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71.
A stable model category is a setting for homotopy theory where the suspension functor is invertible. The prototypical examples are the category of spectra in the sense of stable homotopy theory and the category of unbounded chain complexes of modules over a ring. In this paper we develop methods for deciding when two stable model categories represent ‘the same homotopy theory’. We show that stable model categories with a single compact generator are equivalent to modules over a ring spectrum. More generally stable model categories with a set of generators are characterized as modules over a ‘ring spectrum with several objects’, i.e., as spectrum valued diagram categories. We also prove a Morita theorem which shows how equivalences between module categories over ring spectra can be realized by smashing with a pair of bimodules. Finally, we characterize stable model categories which represent the derived category of a ring. This is a slight generalization of Rickard's work on derived equivalent rings. We also include a proof of the model category equivalence of modules over the Eilenberg-Mac Lane spectrum HR and (unbounded) chain complexes of R-modules for a ring R. 相似文献
72.
The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
73.
A. V. Tarasov P. O. Yablonsky Yu. A. Moskvichev 《Chemistry of Heterocyclic Compounds》2003,39(1):119-122
Various methods were studied for the oxidation of 2-methyl-5-(phenylsulfonyl)benzenesulfamide and its derivatives. The oxidation by sodium dichromate in sulfuric acid was found most efficient. The effects of temperature, concentration, reagent ratio, and time of the oxidation reaction on the yield of the desired product were investigated. Conditions were proposed for obtaining the desired product in yields up to 95%. A synthesis was developed for a series of new saccharin derivatives. 相似文献
74.
We develop a new joint cure rate model for longitudinal and survival data. The model allows for multiple longitudinal markers as well as a cure structure for the survival component based on the promotion time cure rate model, as described in Ibrahim et al. (Bayesian Survival Analysis, Springer, New York, 2001). Several characteristics and properties of the new model are discussed and examined. A real dataset from a melanoma clinical trial is given to demonstrate the methodology. 相似文献
75.
Gravimetric measurements of thermodesorption of n-hexane and n-heptane were performed under quasi-equilibrium conditions. Differential thermodesorption profiles for ZSM-5 and ZSM-11 showed two peaks, but for Y zeolites, only one thermodesorption peak was observed. A model function, derived from the Langmiur adsorption model, was fitted to the experimental data, and the model parameters (the adsorption entropy and enthalpy) were estimated. The two-step desorption profiles observed for ZSM-5 and ZSM-11 were attributed to the commensurate freezing effect, i.e. a transition in the adsorbed phase resulting in ordering of the adsorbed molecules in the zeolite channels. The results observed for ZSM-11 indicate that the zigzag channels typical for ZSM-5 micropore system are not necessary for this transition to occur. 相似文献
76.
77.
Mohamed Haouas Amine Harrane Mohamed Belbachir Francis Taulelle 《Journal of Polymer Science.Polymer Physics》2007,45(22):3060-3068
Results of multinuclear MAS NMR spectroscopy are reported for poly (ε‐caprolactone)/maghnite nanocomposite formation, with ε‐caprolactone in situ polymerized in the presence of maghnite, a proton exchanged montmorillonite clay. Exfoliated and intercalated materials with different maghnite loading in the range 3–15 wt % were investigated. 1H NMR evidences Brønsted acid hydroxyl groups in the silicate layers and shows that their broad signal at 7.6 ppm present in the parent clay disappears in the nanocomposite material. 27Al MAS NMR results show that beside the hexacoordinated aluminum signal, two additional peaks corresponding to two different tetrahedral Al sites are present in the clay framework. The NMR signal intensity of only one of them was found to be affected in the nanocomposites compared with the parent maghnite, suggesting that these specific aluminum sites are the reactive ones at the initial stages of the polymerization. However almost no changes occurred in the 29Si NMR spectra, confirming that the polymer grafting, as indicated earlier by atomic force microscopy, took place on the aluminum tetracoordinated sites rather than on the silicon sites. A mechanism of maghnite surface catalyzed polymerization of ε‐caprolactone was proposed, involving Brønsted and Lewis acid sites. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3060–3068, 2007 相似文献
78.
研究了钍与5-(对羧基苯偶氮)-8-羟基喹啉(5-CPAHQ)的显色反应条件:在阳离子表面活性剂十六烷基三甲基溴化铵(CTMAB)存在下,pH4.4-5.4缓冲介质中,形成稳定的橙红色络合物,最大吸收波长为490nm,ε=1.10×105L·mol-1·cm-1,钍在0-9μg/25mL范围内符合比尔定律。用TBP萃淋树脂分离,该方法可用于测定矿石中的微量钍。 相似文献
79.
80.
项斯端 《浙江大学学报(理学版)》2004,31(1):88-97
根据KIM和LEE(1999)将多管藻属分为两独立属新管藻及多管藻,报道了我国14种及1变种1变型多管藻,以及11种新管藻,其中19种为我国新记录,发表了新种垫状多管藻(Polysiphonia caespitosa sp.nov)及新变种岩生多管藻长节变种(P.scopulorum var.longinodium var.nov.). 相似文献