全文获取类型
收费全文 | 463篇 |
免费 | 158篇 |
国内免费 | 23篇 |
专业分类
化学 | 83篇 |
晶体学 | 5篇 |
力学 | 48篇 |
综合类 | 9篇 |
数学 | 321篇 |
物理学 | 178篇 |
出版年
2023年 | 3篇 |
2022年 | 19篇 |
2021年 | 24篇 |
2020年 | 30篇 |
2019年 | 19篇 |
2018年 | 16篇 |
2017年 | 30篇 |
2016年 | 31篇 |
2015年 | 32篇 |
2014年 | 45篇 |
2013年 | 45篇 |
2012年 | 41篇 |
2011年 | 39篇 |
2010年 | 28篇 |
2009年 | 31篇 |
2008年 | 23篇 |
2007年 | 22篇 |
2006年 | 22篇 |
2005年 | 25篇 |
2004年 | 10篇 |
2003年 | 15篇 |
2002年 | 15篇 |
2001年 | 11篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 9篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 2篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有644条查询结果,搜索用时 166 毫秒
11.
杜毅 《新疆大学学报(理工版)》2004,21(3):258-266
本文将讨论非终生免疫性传染病模型解的适定性及正则性;同时证明了整体解的存在,以及解对初值的连续依赖。 相似文献
12.
Using the thermodynamical approach and the method of York, the back-reaction of anti-de Sitter Schwarzschild black hole in thermal equilibrium with conformal spin-2 field is studied. It is found that both approaches give identical results. 相似文献
13.
Ye Lin Feng Zeng‐Guo Zhao Yu‐Mei Wu Feng Chen Shi Wang Guo‐Qing 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3650-3665
A novel cyclic ether monomer 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy‐methyl}‐3′‐methyloxetane (HEMO) was prepared from the reaction of 3‐hydroxymethyl‐3′‐methyloxetane tosylate with triethylene glycol. The corresponding hyperbranched polyether (PHEMO) was synthesized using BF3·Et2O as initiator through cationic ring‐opening polymerization. The evidence from 1H and 13C NMR analyses revealed that the hyperbranched structure is constructed by the competition between two chain propagation mechanisms, i.e. active chain end and activated monomer mechanism. The terminal structure of PHEMO with a cyclic fragment was definitely detected by MALDI‐TOF measurement. A DSC test implied that the resulting polyether has excellent segment motion performance potentially beneficial for the ion transport of polymer electrolytes. Moreover, a TGA assay showed that this hyperbranched polymer possesses high thermostability as compared to its liquid counterpart. The ion conductivity was measured to reach 5.6 × 10?5 S/cm at room temperature and 6.3 × 10?4 S/cm at 80 °C after doped with LiTFSI at a ratio of Li:O = 0.05, presenting the promise to meet the practical requirement of lithium ion batteries for polymer electrolytes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3650–3665, 2006 相似文献
15.
研究了(CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb)与环戊二烯高产率生成 (C_5H_5)_3Ln·THF的新反应。反应产物经过了元素分析、质谱和X射线的表征。产 物(C_5H_5)_3Ln·THF的特征结构参数,如五元碳环的碳原子与中心金属的平均距 离,五元碳环质心与中心金属距离,配位的四氢呋喃氧原子与中心金属距离,由于 “镧系收缩现象”,随着中心原子序数的增加而减小。 相似文献
16.
通过建立考虑大数据营销及零售商风险规避的博弈模型,对绿色供应链定价、产品绿色度及利润进行比较分析。研究发现:无论集中决策、双方风险中性分散决策还是仅零售商风险规避分散决策,考虑大数据营销时的供应链整体期望利润和产品绿色度较高,且大数据营销效率因子对产品绿色度的增加有正向作用;双方风险中性分散决策下,一定条件下,两部定价契约能够有效协调供应链整体利润,实现帕累托改进;仅零售商风险规避分散决策下,零售商的风险规避行为会降低其对大数据营销的投入,一定条件下,两部定价契约也能够实现供应链整体期望利润的帕累托改进。 相似文献
17.
本文考虑了一个由单一供应商和单一电商平台组成的绿色供应链,分析了三种不同支付策略(立即支付策略、分期付款策略以及最低还款策略)对供应链成员最优决策和利润的影响。研究表明:(1)免息期敏感系数对绿色营销水平和供应链成员利润均有正向影响。(2)信用支付会使产品产生溢价现象。但在一定条件下,信用支付策略可同时提高供应链成员利润和绿色营销水平,实现经济绩效和环境绩效的双赢。(3)手续费率较高时,若信用期限系数较小,立即支付策略最优;若信用期限系数适中,分期付款策略最优;否则最低还款策略最优。手续费率较低且信用期较小时,最低还款策略最优,否则立即支付策略最优。在此基础上,针对两种信用支付模型设计了成本分担和收益共享的组合契约,实现了供应链协调。 相似文献
18.
催化光度返滴定法测定微量锰的研究 总被引:1,自引:0,他引:1
本文研究了催化光度反滴定法测定微量锰的原理,找到最佳实验条件,确立了实验方法,测定波长622nm;反应时间1min40s;活化剂NTA用量0.60mL,KIO4与孔雀石绿用量比为1.00:0.35,室温下滴定;用pH=5.4的乙酸-乙酸钠缓冲溶液控制溶液酸度;测定Mn^2+的浓度范围为1×10^-7~1×10^-5mol/L,Co^2+,Bi^3+,Ca^2+,Al^3+,Pb^2+,Cu^2+, 相似文献
19.
The calculation of Net Asset Values and Solvency Capital Requirements in a Solvency 2 context–and the derivation of sensitivity analyses with respect to the main financial and actuarial risk drivers–is a complex procedure at the level of a real company, where it is illusory to be able to rely on closed-form formulas. The most general approach to performing these computations is that of nested simulations. However, this method is also hardly realistic because of its huge computation resources demand. The least-squares Monte Carlo method has recently been suggested as a way to overcome these difficulties. The present paper confirms that using this method is indeed relevant for Solvency 2 computations at the level of a company. 相似文献
20.
This article considers a co-reinsurance strategy that (1) protects insurance companies against catastrophic risks; (2) enables insurers to gather sufficient information about the different risk attitudes of reinsurers and diversify their reinsured risks; (3) enables insurers to create better risk-sharing profiles by balancing the risk tolerances of reinsurers; (4) has the benefit of allowing reinsurers to accumulate experience with risks with which they are unfamiliar; (5) reduces the overall direct cost of a reinsurance contract; (6) allows a government to back some insurance products, such as the terrorism insurance programs that were established in many countries after the September 11th terrorist attacks; and (7) reflects the practical reinsurance industry of some countries, such as Iran. Such a co-reinsurance strategy can be fully determined by estimating its parameters whenever three optimal criteria are satisfied and prior information about the unknown parameters is available. Two simulation-based studies have been conducted to demonstrate (1) the practical applications of our findings and (2) the possible impact of any type of dependency between the co-reinsurance’s parameters and the evaluated optimal co-reinsurance strategy. 相似文献