Electrophysical characteristics and stability of solid apatite-like electrolytes La x Si6O12 + 1.5x and La x Ge6O12 + 1.5x

Oxygen-ion conduction in apatite-like compounds based on silicates and germanates of lanthanum La _x A₆O_{12 + 1.5x} (A = Si, Ge; x = 9.11–10.22) is studied. The compounds are shown to be purely ionic conductors at 600–900°C and partial oxygen pressures 10^?16 to 10⁵ Pa. The electroconductivity of the best conducting specimens of La _x A₆O_{12 + 1.5x} (A = Si, Ge; x = 9.77–10) exceeds that of electrolyte YSZ at moderate temperatures. The electroconductivity of lanthanum germanate is substantially greater than that of lanthanum silicate, specifically, 7.85 × 10^?2 and 2.35 × 10^?2 S cm^?1, respectively, at 800°C. An inflection is discovered at ～750°C in the temperature dependences of electroconductivity of La _x Ge₆O_{12 + 1.5x} (x = 9.77–10.22). A dilatometric examination points to a second-kind phase transition that may be due to the oxygen sublattice disordering. The behavior of apatite-like electrolytes La _x A₆O_{12 + 1.5x} (A = Si, Ge) during long exploitation periods in the interval of working temperatures of electrochemical devices is studied for the first time ever. The electrolytes’ aging at 800°C in air for 1000 h was investigated by the electroconductivity method. The electroconductivity of lanthanum germanates decayed with time by 5% and that of lanthanum silicates, by 9.5%. The steady-state values of electroconductivity of all compounds studied is reached after 600–700 h. The compounds studied form a class of materials that hold some promise as solid electrolytes for medium-temperature fuel cells and other electrochemical devices.     

高能闪光照相中影响光程确定的几个因素

 利用闪光照相基本原理和成像原理，在直接记录法和转换屏记录法的情况下，研究了闪光照相中影响X射线在材料中光程确定的主要因素。结果表明，影响光程确定的几个因素是：散射效应、光源角分布效应、立体角效应和能谱效应。对于高能闪光照相，散射效应是影响光程确定的最主要因素，散射的存在使光程的测量值比实际值降低20%～40%。因此必须在做CT之前，对散射的影响进行修正。     

Cooling Characteristics During Bath Quenching of Test Probe Using Inverse Heat Transfer

It is of engineering importance to accurately predict the surface cooling characteristics in bath quenching of metals and alloys. In this investigation, the surface cooling characteristics in quenching of Wolfson probe are estimated with reasonable accuracy by solving an inverse heat conduction problem. Regularization method is used for smoothening the input temperature measurements at probe center, for superior inversion estimates. The reverse pool-boiling curve is captured on bath quenching characteristic, plotted as cooling velocity versus surface temperature. The prime advantage is the bypassing of convection coefficients, which are uncertain in pool boiling.     

A quasi‐dynamic procedure for coupled thermal simulations

This paper outlines the development and adaptation of a coupling strategy for transient temperature analysis in a solid via a conjugate heat transfer method. This study proposes a quasi‐dynamic coupling procedure to bridge the temporal disparities between the fluid and the solid. In this approach, dynamic thermal modeling in the solid is coupled with a sequence of steady states in the fluid. This quasi‐dynamic algorithm has been applied to the problem of convective heat transfer over, and transient conduction heat transfer within, a flat plate using the severe thermal conditions of a solid propellant rocket. Two different coupled thermal computations have been performed. In the first one—referred to as the reference computation—the coupling period is equal to the smallest solid time constant. In the second one, a very large coupling period is used. The results show that the procedure can predict accurate transient temperature fields at a reasonable computational cost. The simulation CPU time is approximately reduced by up to 90%, while maintaining a very good accuracy. All the details of the numerical test case are given in the paper. This application illustrates the capabilities and the overall efficiency of this coupled approach in a solid transient problem using long term simulations of time dependent flows. Copyright © 2013 John Wiley & Sons, Ltd.     

Application of a Factorial Design Method to Determine the Accuracy of a Solution to an Inverse Heat Conduction Problem

A numerical/experimental inverse procedure was employed to estimate the temperature-dependent thermal conductivity of a solid body in which 1D heat conduction in a top heated cylindrical sample is assumed. The emphasis is focused on the issue of sensitivity of results to selected assumptions made in inverse calculations. It has been found that the accuracy of heat capacity evaluation brings the largest contribution to final errors (up to 74%). Density accounts for one-fourth to one-third of the total error of determination. The failure to ensure unidirectional heat conduction in a sample during an experiment is important only at elevated temperatures.     

北京城市物流业碳排放及驱动因素研究

估算了1998-2012年北京城市物流业的碳排放量,建立了北京城市物流业碳排放影响因素的通径分析模型.结果表明:物流基础设施的建设是该阶段碳排放增长的决定性因素,经济发展水平、以石油为主的能源结构、城镇化是促进碳排放的重要因素,能源效率对碳排放的正向影响较弱,产业结构对碳排放具有负向影响.最后提出了北京城市物流业低碳化发展的对策.     

Zur kepplimg eines exakten verfahrens mit einem heuristiscieb verfahren für die lösung ganzzahliger linearer optimierungsprobleme

Combining an exact method with a heuristic approach possibilities for solving linear mixed integer optimization problems are investigated. For the considered exact method numerical results with problems from the practice are given. Proper heuristic methods are the interior path methods [2] for which numerical experiences are well-known or the so-called geometric approach [8], Deriving of sufficient conditions for the existence of feasible solutions is possible.     

中学生学习自我效能感、学习策略与学业成就的关系

以学习自我效能感和学习策略量表为工具,通过方差分析、相关分析和路径分析等方法,重点考察了学习自我效能感和学习策略这两个因素对学业成就的影响路径以及相互间的关系.发现中学生的学习自我效能感与学习策略间存在着显著的相关关系;学习自我效能感和学习策略对初中生的学业成就有显著回归效应,而学习策略对高中生的学业成就有显著回归效应;学习自我效能感可通过影响学习策略来间接影响学业成就.     

A novel synthetic strategy for preparing semi‐aromatic components modified polyamide 6 polymer

In this work, a novel synthetic path for preparing semi‐armotic components modified polyamide 6 was developed by caprolactam as solvent of purified terephthalic acid and 1,6‐hexanediamine. First, the ring opening reaction and poly‐addition of caprolactam were initiated by 1,6‐hexanediamine to generate a prepolymer containing amino groups in both ends, then followed by the poly‐condensation reaction with purified terephthalic acid, a long chain copolymer was produced, which the reaction time was reduced by 4 h compared with conventional hydrolytic ring‐opening polymerization of pure caprolactam. By varying the ratio of terephthalic acid and 1,6‐hexanediamine, a series of copolymers with different number average molecular weight and physical properties were prepared. Analytical results showed that the conversion percentage of caprolactam is significantly increased by the proposed method. Furthermore, this new copolymers exhibited excellent transparence and high decomposition temperature. Besides, the copolymers with average molecular weight ≥15,000 present good mechanical properties, making it a potentially useful application in plastics, textile yarn, and membranes. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 959–967