首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3812篇
  免费   829篇
  国内免费   523篇
化学   469篇
晶体学   39篇
力学   536篇
综合类   99篇
数学   1783篇
物理学   2238篇
  2024年   12篇
  2023年   50篇
  2022年   55篇
  2021年   61篇
  2020年   109篇
  2019年   80篇
  2018年   110篇
  2017年   127篇
  2016年   153篇
  2015年   113篇
  2014年   194篇
  2013年   235篇
  2012年   210篇
  2011年   250篇
  2010年   193篇
  2009年   236篇
  2008年   276篇
  2007年   284篇
  2006年   233篇
  2005年   265篇
  2004年   236篇
  2003年   260篇
  2002年   193篇
  2001年   161篇
  2000年   191篇
  1999年   158篇
  1998年   131篇
  1997年   127篇
  1996年   110篇
  1995年   77篇
  1994年   48篇
  1993年   38篇
  1992年   36篇
  1991年   22篇
  1990年   18篇
  1989年   16篇
  1988年   15篇
  1987年   16篇
  1986年   12篇
  1985年   9篇
  1984年   13篇
  1983年   4篇
  1982年   9篇
  1977年   2篇
  1974年   1篇
  1972年   1篇
  1971年   2篇
  1969年   1篇
  1959年   6篇
  1936年   1篇
排序方式: 共有5164条查询结果,搜索用时 15 毫秒
141.
In this paper, we present examples of codes all of whose weight classes support 1‐designs, with duals whose classes include two that support 2‐designs. We can find these examples in the triply even binary codes of length 48, which have been classified by Betsumiya and Munemasa.  相似文献   
142.
In this paper, we prove the existence and uniqueness of relaxation oscillation cycle of a slow–fast modified Leslie–Gower model via the entry–exit function and geometric singular perturbation theory. Numerical simulations are also carried out to illustrate our theoretical result.  相似文献   
143.
A new 1D complex has been prepared and characterized. X-ray single crystal structure confirms that the Cu(II) ions assemble in alternating chains with Cu … Cu distances of 2.5685(4) and 3.1760(4) Å. The temperature dependence of the magnetic susceptibility reveals an antiferromagnetic interaction between the paddle-wheel copper centers with an exchange of −300 cm−1. The exchange integral was also determined by quantum chemical ab-initio calculations, using polarised and unpolarised basis sets reproducing well the experimental value. The second harmonic generation efficiency of a concomitantly crystallized material was evaluated and was found to be comparable to urea.  相似文献   
144.
《Analytical letters》2012,45(5):441-450
Abstract

A microcell has been constructed for stripping analysis in solution volumes as low as 5 μl, employing a glassy carbon or mercury-plated glassy carbon working electrodes and a three electrode system. Using normal d.c. stripping techniques, as little as 100 picograms of mercury and 10 picograms of lead can be determined. With the more sensitive second harmonic a.c. voltammetric technique, this limit is lowered to 10 picograms of mercury and 1 picogram of lead.  相似文献   
145.
在非Born-Oppenheimer近似下,通过求解含时薛定谔方程的方法,对氢分子离子在不均匀场中高次谐波的产生进行了理论研究.计算结果显示,同均匀场相比,电离的电子在不均匀场中加速会获得更多的能量,从而更有利于得到宽频谱.此外,通过优化不均匀场中的空间不均匀度,长量子路径被明显的抑制,最终通过叠加110阶到150阶谐波,获得一个60as的孤立阿秒脉冲.同时,通过库仑势和激光场的相互作用势以及时频分布图解释了其中的物理机制.  相似文献   
146.
We consider symplectic difference systems involving a spectral parameter, together with the Dirichlet boundary conditions. The main result of the paper is a discrete version of the so-called oscillation theorem which relates the number of finite eigenvalues less than a given number to the number of focal points of the principal solution of the symplectic system. In two recent papers the same problem was treated and an essential ingredient was to establish the concept of the multiplicity of a focal point. But there was still a rather restrictive condition needed, which is eliminated here by using the concept of finite eigenvalues (or zeros) from the theory of matrix pencils.  相似文献   
147.
We consider a six-parameter family of the square integrable wave functions for the simple harmonic oscillator, which cannot be obtained by the standard separation of variables. They are given by the action of the corresponding maximal kinematical invariance group on the standard solutions. In addition, the phase space oscillations of the electron position and linear momentum probability distributions are computer animated and some possible applications are briefly discussed. A visualization of the Heisenberg uncertainty principle is presented.  相似文献   
148.
The stuffed tridymite structure Ba(Zn/Co)1−xSi1−xM2xO4 (M=Al3+ and Fe3+) is explored for the possible multiferroic behavior and to develop new inorganic colored materials. The compounds were synthesized by employing conventional solid-state chemistry methods in the temperature range 1100–1175 °C for 24 h. The powder X-ray diffraction (PXRD) and Rietveld refinement studies indicate that the compounds stabilize in the P63 space group (no. 173). The refinement results were also rationalized by employing Raman spectroscopic studies. The compounds were found to be second harmonic generation (SHG) active and show weak ferroelectric behavior. The co-substitution of Co2+ and Fe3+ in the structure gives rise to a weak ferromagnetic behavior to the compound, BaCo0.75Si0.75Fe0.5O4, making it a multiferroic material. The optical studies on the prepared compounds exhibited blue color (Co2+ in Td geometry), purple color (Ni2+ in Td geometry), and simultaneous substitution of Co2+ and Fe3+ gives rise to blue-green color owing to metal-to-metal charge transfer (MMCT) effect.  相似文献   
149.
本文给出了利用基本的物理原理结合高等数学公式的方法推导单摆做简谐运动的周期公式,可以简明扼要地理解单摆简谐运动的过程.  相似文献   
150.
In the light of recent developments in computer technology, a promising and efficient way to design a material with a desired property would be to solve the inverse problem: use a physical property to predict structure. Here, we discuss the basic idea and mathematical foundation of the inverse approach, and proposed strategies for its utilization in the design of materials over nano‐ to macro‐scales. At the nano‐scale, analyzed strategies include scanning of a high‐dimensional space of chemical compounds for those compounds that have a targeted property, and identification of correlations in large databases of materials. However, unlike utilization of inverse approach at nano‐scale where full structural information ‐ atoms and their positions‐ is linked to targeted properties, at the meso‐ and macro‐scale, only partial structural information, manifested via structural motifs or representative volume elements, is available. We discuss the role of partial structural information in the inverse approach to the design of materials at those scales. Risks and limitations of the inverse approach are analyzed and dependence of the approach on factors such as structure parametrization, approximations in theoretical models, and feedback from structural characterization, is addressed.

  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号