首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1834篇
  免费   104篇
  国内免费   233篇
化学   52篇
晶体学   2篇
力学   124篇
综合类   49篇
数学   1701篇
物理学   243篇
  2024年   4篇
  2023年   16篇
  2022年   20篇
  2021年   27篇
  2020年   41篇
  2019年   42篇
  2018年   51篇
  2017年   68篇
  2016年   38篇
  2015年   35篇
  2014年   52篇
  2013年   262篇
  2012年   61篇
  2011年   83篇
  2010年   93篇
  2009年   89篇
  2008年   116篇
  2007年   112篇
  2006年   106篇
  2005年   108篇
  2004年   83篇
  2003年   89篇
  2002年   85篇
  2001年   75篇
  2000年   71篇
  1999年   72篇
  1998年   44篇
  1997年   41篇
  1996年   32篇
  1995年   29篇
  1994年   20篇
  1993年   23篇
  1992年   11篇
  1991年   17篇
  1990年   4篇
  1989年   4篇
  1988年   5篇
  1987年   8篇
  1986年   3篇
  1985年   4篇
  1984年   2篇
  1982年   4篇
  1981年   5篇
  1980年   3篇
  1979年   6篇
  1978年   2篇
  1977年   5篇
排序方式: 共有2171条查询结果,搜索用时 109 毫秒
41.
作为Hom-Leibniz代数胚的代数类比, 本文引入Hom-Leibniz-Rinehart代数的概念. 证明了分裂的正则Hom-Leibniz-Rinehart代数$L$写成$L=U+\sum_{\gamma}I_\gamma$, 其中$U$为极大交换子代数$H$的子空间和$I_\gamma$为$L$的理想, 若$[\gamma]\neq[d]$, 满足$[I_\gamma, I_d]=0$. 随后分别发展了分裂Hom-Leibniz-Rinehart代数的根和权的连通技术.最后研究了紧致的正则Hom-Leibniz-Rinehart代数的结构.  相似文献   
42.
Two Fraenkel-Mostowski models are constructed in which the Boolean Prime Ideal Theorem is true. In both models, AC for countable sets is true, but AC for sets of cardinality 2 and the 2m = m principle are both false. The Principle of Dependent Choices is true in the first model, but false in the second. Mathematics Subject Classification: 03E25, 03E35, 04A25.  相似文献   
43.
In this paper, we analyze the exponential method of multipliers for convex constrained minimization problems, which operates like the usual Augmented Lagrangian method, except that it uses an exponential penalty function in place of the usual quadratic. We also analyze a dual counterpart, the entropy minimization algorithm, which operates like the proximal minimization algorithm, except that it uses a logarithmic/entropy proximal term in place of a quadratic. We strengthen substantially the available convergence results for these methods, and we derive the convergence rate of these methods when applied to linear programs.Research supported by the National Science Foundation under Grant DDM-8903385, and the Army Research Office under Grant DAAL03-86-K-0171.  相似文献   
44.
Capillary gc is now rapidly expanding. Naturally, initiation is most often attempted on the basis of the experience acquired with packed columns. However, such an extrapolation is successful only if a number of essential peculiarities of capillary gc are considered. Based on practical examples this paper discusses six essential details: 1) design and maintenance of the gas flow paths, 2) the greatly increased importance of sampling technique, which should not be confined just to stream splitting, 3) the problems in quantitative analysis arising from small sample size, 4) specific sources of trouble related to small amounts of liquid phase, 5) specific arguments for the choice of the carrier gas, clearly pointing to hydrogen as the ideal carrier and, 6) the different way to approach column production. Figures for all selected examples are given.  相似文献   
45.
