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51.
A direct kinetic study is reported for the electrophilic amination of substituted phenylmagnesium bromides with N,N‐dimethyl O‐(mesitylenesulfonyl)hydroxylamine in THF. Rate data, Hammett relationship, and activation entropy are consistent with a SN2 displacement involving the attack of carbanions to sp3N in the amination reagent (AR). Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
52.
Zhi-Gang Wang 《The European Physical Journal C - Particles and Fields》2009,61(2):321-329
We calculate the masses and the pole residues of the
heavy baryons Ω
c
0(css) and Ω
b
−(bss) with the QCD sum rules. The numerical values
GeV (or
GeV) and
GeV (or
GeV) are in good agreement with the experimental data. 相似文献
53.
A. G. Knospe 《The European Physical Journal C - Particles and Fields》2009,62(1):223-227
Heavy-flavor semileptonic decays are expected to dominate the spectrum of non-photonic electrons produced from collisions
at the energies of the Relativistic Heavy Ion Collider. The non-photonic electron yield is suppressed by approximately a factor
of 5 in central Au + Au events at
GeV relative to p+p events with the same collision energy. Most theoretical models predict less non-photonic-electron suppression than is observed
experimentally. We present a preliminary measurement of the yield of non-photonic electrons in Cu + Cu events at
GeV, as well as the nuclear modification factor. 相似文献
54.
A three-dimensional (3D) spherical acoustic cloak is designed using an acoustic layered system, which can hide an object from
the detection of acoustic wave in arbitrary direction. The cloak is constructed from multilayered concentric spherical shells
filled with homogeneous isotropic materials. Based on spherical wave expansion method, we confirm that significant low-reflection,
acoustic-shadow-reducing, and wavefront-bending effects in 3D space can be achieved by the proposed cloak. The angle distribution
of the scattered wave is further evaluated by the far-field scattering pattern. In addition, the cloak is demonstrated to
work efficiently in a wide bandwidth in which the cloaking efficiency decreases with increasing frequency. This study may
be helpful to design high-performance 3D acoustic cloaks for broadband acoustic waves in all incidence directions. 相似文献
55.
X. Deng R. Citro E. Orignac A. Minguzzi 《The European Physical Journal B - Condensed Matter and Complex Systems》2009,68(3):435-443
Using exact diagonalisation and Density Matrix Renormalisation group (DMRG) approach we analyse the transition to a localised
state of a weakly interacting quasi-1D Bose gas subjected to a quasiperiodic potential. The analysis is performed by calculating
the superfluid fraction, density profile, momentum distribution and visibility for different periodicities of the second lattice
and in the presence (or not) of a weak repulsive interaction. It is shown that the transition is sharper towards the maximally
incommensurate ratio between the two lattice periodicities, and shifted to higher values of the second lattice strength by
weak repulsive interactions. We also relate our results to recent experiments. 相似文献
56.
J. Beals N. Bamiedakis A. Wonfor R. V. Penty I. H. White J. V. DeGroot K. Hueston T. V. Clapp M. Glick 《Applied Physics A: Materials Science & Processing》2009,95(4):983-988
An optical backplane based on a meshed polymer waveguide architecture enabling high-speed board-to-board optical interconnection
is presented. This planar array of multimode polymer waveguides can provide passive strictly non-blocking links between server
line cards fitted with optical transmitter and receiver arrays. This architecture offers a scalable and low-cost solution
to the bandwidth limitations faced by electrical backplanes and is suitable for PCB integration. The reported backplane demonstrator
uses a matrix of 100 waveguides each capable of 10 Gb/s operation to interconnect 10 cards for a total capacity of a terabit
per second aggregate data rate in multicast mode. Characterisation of the backplane demonstrator reveals low link losses of
2 to 8 dB for a multimode fibre input and crosstalk values below −35 dB. Error free data transmission at 10 Gb/s is achieved
with a power penalty of only 0.2 dB at a bit-error-rate of 10−9. Additionally, lossless operation of a Gigabit Ethernet link over the backplane is achieved even when using the worst-case
highest loss links. 相似文献
57.
