1‐rotationally resolvable 4‐cycle systems of 2Kv

In this article, it is shown that there exists a 1‐rotationally resolvable 4‐cycle system of 2K_υ if and only if υ ≡ 0 (mod 4). To prove that, some special sequences of integers are utilized. © 2002 Wiley Periodicals, Inc. J Combin Designs 10: 116–125, 2002; DOI 10.1002/jcd.10006     

光纤水听器相位生成载波解调非线性因素的抑制方法

为了消除非线性因素对相位生成载波解调结果的干扰,降低相位生成载波解调过程中低通滤波器的频响特性对相位生成载波解调结果的影响,该文提出了一种基于扩展卡尔曼滤波椭圆参数估计的相位生成载波微分交叉相乘解调方法。该方法在综合考虑各种非线性因素对相位生成载波微分交叉相乘解调结果的影响的基础上,对传统的相位生成载波微分交叉相乘解调过程进行了改进。经过计算机仿真和实验验证,该文所提出的扩展卡尔曼滤波微分交叉相乘方法能够有效地抑制非线性因素对相位生成载波解调结果的干扰,相比传统的相位生成载波微分交叉相乘方法,其信噪比提高了35.0 d B,总谐波失真降低了30.7 dB,信噪谐波比提高了31.0 dB,且扩展卡尔曼滤波微分交叉相乘方法受解调过程中低通滤波器频响特性的影响较小。     

DYNAMIC MODELING AND STABILITY CONTROL OF FOLDING WING AIRCRAFT 1)

折叠翼飞行器在变形过程中,其动力学模型呈现多刚体、多自由度和强非线性特点,同时气动力/力矩、压心、质心和转动惯量等参数也会大幅度变化,严重影响飞行稳定性. 由此,本论文将对飞行器的多刚体动力学建模与变形稳定控制进行研究.基于凯恩方法建立了折叠翼飞行器的多刚体动力学模型,并从中得到了变形所产生的附加力和力矩表达式.通过气动计算拟合出气动参数与折叠角之间的函数关系,由此分析了不同折叠角速度下飞行器的纵向动态特性, 结果表明,折叠翼飞行器变形过程中速度、高度和俯仰角均会发生变化,飞行器无法保持稳定飞行.为此提出了一种基于自抗扰理论的飞行器变形过程中的稳定控制方法.将折叠翼飞行器纵向非线性动力学模型中存在的非线性项、耦合项以及参数时变项都视为系统内外总扰动,利用扩张状态观测器对总扰动进行实时估计和补偿, 针对补偿后的系统设计PD控制器,实现了速度通道和高度通道的解耦控制.通过Lyapunov稳定性原理证明了系统的稳定性, 并进行数学仿真验证. 仿真结果表明,基于自抗扰理论设计的稳定控制器能够解决飞行器变形所带来的强非线性和参数时变等问题,保证飞行器的高精度稳定控制.     

捷联式惯导系统快速初始对准方法研究

针对初始对准过程中对准精度与快速性相矛盾的问题，提出并设计了把扩张状态观测器（ESO）与卡尔曼滤波滤波估计器相结合，用于捷联惯导系统初始对准的方法。数值仿真结果表明，该方法使对准过程所需要的时间大大缩短，并保证了较高的对准精度及较强的鲁棒性。     

meso‐Dibenzoporphycene has a Large Bathochromic Shift and a Porphycene Framework with an Unusual cis Tautomeric Form

meso‐Monobenzoporphycene (mMBPc) and meso‐dibenzoporphycene (mDBPc), in which one or two benzene moieties are fused at ethylene‐bridged positions (meso‐positions) of porphycene, were prepared in an effort to further delocalize the π‐electrons within the porphycene molecule. mMBPc and mDBPc were fully characterized by mass spectrometry, ¹H and ¹³C NMR spectroscopy, and X‐ray crystallography. The longest‐wavelength Q‐bands of mMBPc and mDBPc are red‐shifted by 92 nm and 418 nm, respectively, compared to that of the unsubstituted porphycene (Pc). Electrochemical measurements indicate that the HOMO is destabilized and the LUMO is stabilized by the fused benzene moieties at the meso positions. Furthermore, both XPS and theoretical studies support the presence of a cis tautomeric form in the ground state of mDBPc, despite the fact that essentially all known porphycene derivatives adopt the trans tautomeric form.     

Synthesis of Extended π‐Systems through C–H Activation

Activation of aromatic C? H bonds by a transition metal catalyst has received significant attention in the synthetic chemistry community. In recent years, rapid and site‐selective extension of π‐electron systems by C–H activation has emerged as an ideal methodology for preparing organic materials with extended π‐systems. This Review focuses on recently reported π‐extending C–H activation reactions directed toward new optoelectronic conjugated materials.     

Halogen‐bonded adduct of 1,2‐dibromo‐1,1,2,2‐tetrafluoroethane and 1,4‐diazabicyclo[2.2.2]octane

Halogen bonding is an intermolecular interaction capable of being used to direct extended structures. Typical halogen‐bonding systems involve a noncovalent interaction between a Lewis base, such as an amine, as an acceptor and a halogen atom of a halofluorocarbon as a donor. Vapour‐phase diffusion of 1,4‐diazabicyclo[2.2.2]octane (DABCO) with 1,2‐dibromotetrafluoroethane results in crystals of the 1:1 adduct, C₂Br₂F₄·C₆H₁₂N₂, which crystallizes as an infinite one‐dimensional polymeric structure linked by intermolecular N...Br halogen bonds [2.829 (3) Å], which are 0.57 Å shorter than the sum of the van der Waals radii.     

Interaction parameters and (solid + liquid) equilibria calculation for KCl–H2O–HCl–C2H5OH,K2SO4–H2O–H2SO4 and K2SO4–H2O–C2H5OH mixed solvent-electrolyte systems

This work deals with the prediction and experimental measurements of the (solid + liquid) equilibrium (SLE) in acid medium for industrial purposes. Specific systems including KCl–ethanol–water–HCl and K₂SO₄–water–H₂SO₄ were analyzed. At first, a critical discussion of SLE calculations was given, based on the well-known UNIQUAC extended and LIQUAC models. Two new proposals were derived, considering the explicit necessity of a new reference state for SLE calculations for the studied (solvents + acid) mixtures. The solubility of KCl in water–ethanol–HCl mixed solvents was measured in the temperature range of 300.15 to 315.15 K using an analytical gravimetric method. These results combined with some other experimental data reported in the open literature let us to propose a set of parameters for the new models. They included the interaction parameters between ethanol and the H⁺ ion. The prediction capability of the new models, for calculations in acid medium, was illustrated. Experimentally, it was observed that the (K₂SO₄ + water + H₂SO₄) system presented the unusual behavior of increasing K₂SO₄ solubility with an increase in the sulfuric acid concentration. This was accurately predicted by the newly proposed models.     

Nonmonotone Inexact Newton Method for the Extended Linear Complementarity Problem

This paper presents a nonmonotone inexact Newton-type method for the extended linear complementarity problem (ELCP). We first reformulate the optimization system of the ELCP problem into a system of smoothed equations. Then we solve this system by a nonmonotone inexact Newton-type algorithm. The global convergence is obtained and numerical tests for some classes of ELCP include linear complementarity, horizontal linear complementarity, and generalized linear complementarity problems are also given to show the e?ciency of the proposed algorithm.