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排序方式: 共有173条查询结果,搜索用时 81 毫秒
171.
Doris Pospiech Liane Häußler Dieter Jehnichen Wolfram Kollig Kathrin Eckstein Karina Grundke 《Macromolecular Symposia》2003,198(1):421-434
The goal of the investigation presented here is the development of extremely hydrophobic materials based on polysulfone that can be applied, for instance, as fouling-resistant membrane materials. The concept used is the addition of semifluorinated polymers to polysulfone in suitable blend compositions. The influence of molecular parameters like chain structure of the semifluorinated polymer (segmented block copolymers, random copolymers) and segment molecular weight on the state of phase separation in the bulk and its influence on the surface properties have been systematically examined. It could be shown that segmented block copolymers with semifluorinated polyester segments with intermediate segment molecular weight are more suitable in blends with polysulfone than random polysulfone copolymers having semifluorinated side chains with respect to form homogeneous thin films (coatings) with highly non-wetting properties. 相似文献
172.
C. Raghunatha Nishant R. Chirania M. Niranjan A. R. Usha Devi S. A. Rangwala Sarbari Bhattacharya 《Macromolecular Symposia》2024,413(1):2300030
Self-organization can be defined as a process of arrangement of entities that start out in an irregular arrangement and evolve into a stable, regular pattern without the aid of an external agent. A system of magnetic particles that are constrained to move only in a plane is reported. The individual components in the system have dipole moments in an orientation perpendicular to the plane of motion and the interaction between components is purely repulsive. For such a system, it is attempted to understand the influence of the boundary of the monolayer on the patterns that emerge. A system with a small number of magnets is found where the range of the magnetic interactions is of the size of the boundary; the symmetry of the boundary imposed on the monolayer plays a crucial role in determining the pattern types, the number of different pattern types, and the frequency of appearance of a particular pattern type. The effect of scaling up the size of the system while maintaining the characteristics of individual components as well as the component areal density is also discussed. 相似文献
173.
《Mendeleev Communications》2023,33(1):86-89
The effect of crystallization of a hydrophobic poly(lactide) block on the self-organization of biocompatible and biodegradable amphiphilic poly(lactide)-block-poly(ethylene oxide) (PLA-b-PEO) copolymers in a dilute aqueous solution has been investigated. It was demonstrated that the co-crystallization of poly(L,L-lactide) [P(L,L)LA] and poly(d,d-lactide) [P(d,d)LA] chains under equimolar mixing of P(L,L)LA46-b-PEO113 and P(d,d)LA56-b-PEO113 copolymers resulted in the formation of stable and spontaneously water-redispersible stereocomplex micelles with semicrystalline P(L,L)LA/P(d,d)LA cores. It was shown that the P(L,L)LA46 / P(d,d)LA56-b-PEO113 stereo-complex micelles produced by dialysis can be potential vehicles for the anticancer agent oxaliplatin 相似文献