Polymer-protected palladium nanoparticles. Morphologies and catalytic selectivities

Colloidal palladium nanocatalysts prepared by in situ reductions of palladium chloride were immobilized and protected by either of two water-soluble polymers. The particle sizes and size distributions of the palladium colloids were determined by transmission electron microscopy. Their selectivities as catalysts were determined by comparing the extents of hydrogenation of carefully chosen pairs of small-molecule olefins. There was found to be high hydrogenation selectivity with regard to cyclic vs. noncyclic olefins. Selectivity was relatively low, however, among olefins that differed only in size (such as hexene vs. octene), or olefins differing only with regard to the positions of the double bonds (such as 1-octene vs. 3-octene). Selectivity could be improved by careful choice of the immobilizing polymer, and by its use at relatively high concentrations.     

杨村烟煤快速液化反应性的研究

用共振搅拌反应器研究了杨村烟煤的高温快速液化。研究发现，在体系保持较高活性氢浓度时，适当提高反应温度，缩短反应时间——在短时间内达到较高的煤转化率,即高温快速液化是可行的。高温快速液化的最佳反应温度正是热重曲线反映的煤活泼热解温度范围的上限。从液化产物看，高温快速液化反应产物中苯可溶物占绝大多数，这对于煤液化产物的进一步利用非常有利。     

层状正极材料LiNi1/6Co1/6Mn2/3O2的制备及电池性能

0引言为解决目前日益严重的汽车尾气排放对城市空气造成污染问题,作为绿色能源的锂离子电池已成为动力电池的首选对象。国际上,高容量、大功率锂离子电池早于1995年已开始研制。1996年,我国天津电源研究所也进行了大容量锂离子蓄电池及电池组的探索[1]。目前,锂离子电池的正极材料是制约其大规模推广应用的关键。现研究的正极材料主要包括具有层状结构的LiCoO2,LiN iO2和LiM nO2及具有尖晶石结构的LiM n2O4等。其中LiC oO2作为目前唯一已经商业化的正极材料具有理论容量高、可循环性能好等优点,但因Co资源的相对缺乏导致其价格高昂。…     

基于三阶段SBM模型的中国节能服务上市企业效率研究

节能服务企业效率对于推动节能服务产业发展和确保国家“双碳”目标实现具有重要意义。运用三阶段SBM模型,对2020年60家中国节能服务上市企业的综合效率进行实证研究,并分析效率的影响因素。研究结果表明,经济发展水平对综合效率具有双重影响,合适的产业结构和较高的投入资本回报率有利于综合效率提升,而政府补贴与企业存续时间制约了综合效率改进;剔除环境因素与随机误差影响后,多数企业综合效率下降,整体效率偏低;提高规模效率是提升综合效率的关键,且绝大部分企业处于规模收益递增状态。研究最后提出创新补贴方式、建立企业认证制度、开展综合能源服务和推动企业间兼并重组等可行建议,以提升节能服务企业的综合效率。     

含有偏好的DEA-BWM评价方法研究

针对传统的DEA模型在评估过程中并未考虑决策者对相关指标权重的偏好,将最优最差方法(BWM)嵌入到传统DEA模型中,基于决策者偏好排序的判断矩阵,构建一种含有偏好的DEA-BWM评价方法。首先在保持传统DEA方法的优势基础上,构建了CCR-BWM评价模型对各DMU进行评价。同时考虑为了便于各决策单元在统一权重基础上相互比较,构建了CSW-BWM公共权重模型。另外考虑决策单元自评和互评,构建了NCE-BWM中立型交叉效率。然后采用min-max方法分别将上述三种多目标评价模型转换为单目标线性规划进行求解。最后,选择一组算例对三种模型的有效性与合理性进行验证。     

我国区域绿色技术创新效率的分类测度和提升模式研究——基于非期望产出的SBM-SupSBM模型

本文首先运用考虑非期望产出的SBM-SupSBM模型估计我国各省市绿色技术创新效率并进行分类:稳定上升类、平稳类、大幅度波动类以及下降类。之后从企业内部和外部两方面对绿色技术创新效率提升的影响因素提出假设,着重考虑大幅度波动类别省份的效率提升。运用面板数据模型各影响因素进行验证,结论显示:企业规模对绿色技术创新效率波动较大的省份起到显著的抑制作用,环境规制和技术进步对绿色技术创新效率波动较大的省份作用不明显。针对分析结果,提出结论:在提升绿色技术创新效率的过程中,应注重企业规模和技术进步的协同作用,以及技术的开放程度。     

On Bahadur asymptotic efficiency in a semiparametric regression model

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Bahadur efficiency and robustness of studentized score tests

We derive the exact Bahadur slopes of studentized score tests for a simple null hypothesis in a one-parameter family of distributions. The Student's t-test is included as a special case for which a recent result of Rukhin (1993, Sankhy Ser. A, 55, 159–163) was improved upon. It is shown that locally optimal Bahadur efficiency for one-sample location models with a known or estimated scale parameter is attained within the class of studentized score tests. The studentized test has an asymptotic null distribution free of the scale parameter, and the optimality of likelihood scores does not depend on the existence of a moment generating function. We also consider the influence function and breakdown point of such tests as part of our robustness investigation. The influence of any studentized score test is bounded from above, indicating certain degree of robustness of validity, but a bounded score function is needed to cap the influence from below and to ensure a high power breakdown point. We find that the standard Huber-type score tests are not only locally minimax in Bahadur efficiency, but also very competitive in global efficiency at a variety of location models.     

黑腔靶X光转换,输运的定量测量

为了测量黑腔靶X光引光效率、转换效率,我们设计了相应的分解靶(泄漏靶)实验,1989～1992年在″神光″装置上共进行了四次漏靶分解实验,利用灵敏度作了绝对标定的平响应X光二极管对漏靶注入孔、引光孔流出的X光角分布进行了测量,测出了x光角分布,得到了黑腔靶X光转换效率为50％～60％,引光效率约6％,为以后辐射驱动内爆研究的理论计算和靶的优化设计提供了重要的数据。     

A Novel High Active TiO2/AC Composite Photocatalyst Prepared by Acid Catalyzed Hydrothermal Method

A high active novel TiO2/AC composite photocatalyst was prepared and used for phenol degradation. It was much more active than P-25 and exhibiting good decantability, less deactivation after several runs and less sensitive to pH change. Diffuse reflectance spectra (DRS) revealed that the electronic change in TiO2 did not occur by the addition of AC. Results of SEM and XRD suggested that better TiO2 distribution can be achieved when optimal AC content was adopted. The performance of the prepared TiO2/5AC catalyst revealed great practical potential in wastewater treatment field.