全文获取类型
收费全文 | 12163篇 |
免费 | 2376篇 |
国内免费 | 1354篇 |
专业分类
化学 | 6103篇 |
晶体学 | 195篇 |
力学 | 521篇 |
综合类 | 83篇 |
数学 | 1504篇 |
物理学 | 7487篇 |
出版年
2024年 | 21篇 |
2023年 | 166篇 |
2022年 | 376篇 |
2021年 | 401篇 |
2020年 | 556篇 |
2019年 | 512篇 |
2018年 | 474篇 |
2017年 | 516篇 |
2016年 | 603篇 |
2015年 | 497篇 |
2014年 | 624篇 |
2013年 | 1036篇 |
2012年 | 808篇 |
2011年 | 864篇 |
2010年 | 749篇 |
2009年 | 745篇 |
2008年 | 760篇 |
2007年 | 732篇 |
2006年 | 697篇 |
2005年 | 602篇 |
2004年 | 570篇 |
2003年 | 493篇 |
2002年 | 572篇 |
2001年 | 421篇 |
2000年 | 368篇 |
1999年 | 281篇 |
1998年 | 240篇 |
1997年 | 184篇 |
1996年 | 154篇 |
1995年 | 112篇 |
1994年 | 116篇 |
1993年 | 73篇 |
1992年 | 86篇 |
1991年 | 63篇 |
1990年 | 48篇 |
1989年 | 46篇 |
1988年 | 45篇 |
1987年 | 30篇 |
1986年 | 37篇 |
1985年 | 39篇 |
1984年 | 39篇 |
1983年 | 18篇 |
1982年 | 23篇 |
1981年 | 13篇 |
1980年 | 13篇 |
1979年 | 7篇 |
1978年 | 19篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1973年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
David Fryberger 《Foundations of Physics Letters》1990,3(4):379-386
Issues raised by W. A. Rodrigues, Jr. are discussed.1. This is not a new result; see,e.g., Rohrlich.(3)
2. A typographical error in Eq. (77) is corrected here: The productj A in the right-hand parentheses was erroneously transcribed in Ref. (2) as
A.3. I define electromagnetic fieldF = A to be that generated by electric charges and the magnetoelectric fieldG = M to be that generated by magnetic monopoles:F F +5
G.
4. Rodrigues, on the other hand, takes the position that the importance of the Lagrangian formulation should be downgraded if not discarded altogether: ... it is redundant to look for Lagrangians.(1)
5. In fact, he reformulates it using the language of differential forms.6. It is interesting to observe that this bilinear form has the additional virtue of being appropriate for dealing with the monopolecharge parity question, which was pointed out long ago.(14)
7. In fact, even mathematics looks to Nature for its authority.(16) There is evidence that Rodrigues does not understand this concept.(17) 相似文献
12.
合成和表征了一种新的Schiff碱配合物MnL(ClO4)*3H2O(1)(其中L为n(水杨醛)∶n(二乙撑三胺)=1∶1缩合而成的Schiff碱).1与FeSO4*7H2O和K3[Fe(ox)3]*3H2O(ox=oxalate)进一步反应,生成了双金属层状配位聚合物{[MnL][FeⅡFeⅢ(ox)3]*1.5H2O}∞(2).IR和Mssbauer谱测定结果表明,2具有二维层状结构,其阴离子层由[FeⅡFeⅢ(ox)3]-单元构成.变温磁化率(5K~100K)测试结果表明,2中的自旋载体之间存在反铁磁交换作用.5K时的磁滞现象表明2在低温时可能存在铁磁有序,这可能是亚铁磁或自旋倾斜造成的. 相似文献
13.
Malykhina L. V. Prosvirin A. V. Haase W. Galyametdinov Yu. G. 《Russian Chemical Bulletin》2001,50(3):488-493
The reaction of Schiff"s base L with lanthanide alkylsulfates affords liquid crystalline complexes with the general formula L3Ln(CnH2n+1OSO3)3. The liquid crystalline structure and magnetic properties are studied by polarization thermal microscopy, differential scanning calorimetry, X-ray diffraction, and measurement of magnetic susceptibility. The temperatures of the existence of the mesophase and magnetic anisotropy of the complexes with the same lanthanide depend on the chain length of the alkyl fragment in the sulfate anion. 相似文献
14.
Y. Kuwahara H. Fukami R. Howard S. Ishii F. Matsumura W.E. Burkholder 《Tetrahedron》1978,34(12):1769-1774
Chemical an spectroscopic evidence is presented to show that 2,3-dihydro-2,3,5-trimethyl-6-(1-methyl-2-oxobutyl)-4H-pyran-4-one (10) is the sex pheromone produced by the female drugstore beetle, Stegobium paniceum L. 相似文献
15.
