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991.
In recent papers [S. Dhompongsa, T. Domínguez-Benavides, A. Kaewcharoen, A. Kaewkhao, B. Panyanak, The Jordan–von Neumann constants and fixed points for multivalued nonexpansive mappings, J. Math. Anal. Appl. 320 (2006) 916–927; S. Dhompongsa, A. Kaewcharoen, A. Kaewkhao, The Domínguez–Lorenzo condition and multivalued nonexpansive mappings, Nonlinear Anal. 64 (2006) 958–970], two sufficient conditions, namely the Domínguez–Lorenzo condition and property (D), for fixed points of multivalued nonexpansive mappings are introduced. The authors also give some sufficient conditions for the Domínguez–Lorenzo condition and property (D). In their proofs, it seems reasonable to use the James and von Neumann–Jordan constants. With slight modifications, significant improvements are obtained. Some new estimates are tight in Hilbert spaces. 相似文献
992.
A.M. Issam 《European Polymer Journal》2007,43(1):214-219
3,4-Di-(2′-hydroxyethoxy)-4′-nitrobenzylidene II was prepared by condensation reaction of 3,4-dihydroxy-4′-nitrobenzylidene I with 1-chloro-2-ethanol. Monomer II was reacted with p-phenylene diisocyanate to yield polyurethane containing the non-linear optical chromophore 3,4-di-(2′-hydroxyethoxy)-4′-nitrobenzylidene. Polymer III shows thermal stability up to 300 °C in TGA thermogram. Tg value of the polymer obtained from DSC thermogram was 110 °C. The resulting polyurethane III was soluble in common organic solvents such as acetone, DMF and DMSO. The values of electro optic coefficient d33 and d31 of the poled polymer film were 3.15 × 10 −7 and 1.5 × 10 −7 esu, respectively. 相似文献
993.
(1,1-Dihydroperfluoroalkyl)phenyliodonium N,N-bis(trifluoromethylsulfonyl)imides (4, n = 0-2) were synthesized and used to transfer the corresponding 1,1-dihydroperfluoroalkyl groups to the α-amino group of (l)tyrosine. The obtained Nα-2,2,2-trifluoroethylated (l)tyrosine (6, n = 0) was further used as the N-terminus in the solid phase peptide synthesis of leucine enkephalin analogue. The lipophilicity of the Nα-1,1-dihydroperfluoroalkylated (l)tyrosines (6, n = 0-2) and N-terminus-2,2,2-trifluoroethylated leucine enkephalin analogue (7), as well as the corresponding parent compounds, was measured. 相似文献
994.
V. P. Korolev 《Journal of Structural Chemistry》2007,48(3):573-577
Changes in the thermal expansion coefficient and isothermal compressibility in homological series of n-alcohols at 298 K are discussed. It is shown that only methanol exhibits abnormal behavior. Volumetric coefficients of hypothetical solvents such as pseudo-water and pseudo-methanol are determined. Internal pressure values of liquids are calculated. The internal pressure of pseudo-water exceeds that of water, whereas the situation is opposite for the cohesion energy density. 相似文献
995.
Temperature coefficients (Deltadelta/DeltaT) of amide chemical shifts of N-acetylglucosamine residues have been measured in a range of oligosaccharides of the important vertebrate polysaccharide hyaluronan. Odd- and even-numbered oligosaccharides with glucuronic acid, Delta-4,5-unsaturated glucuronic acid and N-acetylglucosamine at the termini were investigated. All amide proton temperature coefficients were only slightly less negative (-6.9 to - 9.1 ppb/ degrees C) than those of amide protons in free exchange with water (approximately equal to -11 ppb/ degrees C), indicating an absence of persistent intramolecular hydrogen bonds. With the exception of amide groups in reducing-terminal N-acetylglucosamine rings, all amide proton environments have the same temperature coefficient (-6.9 ppb/ degrees C), irrespective of differences in amide group chemical shifts and (3)J(HH) coupling constants, i.e. they do not sense subtle differences in orientation of the amide group. Amide nitrogen temperature coefficients report the same phenomena but with greater sensitivity. These data provide a set of reference values for temperature coefficients measured in other carbohydrates with acetamido sugars. 相似文献
996.
Hilal SH Saravanaraj AN Whiteside T Carreira LA 《Journal of computer-aided molecular design》2007,21(12):693-708
Mathematical models for predicting the transport and fate of pollutants in the environment require reactivity parameter values
– that is the value of the physical and chemical constants that govern reactivity. Although empirical structure–activity relationships
have been developed that allow estimation of some constants, such relationships are generally valid only within limited families
of chemicals. The computer program, SPARC, uses computational algorithms based on fundamental chemical structure theory to
estimate a large number of chemical reactivity parameters and physical properties for a wide range of organic molecules strictly
from molecular structure. Resonance models were developed and calibrated using measured light absorption spectra, whereas
electrostatic interaction models were developed using measured ionization pKas in water. Solvation models (i.e., dispersion, induction, H-bonding, etc.) have been developed using various measured physical
properties data. At the present time, SPARC’s physical property models can predict vapor pressure and heat of vaporization
(as a function of temperature), boiling point (as a function of pressure), diffusion coefficient (as a function of pressure
and temperature), activity coefficient, solubility, partition coefficient and chromatographic retention time as a function
of solvent and temperature. This prediction capability crosses chemical family boundaries to cover a broad range of organic
compounds. 相似文献
997.
邓雪 《纯粹数学与应用数学》2007,23(4):524-528
研究非负投资比例系数约束条件下,实现风险最小化的组合证券投资问题.应用罚函数法,对最小风险组合证券的非负投资比例系数进行研究.实例表明:这一方法是可行的、有效的. 相似文献
998.
结合组氨酸与一种多糖之间的酯化反应产物的鉴定,介绍了扩散系数加权的核磁共振波谱法(DW-NMR)的原理及应用。 相似文献
999.
1000.