Yu-Chia Chang Larry A. Coldren 《Applied Physics A: Materials Science & Processing》2009,95(4):1033-1037
High-efficiency, high-speed, tapered-oxide-apertured vertical-cavity surface-emitting lasers (VCSELs) emitting at 980 nm have
been demonstrated. By carefully engineering the tapered oxide aperture, the mode volume can be greatly reduced without adding
much optical scattering loss for the device sizes of interest. Consequently, these devices can achieve higher bandwidth at
lower current and power dissipation. In addition, the parasitics are reduced by implementing deep oxidation layers and an
improved p-doping scheme in the top mirror. Our devices show modulation bandwidth exceeding 20 GHz, a record for 980 nm VCSELs. Moreover,
35 Gb/s operation has been achieved at only 10 mW power dissipation. This corresponds to a data-rate/power-dissipation ratio
of 3.5 Gbps/mW. Most importantly, our device structure is compatible with existing manufacturing processes and can be easily
manufactured in large volume making them attractive for optical interconnects. 相似文献
58.
Chongfeng Guo Shuiting Wang Tao Chen Lin Luan Yan Xu 《Applied Physics A: Materials Science & Processing》2009,94(2):365-371
A series of double molybdates phosphors AEu(MoO4)2 (A = Li, Na, K and Ag) have been prepared by sol-gel method. Their crystal structure and luminescent properties have also
been investigated in a comparable way. The crystallization processes of the phosphor precursors were characterized by X-ray
diffraction (XRD) and thermogravimetry-differential thermal analysis (TG-DTA). Field emission scanning electron microscopy
(FE-SEM) was also used to characterize the shape and size distribution of the phosphors. Samples except KEu(MoO4)2 showed tetragonal scheelite structure in the range of our experiments, and no phase transition appeared. Phosphor KEu(MoO4)2 possessed two structures, and the phase transition took place at about 800°C. All samples with high purity could be obtained
at about 500°C for 5 hours, and they all showed intense red light peaked at 616 nm originated from 5D0→7F2 emission of Eu3+ under the excitation of 465 nm or 394 nm light. The excitation spectra of phosphors AEu(MoO4)2 (A = Li, Na, and K) are composed of a strong broad charge transfer (CT) band and some sharp lines, and the relative intensity
of CT band, the two strongest absorption lines at 395 nm and 465 nm are comparative, so these three phosphors are good red
phosphor candidates for violet or blue LEDs. For the excitation spectrum of phosphor AgEu(MoO4)2, intensities of CT band and the absorption line at 395 nm are much weaker than that of line at 465 nm, thus phosphor AgEu(MoO4)2 is only suit for GaN-based blue LED. 相似文献
59.
D. Do S. S. Kim S. W. Yi J. W. Kim 《Applied Physics A: Materials Science & Processing》2009,94(3):697-701
Ferroelectric and dielectric properties of bilayered ferroelectric thin films, SrBi4Ti4O15 grown on Bi4Ti3O12, were investigated. The thin films were annealed at 700°C under oxygen atmosphere. The bilayered thin films were prepared
on a Pt(111)/Ti/SiO2/Si substrate by a chemical solution deposition method. The dielectric constant and dielectric loss of the bilayered thin
films were 645 and 0.09, respectively, at 100 kHz. The value of remnant polarization (2P
r) measured from the ferroelectric thin film capacitors was 60.5 μC/cm2 at electric field of 200 kV/cm. The remnant polarization was reduced by 22% of the initial value after 1010 switching cycles. The results showed that the ferroelectric and dielectric properties of the SrBi4Ti4O15 on Bi4Ti3O12 ferroelectric thin films were better than those of the SrBi4Ti4O15 grown on a Pt-coated Si substrate suggesting that the improved properties may be due to the different nucleation and growth
kinetics of SrBi4Ti4O15 on the c-axis-oriented Bi4Ti3O12 layer or on the Pt-coated Si substrate. 相似文献
60.
Takashi Harumoto Javed Iqbal Xiaofang Liu Ji Shi Yoshio Nakamura Ronghai Yu 《Applied Physics A: Materials Science & Processing》2009,97(1):211-215
Co doped SnO2 nanoparticles have been prepared via a wet chemical method with different precipitation processes. The structure and morphology
of Co doped SnO2 nanoparticles demonstrate that the nanoparticles are in a rutile single phase and uniform, respectively. X-ray photoelectron
spectroscopy shows that the Co dopants are in 2+ oxidation valence state and doped ∼2 atm% in SnO2 nanoparticles. Moreover, Raman spectroscopy further confirms that Co doped SnO2 nanoparticles have single phase crystallinity without forming any extra modes related to secondary phases. The magnetic measurements
reveal that all nanoparticles exhibit room temperature ferromagnetism (RTFM) due to the presence of disorders and defects
introduced by hydroxyls in the crystal structure. In addition, it has been clearly observed that the saturated magnetic moments
are strongly affected by the precipitation processes which control the incorporation of hydroxyls into the lattice. 相似文献