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81.
Multiwalled carbon nanotubes were modified by carboxy groups. Four independent methods for the determination of the degree
of functionalization of the surface were proposed: 13C NMR spectroscopy, thermogravimetry, titrimetry, and fluorimetry. The first two methods show the total content of carboxy
groups in the sample, and the latter two methods give information about the content of the surface groups only.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 291–295, February, 2008. 相似文献
82.
83.
The paper analyzes new publications on the brittle fracture mechanics of prestressed materials. It is found out that new scientific results published in the International Journal of Solids and Structures in 2002 are a particular case of the results obtained at the Institute of Mechanics 20 years ago 相似文献
84.
Monica Sorescu L Diamandescu D Tarabasanu-Mihaila 《Journal of Physics and Chemistry of Solids》2004,65(10):1719-1725
α-Fe2O3-In2O3 mixed oxide nanoparticles system has been synthesized by hydrothermal supercritical and postannealing route, starting with (1−x)Fe(NO3)3·9H2O·xIn(NO3)3·5H2O aqueous solution (x=0-1). X-ray diffraction and Mössbauer spectroscopy have been used to study the phase structure and substitutions in the nanosized samples. The concentration regions for the existence of the solid solutions in the α-Fe2O3-In2O3 nanoparticle system together with the solubility limits of In3+ ions in the hematite lattice and of Fe3+ ions in the cubic In2O3 structure have been evidenced. In general, the substitution level is considerably lower than the nominal concentration x. A justification of the processes leading to the formation of iron and indium phases in the investigated supercritical hydrothermal system has been given. 相似文献
85.
Cristian Barbarosie Anca‐Maria Toader 《Mathematical Methods in the Applied Sciences》2005,28(9):1089-1114
We prove bounds on the homogenized coefficients for general non‐periodic mixtures of an arbitrary number of isotropic materials, in the heat conduction framework. The component materials and their proportions are given through the Young measure associated to the sequence of coefficient functions. Upper and lower bounds inequalities are deduced in terms of algebraic relations between this Young measure and the eigenvalues of the H‐limit matrix. The proofs employ arguments of compensated compactness and fine properties of Young measures. When restricted to the periodic case, we recover known bounds. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
86.
S. A. Patlazhan 《Journal of Polymer Science.Polymer Physics》1993,31(12):1649-1665
A statistical theory of light scattering from deformed isotropic and textured heterogeneous polymer materials is formulated. Two types of textured structures are analyzed: assemblies of optically isotropic and anisotropic rods and a spatially anisotropic distribution of isotropic spherical inclusion centers. The small-angle Hv light-scattering patterns are calculated. The appearance of scattering from isotropic rods and spheres in deformed materials has been demonstrated. The changes of the Hv scattering patterns as a function of elongation and strucuture parameters are discussed. © 1993 John Wiley & Sons, Inc. 相似文献
87.
二硼化镁(MgB2)超导体在非铜氧化物陶瓷超导体中具有最高临界转变温度,给超导应用带来了新的契机.铁与镁不反应,且价格低廉,在需要热处理的超导成材工艺中,常常采用铁作MgB2的基底;然而,这种高磁导率的材料有可能增大基底的损耗.本文采用有限元分析软件ANSYS计算了工频下不同材料基底超导圆线传输交流的基底损耗,分析了基底损耗与电流大小、基底厚度之间的关系,对双层基底的损耗也进行了研究.本文的结果对于适当选取截面尺寸、基底材料和工作电流以期减小交流损耗,具有一定参考意义. 相似文献
88.
I.V. Kityk A. Ali Umar M. Oyama 《Physica E: Low-dimensional Systems and Nanostructures》2005,27(4):420-426
We have found that the gold nanoparticles on the ITO substrates might be considered promising materials for circularly polarized light-induced linear electrogyration (EG). The maximal achieved value of the EG susceptibility described by third-order axial tensor caused by probe circularly polarized light at a wavelength of 1060 nm was equal to about 13 deg/mm at pulsed electric field strength 30.0 V/cm with a duration of about 1 ms. We have revealed that the maximal EG coefficient is achieved for the samples possessing maximal resistivity. The investigated composites possess long-lived EG grating which decreases by not more than 12% after 120 min of laser treatment. Applying a non-circular pump light leads to the diminishing of the observed EG. 相似文献
89.
We study the aggregation of oxygen dipoles well dispersed in a CaF2 crystal upon annealing at temperatures ranging from 370 to 420 K. The concentration of oxygen dipoles is monitored by measuring the intensity of the ionic thermocurrent peak as well as by absorption and luminescence spectroscopies. Results from three methods agree within experimental error and yield an activation energy of (1.2±0.1) eV for the diffusion of isolated oxygen centres in the crystal. 相似文献
90.
K7[P2Mo4W13M(H2O)O61]及其有机复合材料的合成及光谱研究 总被引:1,自引:1,他引:0
用降解法制得了Dawson结构铬、铁取代的磷钼钨酸钾,并将其与溴化(E)-N-丁基-4-(2-(4-二甲氨基苯基)乙烯基)吡啶反应制备了有机复合材料.通过元素分析和TG-DTA确定了配合物的组成分别为K7[P2Mo4W13M(H2O)O61](M=Cr(1),Fe(2))和(C19H25N2)6K3[P2Mo4W13MO62](M=Cr(3),Fe(4)).利用红外光谱、紫外-可见光谱、固体漫反射紫外-可见-近红外光谱、X射线光电子能谱以及荧光光谱对上述化合物进行了表征,并研究了复合材料中无机与有机组分间的相互作用及其荧光性质. 相似文献