconfigurationandsugarsequence.ThepresentpaperdescribesthestructuredeterminationofanewtriterpenoidsaponinnamedescinIVefromthesameplant.EscinIVe,whitepowder.Positive-modeTOF-MScm/zI111[M Na] ,coupledwitllNMRdata.correspondstoane… 相似文献
64.
Three furofuran lignans named neocuscutasides A, B and C were obtained from the ethanolic extract of the dried seeds of Cuscuta chinensis and their structures were characterized by chemical and spectroscopic methods. 相似文献
65.
Kun ZOU Jun WU Chuang LIU Zhi Hui XIAO 《中国化学快报》2006,17(10):1335-1338
More than 1800 species of medicinal plants grow in Shennongjia Forest District. Most of them were recorded to be used as anti-inflammatory agents in the folk medicine1. Kaikoujian, a Chinese name for rhizomes of Tupistra chinensis Bak., is a reputed folk … 相似文献
66.
采用非水毛细管电泳(NACE)法,以pH5.8的醋酸盐-甲醇为背景电解质溶液,运行电压25kV,温度20℃,检测波长210nm,正极压力(5kPa×10s)进样,建立了黄柏药材的NACE指纹图谱。以氯化两面针碱为内标,确定黄柏的NACE指纹峰为13个。测定了10个产地黄柏的NACE指纹图谱,与对照NACE指纹图谱的相似度为0.718~0.982。本方法具有较好的精密度,各指纹峰相对迁移时间的相对标准偏差(RSD)<1.5%,相对峰面积的RSD≤5%。方法可用于黄柏药材的质量控制。 相似文献
67.
Bin Zhu Qingbiao Wang Esben F. Roge Peng Nan Zhijun Liu Yang Zhong 《Chemistry of Natural Compounds》2006,42(4):422-425
Hydrodistilled leaf oils of Pistacia chinensis Bunge from five locations in China were analyzed using GC/MS. A total of 58
compounds was identified in the oils, and a relatively high variation in their contents was found. The major compounds include
β-phellandrene (0.54–53.86%), α-pinene (4.74–54.44%), β-pinene (0.49–42.90%), caryophyllene (5.64–20.01%), cis-ocimene (tr−43.93%), eudesmadiene (0–15.06%), and camphene (tr−20.57%). Cluster analysis classified the leaf oils into two
chemotypes: one rich in α-pinene and β-pinene, and the other rich in β-phellandrene.
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 341–343, July–August, 2006. 相似文献
68.
Kun Zou Jun‐zhi Wang Zhi‐yong Guo Ming Du Jun Wu Yuan Zhou Fei‐jun Dan Chuang Liu 《Magnetic resonance in chemistry : MRC》2009,47(1):87-91
Four new furostanol saponins (1–4), two pairs of diastereoisomers, were isolated from methanolic extracts of Tupistra chinensis rhizomes and their structures were assigned from 1H and 13C NMR spectra, DEPT, and by 2D COSY, NOESY, HMQC, and HMBC experiments. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
69.
新疆红柳花中红色素的提取及理化性质的研究 总被引:3,自引:0,他引:3
报道了新疆红柳花中红色素的提取及物理化学性质的研究,为红柳花红色素的提取和利用提供了科学依据。 相似文献
70.