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91.
We consider an anharmonic crystal described by variablesS x ,x d ,S x , with one-body interaction ¦S x ¦ and nearest neighbor (n.n.) two body interaction ¦S x –S y ¦. We prove that, for d bounded, , where is the correlation function for the free boundary condition Gibbs state in ,>0 and are suitable constants independent of and . This generalizes previous results obtained in the case.Research partially supported by Consiglio Nazionale delle Ricerche.  相似文献   
92.
Functional organic molecular materials and conjugated oligomers or polymers now allow the low-cost fabrication of thin films for insertion into new generations of electronic and optoelectronic devices. The performance of these devices relies on the understanding and optimization of several complementary processes. Our goal is to discuss the relationship between the molecular stacking structures and their optoelectronic properties that are of importance in all these areas. The concept of intermolecular interaction should be taken here in the special sense that is inter-dipole coupling. Specifically, we will address the impact of inter-dipole interaction between adjacent molecules in aggregate state on the solid-state emission properties.  相似文献   
93.
For lattices with two kinds of points (black and white), distributed according to a translation-invariant joint probability distribution, we study statistical properties of the sequence of consecutive colors encountered by a random walker moving through the lattice. The probability distribution for the single steps of the walk is considered to be independent of the colors of the points. Several exact results are presented which are valid in any number of dimensions and for arbitrary probability distributions for the coloring of the points and the steps of the walk. They are used to derive a few general properties of random walks on lattices containing traps.Presented at the Symposium on Random Walks, Gaithersburg, MD, June 1982.  相似文献   
94.
There have been many experimental and theoretical studies on molecular conduction, as it is a fundamental parameter in the study of molecular‐scale electronics. We have investigated the features of molecular conduction using a Green's function method, which has often been used to solve problems in quantum transport and is also effective in elucidating electron transport in molecules. We have obtained the novel effective Green's functions, including the first‐order energy corrections, by accommodating the self‐energy of the electrodes as perturbation terms. Although these approximate Green's functions only provide information on the first‐order energy corrections, they can involve the elementary properties of molecular conduction. We propose a scheme for the analysis of the relations between molecular orbitals and their roles in molecular conduction and present analytical calculations for normal and cyclic polyenes. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006  相似文献   
95.
非理想状态下的塔板理论模型   总被引:3,自引:0,他引:3  
王少坤  夏芸  汪圣利 《色谱》2002,20(1):30-33
 在过程中 ,将流动相看成是由许多连续的塔板组成 ,每一塔板的高度与固定相塔板的高度相同。初始浓度的溶质被认为全部集中在流动相的第一塔板中 ;溶质在流动相和固定相之间动态分布。由于动力学因素的影响 ,当流动相流过一个塔板距离时 ,溶质不能够迅速地从固定相释放到流动相中 ,因此溶质在流动相和固定相中的分布浓度受到两个因素即反映系统热力学性质的分配系数P和反映系统动力学性质的释放概率因子α的影响。这一过程被认为是非理想状态下的过程。  相似文献   
96.
关于两两NQD列的若干极限性质   总被引:32,自引:0,他引:32  
本文讨论了两两NQD列的Marcinkiewicz型弱大数律及Jamison型加权和的强稳定性,指出了两两NQD列与独立列的一个本质性区别,从而提出了解决两两NQD旬几乎处处收敛和完全收敛的一种方式。  相似文献   
97.
In this paper a one-dimensional surplus process is considered with a certain Sparre Andersen type dependence structure under general interclaim times distribution and correlated phase-type claim sizes. The Laplace transform of the time to ruin under such a model is obtained as the solution of a fixed-point problem, under both the zero-delayed and the delayed cases. An efficient algorithm for solving the fixed-point problem is derived together with bounds that illustrate the quality of the approximation. A two-dimensional risk model is analyzed under a bailout type strategy with both fixed and variable costs and a dependence structure of the proposed type. Numerical examples and ideas for future research are presented at the end of the paper.  相似文献   
98.
We construct a quantum circuit to produce a task-oriented partially entangled state and use it as the quantum channel for controlled joint remote state preparation. Unlike most previous works, where the parameters of the quantum channel are given to the receiver who can accomplish the task only probabilistically by consuming auxiliary resource, operation and measurement, here we give them to the supervisor. Thanks to the knowledge of the task-oriented quantum channel parameters, the supervisor can carry out proper complete projective measurement, which, combined with the feed-forward technique adapted by the preparers, not only much economizes (simplifies) the receiver's resource (operation) but also yields unit total success probability. Notably, such apparent perfection does not depend on the entanglement degree of the shared quantum channel. Our protocol is within the reach of current quantum technologies.  相似文献   
99.
This review reports a broad overview of the synthetic procedures of 1,8-naphthyridines, dibenzo[b,g][1,8]naphthyridine, dibenzo[c,f][1,8]naphthyridine, 1,8-naphthyridine-3-carboxylic acid, 1,8-naphthyridine-3-carboxamide, and 1,8-naphthyridine-3-carbohydrazide compounds and their reactions. The physical properties, spectral data, and biological importance of naphthyridines are discussed.  相似文献   
100.
《力学学报》2012,44(1)
为了解决一般工程问题中输出量为多项式情况下相关正态输入变量的贡献识别问题,以二次不含交叉项的多项输出量为例,利用多维相关正态分布及其条件分布的性质,解析地推导了相关正态输入变量对输出量总方差的独立贡献及相关贡献,采用算例验证了所推导的解析表达式的正确性.文中所推导的相关正态变量独立贡献和相关贡献的表达式可直接用于输出量为二次不含交叉项多项式或一次多项式情况下的输入变量贡献的识别,并且为其他新的算法提供了对照解,另外此方法亦可以推广至含交叉项的高阶多项式,解决更为复杂输出量情况下输入量的贡献识别问题.  相似文献   
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