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61.
Yuan Chen Lulu Fu Baobao Sun Cheng Qian Dr. Srikala Pangannaya Hong Zhu Prof. Jing Ma Prof. Juli Jiang Dr. Zhigang Ni Prof. Ruibing Wang Prof. Xiancai Lu Prof. Leyong Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(19):5890-5896
Chiral α-amino acids play critical roles in the metabolic process in nearly all life forms. So far, chiral recognition of α-amino acids has mainly focused on the determination of l /d enantiomers. Herein, selection of planar chiral conformations between water-soluble pillar[5]arene WP5 and pillar[6]arene WP6 was observed due to α-side chain or ethyl ester moieties of l -α-amino acid ethyl ester hydrochlorides binding with WP5 and WP6 , respectively. Therefore, α-side chain and ethyl ester moieties of l -α-amino acid ethyl ester hydrochlorides were recognized by observing the induced CD signal and its inversion. This is a rare example of being able to detect the chiral region around α-carbon of a chiral α-amino acid molecule. 相似文献
62.
《Biomedical chromatography : BMC》2017,31(6)
Pinostrobin (PI, 5‐hydroxy‐7‐methoxyflavanone) is a natural flavonoid known for its rich pharmacological activities. The objective of this study was to identify the human liver cytochrome P450 (CYP450) isoenzymes involved in the metabolism of PI. A single hydoxylated metabolite was obtained from PI after an incubation with pooled human liver microsomes (HLMs). The relative contributions of different CYP450s were evaluated using CYP450‐selective inhibitors in HLMs and recombinant human CYP450 enzymes, and the results revealed the major involvement of CYP1A2, CYP2C9 and CYP2E1 in PI metabolism. We also evaluated the ability of PI to inhibit and induce human cytochrome P450 enzymes in vitro . High‐performance liquid chromatography and liquid chromatography–tandem mass spectrometry analytical techniques were used to estimate the enzymatic activities of seven drug‐metabolizing CYP450 isozymes in vitro . In HLMs, PI did not inhibit CYP 1A2, CYP2B6, CYP2C8, CYP2C9, CYP2C19, CYP2D6 or CYP3A4 (IC50 > 100 μm ). In the induction studies, PI had minimal effects on CYP1A2, CYP2B6and CYP3A4 activity. Based on these results, PI would not be expected to cause clinically significant CYP450 inhibition or induction. 相似文献
63.
64.
The design of the China Spallation Neutron Source (CSNS) low-energy beam transport (LEBT) line, which locates between the ion source and the radio-frequency quadrupole (RFQ), has been completed with the TRACE3D code. The design aims at perfect matching, primary chopping, a small emittance growth and sufficient space for beam diagnostics. The line consists of three solenoids, three vacuum chambers, two steering magnets and a pre-chopper. The total length of LEBT is about 1.74 m. This LEBT is designed to transfer 20 mA of H-pulsed beam from the ion source to the RFQ. An induction cavity is adopted as the pre-chopper.The electrostatic octupole steerer is discussed as a candidate. A four-quadrant aperture for beam scraping and beam position monitoring is designed. 相似文献
65.
G. G. Fedoruk 《Journal of Applied Spectroscopy》2002,69(2):161-182
The application of transient nutations in EPR spectroscopy of condensed media is considered. The main methods of formation and observation of transient nutations are presented. The laws governing this phenomenon in twolevel and multilevel spin systems and also in inhomogeneous broadening of EPR lines are described. Recent advances in the use of transient nutations to separate overlapping spectra, identify quantum numbers and quantum transitions, investigate the kinetics of photoinduced paramagnetic centers, and determine relaxation times for a wide range of crystalline and disordered media are presented. 相似文献
66.
Summary Radiation inhibition in the many-atom Jaynes-Cummings model being a consequence of cooperative as well as cavity detuning
effects is examined. Numerical solutions for the time evolution of the atomic population inversion exhibiting quasi-stationary
behaviour are presented. Furthermore, the cooperative energy shift of these quasi-stationary states is numerically computed
by using a special projection operator.
The authors of this paper have agreed to not receive the proofs for correction. 相似文献
67.
Kazuhiko Saigo Yukihiko Hashimoto Kazushi Kinbara Atsushi Sudo 《Journal of Chemical Sciences》1996,108(6):555-573
The review describes the mechanism of chiral discrimination of racemic amines upon crystallization and the induction of chirality
in organic reactions by using them as chiral auxiliaries. In order to form conglomerates, which can be resolved into the two
enantiomers upon alternative seeding, both formation and packing of 21-columns are essentially very important. On the other hand, in order to achieve high efficiency in resolution through diastereomeric
salt formation, which is the most practical method, one of a pair of diastereomeric salts derived from a racemic amine and
an enantiomerically pure resolving agent should at least have two 21-columns and planar boundary surfaces in its crystal structure. On the basis of this knowledge, we developed several artificial
chiral auxiliaries such as erythro-2-amino-1,2-diphenylethanol,cis-2-amino-1-acenaphthenol, andcis-2-amino-3,3-dimethyl-1-indanol. These were found to be very efficient chiral auxiliaries in asymmetric inductions: alkylation
of chiral imines, catalytic borane-reduction, and alkylation of chiral N-acylated oxazolidinone. 相似文献
68.
69.
Wolfgang R.?BergmannEmail author Roberto?ContiEmail author 《Annali di Matematica Pura ed Applicata》2003,182(3):271-286
Let H be the extended Cuntz algebra over the Hilbert space H. Since its zero grade part H0 is the C*-inductive limit of B(Hr), we look for some family of representations on an inductive limit of Hr as r. When such construction is shaped according to the structure of H0, von Neumanns notion of a reference sequence of unit vectors for Hilbert infinite tensor products emerges; after a further Rieffel induction step, a class IPR[H] of representations of H arises. For any two such representations, we describe explicitly their associated intertwiners. Any two representations in IPR[H] are either disjoint or unitarily equivalent. Actions of the group by translation on sequences of unit vectors are involved, as well as the ideals of . 相似文献
70.
Alessandro Berarducci 《Transactions of the American Mathematical Society》2000,352(2):553-577
The field of generalized power series with real coefficients and exponents in an ordered abelian divisible group is a classical tool in the study of real closed fields. We prove the existence of irreducible elements in the ring consisting of the generalized power series with non-positive exponents. The following candidate for such an irreducible series was given by Conway (1976): . Gonshor (1986) studied the question of the existence of irreducible elements and obtained necessary conditions for a series to be irreducible. We show that Conway's series is indeed irreducible. Our results are based on a new kind of valuation taking ordinal numbers as values. If we can give the following test for irreducibility based only on the order type of the support of the series: if the order type is either or of the form and the series is not divisible by any monomial, then it is irreducible. To handle the general case we use a suggestion of
M.-H. Mourgues, based on an idea of Gonshor, which allows us to reduce to the special case . In the final part of the paper we study the irreducibility of series with finite support.
M.-H. Mourgues, based on an idea of Gonshor, which allows us to reduce to the special case . In the final part of the paper we study the irreducibility of series with finite support.