表面氧钝化碳化硅纳米团簇电子结构和光学性质的第一性原理研究

基于密度泛函理论(DFT)和广义梯度近似(GGA),对氧钝化条件下4H-SiC纳米团簇的电子结构和光学性质进行了研究。计算了不同直径的4H-SiC纳米球氧钝化后的能带结构、电子态密度和光学性质。团簇的尺度在0.4~0.9 nm之间,构建表面仅存在硅氧双键和表面仅存在碳氧双键的两种模型。研究表明硅氧双键和碳氧双键所引起的缺陷态位于原4H-SiC的价带和导带之间,并且缺陷态与价带顶的能量差随纳米团簇颗粒直径的增大而减小;缺陷态主要是由Si原子外层电子和氧原子外层电子轨道杂化引起的。同时,由于氧的存在,对碳化硅的结构产生一定的影响,这也是缺陷态形成的一个原因。另外,碳氧双键和硅氧双键钝化对4H-SiC纳米团簇的光学性质有着不同的影响。在表面仅存在C=O的情况下,4H-SiC纳米团簇表现出各向同性的性质。在表面仅存在Si=O的情况下,4H-SiC纳米团簇表现出各向异性的性质。     

Synthesis methods of multiple phase-cycled SSFP images to reduce the band artifact and noise more reliably

The band artifact in steady-state free precession can be reduced by synthesizing the multiple images obtained through different phase increments of successive radiofrequency pulses. Even though the complex summation method was reported to be effective in reducing the band artifact, it has the pitfalls of intensity abnormality and sensitivity to the phase abnormality. Two new methods have been developed for more reliable reduction of the band artifact than the complex summation method. One method is to sum the complex images partially and to take the maximum intensity of the partially summed images. The other method is to sum the free induction decay (FID) and primary echo components of the Fourier series that are obtained through Fourier analysis of the complex base images. Both proposed methods were compared with other magnitude (maximum intensity projection, spectrally decomposed synthesis, sum-of-squares, nonlinear averaging) and complex-based (complex summation, magnitude-weighted complex summation) methods experimentally at 3 T for the phantom and volunteer's head imaging. Both proposed methods were confirmed to maintain the advantage of the complex summation in reducing both the dark and bright band artifacts while reducing the intensity abnormality and sensitivity to the phase abnormality from that of the complex summation method over a wide range of flip angles and relaxation times.     

Constraining WIMP magnetic moment from CDMS II experiment

We consider a degenerate or a nearly degenerate dark matter sector where a sizable magnetic moment of a (almost) Dirac type neutral dark matter candidate N is anticipated. Then, due to soft photon exchange, the cross-section in direct detection of N   can be enhanced at low Q²$Q^2$ region. We discuss the implication of this type of models in view of the recent CDMS II report.     

一种新型的双向长距离光纤混沌保密 通信系统性能研究

基于两个在驱动混沌信号注入下的响应半导体激光器之间的混沌同步, 提出了一种新型的可实现信息双向、长距离保密传输的系统, 并建立了相应的理论模型. 利用该理论模型, 研究了系统的双向传输性能、 安全性能以及系统性能随传输距离的变化. 结果表明: 两个响应激光器在受到发自同一驱动混沌激光器的混沌光注入下, 其混沌输出虽然与注入混沌信号相差很大, 但两个响应激光器的混沌输出却能实现非常好的无时间延迟的等时同步; 对窃听者可能获取信息的各个途径进行了考察, 结果显示该系统具有很好的安全性; 采用普通单模光纤作为传输信道, 信息经过50 km传输后, 解调信息Q因子可达到6以上; 采用色散位移光纤, 信息经过200 km的传输, 解调信息Q因子还可达6以上.     

电光调制对外部光反馈垂直腔表面发射激光器输出矢量混沌偏振的操控

基于周期性极化铌酸锂晶体的线性电光效应耦合波理论,数值研究了电光调制对外部光反馈垂直腔表面发射激光器(VCSEL)输出矢量混沌偏振模的操控.研究结果表明,VCSEL输出的偏振度随着电光晶体的长度或施加于电光晶体的外电场强度成周期性转换,控制一定的施加外电场强度和晶体的长度,激光器的不同参数下引起初始混沌偏振态都可以转换为其他任意混沌偏振态.特别是合理选择一定的施加外电场强度或晶体长度,VCSEL输出的任意混沌偏振模可以转换为完全一致的两线性混沌偏振模(x和ŷ偏振),即两线性混沌偏振模的能量能够达到稳定和完全均衡.     

二氧化钛修饰的微结构聚合物光纤预制棒制备及其在光催化中应用的探索研究

首次用二氧化钛(TiO₂)纳米材料修饰的547孔微结构聚合物光纤(MPOF)二次预制棒作为阵列化微管式光催化反应器对亚甲基兰的光催化分解进行研究.将高光催化活性的P25型二氧化钛纳米粒子均匀分散在TiO₂溶胶中,对547孔微结构聚合物光纤孔洞内壁进行铺膜,得到了负载光催化剂的阵列化微管材料.该TiO₂MPOF有序复合的阵列化微管不仅对二氧化钛纳米粒子起到负载作用,还可以作为光波导介质(rolling-up薄膜波导,聚光、导光进入二氧化钛薄膜层)、污染物反应流体通道.以有机染料亚甲基兰为模拟污染物,研究了TiO₂负载量、亚甲基兰的初始浓度及溶液pH值等因素对光降解效果的影响.该反应器547个孔道的内表面用于负载光催化剂,不仅增加了固-液接触面积,也提高了光的吸收效率,从而提高了光催化效率.迄今为止,这种兼具导光、聚光、传质、负载功能于一体的光催化反应器还未见报道.     

Approximating the maximum 2- and 3-edge-colorable subgraph problems

For a fixed value of a parameter k≥2, the Maximum k-Edge-Colorable Subgraph Problem consists in finding k edge-disjoint matchings in a simple graph, with the goal of maximising the total number of edges used. The problem is known to be -hard for all k, but there exist polynomial time approximation algorithms with approximation ratios tending to 1 as k tends to infinity. Herein we propose improved approximation algorithms for the cases of k=2 and k=3, having approximation ratios of 5/6 and 4/5, respectively.     

On the complexity of some subgraph problems

We study the complexity of the problem of deciding the existence of a spanning subgraph of a given graph, and of that of finding a maximum (weight) such subgraph. We establish some general relations between these problems, and we use these relations to obtain new NP-completeness results for maximum (weight) spanning subgraph problems from analogous results for existence problems and from results in extremal graph theory. On the positive side, we provide a decomposition method for the maximum (weight) spanning chordal subgraph problem that can be used, e.g., to obtain a linear (or O(nlogn)) time algorithm for such problems in graphs with vertex degree bounded by 3.     

-extension of Lie triple systems

In this paper, we introduce the notion of T^*-extension of a Lie triple system. Then we show that T^*-extension is compatible with nilpotency, solvability, and it preserves in certain sense the decomposition properties. In addition, we investigate the equivalence of T^*-extensions using cohomology. Finally, we show that every finite-dimensional nilpotent metrised Lie triple system over an algebraically closed field is the T^*-extension of an appropriate quotient system.