In this study, a fingerprint-activity relationship modeling between chemical fingerprints and antirheumatic activity was established, and multivariate statistical analysis was used to evaluate the quality of Taxilli Herba (TH) from different hosts. Characteristic fingerprints of 20 batches of TH samples were generated by high-performance liquid chromatography coupled with triple quadrupole-time of flight tandem mass spectrometry (HPLC-Triple TOF-MS/MS), and the similarity analysis was calculated based on thirteen common characteristic peaks by hierarchical clustering analysis (HCA). Subsequently, nine efficacy markers were discovered by combining fingerprints and antirheumatic activity through grey correlation analysis (GCA) and bivariate correlation analysis (BCA). Meanwhile, the content of 5 constituents in 9 markers was determined by high-performance liquid chromatography coupled with triple quadrupole-linear ion trap tandem mass spectrometry (HPLC-QTRAP-MS/MS). The comprehensive quality of TH was assessed using multivariate statistical analysis, including principal components analysis (PCA) and technique for order preference by similarity to ideal solution (TOPSIS). The results showed that a high dose of TH extract could markedly ameliorate arthritis damage compared to other doses, with flavonoids playing an important role in the antirheumatic activity. The comprehensive quality of samples from Morus alba L. (SS) was superior to those from Liquidambar formosana Hance (FXS). The present study will demonstrate the markers associated with efficacy, and provide an applicable strategy for more comprehensive quality control and evaluation of TH.  相似文献   
46.
非理想状态下的塔板理论模型   总被引:3,自引:0,他引:3  
王少坤  夏芸  汪圣利 《色谱》2002,20(1):30-33
 在过程中 ,将流动相看成是由许多连续的塔板组成 ,每一塔板的高度与固定相塔板的高度相同。初始浓度的溶质被认为全部集中在流动相的第一塔板中 ;溶质在流动相和固定相之间动态分布。由于动力学因素的影响 ,当流动相流过一个塔板距离时 ,溶质不能够迅速地从固定相释放到流动相中 ,因此溶质在流动相和固定相中的分布浓度受到两个因素即反映系统热力学性质的分配系数P和反映系统动力学性质的释放概率因子α的影响。这一过程被认为是非理想状态下的过程。  相似文献   
47.
We provide a straightforward proof of one of the main results of the Baum-Douglas K-homology theory: If A is a separable nuclear C *-algebra and I an ideal of A, then the natural restriction map K 0(A, I) K 0(I) is an isomorphism of Abelian groups.  相似文献   
48.
We first determine the homotopy classes of nontrivial projections in a purely infinite simpleC*-algebraA, in the associated multiplier algebraM(A) and the corona algebraM A/A in terms ofK *(A). Then we describe the generalized Fredholm indices as the group of homotopy classes of non-trivial projections ofA; consequently, we determine theK *-groups of all hereditaryC*-subalgebras of certain corona algebras. Secondly, we consider a group structure of *-isomorphism classes of hereditaryC*-subalgebras of purely infinite simpleC*-algebras. In addition, we prove that ifA is aC*-algebra of real rank zero, then each unitary ofA, in caseA it unital, each unitary ofM(A) and ofM(A)/A, in caseA is nonunital but -unital, can be factored into a product of a unitary homotopic to the identity and a unitary matrix whose entries are all partial isometries (with respect to a decomposition of the identity).Partially supported by a grant from the National Science Foundation.  相似文献   
49.
In this paper, we present a unified theory of first-order and higher-order necessary optimality conditions for abstract vector optimization problems in normed linear spaces. We prove general multiplier rules, from which nearly all known first-order, second-order, and higher-order necessary conditions can be derived. In the last section, we prove higher-order necessary conditions for semi-infinite programming problems.This work was developed within the Forschungsschwerpunkt Dynamische Systeme, Universität Bremen, Bremen, West Germany.The author wishes to thank Prof. Dr. D. Hinrichsen for his helpful remarks and discussions during the preparation of this work.  相似文献   
50.
The binary system H2O—UO2(NO3)2 was studied by solubility measurements and constant heat flow thermal analysis. Temperature and composition of the eutectic transformation between ice and uranyl nitrate hexahydrate were accurately defined. A new hydrate with 24 molecules of water decomposes at –21°C according to the peritectoid reaction<UO2(NO3)2·24H2O> <UO2(NO3)2·6H2O> + 18<H2O>The quasi-ideal model was applied to the solid—liquid equilibria, using the following reaction hypothesis:((UO 2 2+ )) + 2((NO 3 ))+ h((H2O)) ((UO2OH+aq)) + ((H3O+aq + 2((NO 3 aq))A complete calculation of the binary system was carried out with a global ionic hydration number h equal to 9 in the aqueous solutions. It allowed to the melting enthalpies of uranyl nitrate hydrates.
This revised version was published online in November 2005 with corrections to the Cover Date.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号