The Reaction of SeCl4 with Transition Metal Tetrachlorides. Synthesis and Crystal Structures of (SeCl3)2MCl6 with M = Zr, Hf, Mo, Re The transition metal tetrachlorides ZrCl4, HfCl4 and MoCl4 react with SeCl4 in closed ampoules at temperatures of 140°C to (SeCl3)2MCl6 (M = Zr, Hf, Mo) which are all isotypic and crystallize in the (SeCl3)2ReCl6 structure type (orthorhombic, Fdd2, Z = 8, lattice constants for M = Zr: a = 1165.7(1)pm, b = 1287.2(2)pm, c = 2180.2(2)pm; for M = Hf: a = 1162.9(2)pm, b = 1285.0(2)pm, c = 2178.2(3)pm; for M = Mo: a = 1153.8(1)pm, b = 1267.7(1)pm, c = 2147.4(2)pm). The Cl? ions form a hexagonal closest packing with one fourth of the octahedral holes filled by Se4+ and M4+ in an ordered way. The MCl6 octahedra are regular, the SeCl6 octahedra are distorted with 3 short and 3 long Se? Cl bonds (mean 215 pm and 287 pm). The structures can thus be regarded as built of SeCl3+ and MCl62? ions. Magnetic susceptibility measurements show for M = Zr the expected diamagnetic behavior, for M = Mo and Re paramagnetic behavior according to the Curie-Weiss law with magnetic moments of 2.5 B. M. for M = Mo and 3.7 B. M. for M = Re corresponding to 2 and 3 unpaired electrons respectivly. 相似文献
16.
O. G. Shakirova D. Yu. Naumov Yu. G. Shvedenkov N. I. Alferova G. V. Dolgushin L. G. Lavrenova 《Journal of Structural Chemistry》2003,44(4):642-649
A new trinuclear nickel(II) complex with 4-(pyridyl-2)-1,2,4-triazole (pytrz), [Ni3(pytrz)6(H2O)6](NO3)6, has been synthesized, and its crystal structure has been determined. The compound was studied by X-ray phase analysis (XRPA), magnetochemical measurements, and electronic and IR spectroscopy. 相似文献
17.
18.
Proton relaxation time measurements are performed for 6m aqueous solutions of7LiI and6LiI in D2O containing small amounts of H2O. The measurements are done at low temperatures and yield maxima of the relaxation rate plotted against 1/T. From the maxima of the relaxation rates, proteon-I– and proton-Li+ distances in the first coordination sphere of the ions are determined, and from the knowledge of the ion-water oxygen distance it is shown that for iodide a somewhat broadened H-bonded configuration is valid and that for Li+ the electric dipole orientation deviates from the radial direction. In order to test the reliability of the method a proton-127I interaction study is also performed in KI solution in glycerol. The I-H distance obtained is in satisfactory agreement with that found in the aqueous system. 相似文献
19.
DySBr and DySI – Synthesis, Crystal Structure, and Magnetism By reaction of Dy2S3 with Dy metal and Br2 (I2) at 750°C (900°C), single phase crystalline DySBr (DySI) has been synthesized. Crystal structure refinement of DySBr confirms the FeOCl-type structure (R = 0.049; space group Pmmn, Z = 2, lattice parameters (in Å): a = 5.349(2), b = 4.079(2), c = 8.066(2)) which is also ascertained for DySI (R = 0.059; lattice parameters (in Å): a = 5.320(2), b = 4.168(1), c = 9.224(5)). The magnetic susceptibilities (temperature range 3.4 K – 295 K) can be described on the basis of simple models (cubic crystal field, molecular field approximation) above 5 K and 15 K respectively. The deviations at low temperature are assumed to be related essentially to Dy—Dy exchange interactions which are not adequately described with the molecular field approach. 相似文献
20.
Jos R. Ascenso Maria de Deus Carvalho Alberto R. Dias Carlos C. Romo Maria J. Calhorda Luis F. Veiros 《Journal of organometallic chemistry》1994,470(1-2):147-152
The metallocene thioether derivatives [Cp2M(MeSCH2CH2SMe)][PF6]2 (1, M = MO; 2, M = W), [Cp2Mo(SCH2CH2SMe)][PF6] (3) and [Cp2M(SCH2CH2S)] (4, M = Mo; 5, M = W) exhibit temperature-dependent fluxional behavior in solution, owing to the pyramidal sulfur inversion process. The activation energies for this process were determined from proton band-shape analysis in the cases of 1 (54.9 ± 2 kJ mol−1), 2 (51.2 ± 4.6 kJ mol−1) and 3 (30.0 ± 3.1 kJ mol−1). Extended Hückel calculations on related model complexes suggest that local inversion at the sulfur atoms, rather that an inversion of the complete S---C---C---S chain, is responsible for the observed fluxional behaviour. 相似文献