Intramolecular orbital engineered hetero bimetallic Ce-Fe MOF with reduced transition energy and enhanced visible light property

A structurally stable, 3d-4f heterometallic coordination polymer has been solvothermally synthesised and evaluated for its accomplished materials properties. The light absorption activity in the visible band was higher for unique Ce-Fe MOF than that of the homometallic Ce-MOF or Fe- MOF. The intimate overlap of two different metal clusters in heterometallic environmental induced the formation of low line conduction orbital, which ultimately lowered the transition energy. The heterometallic acquired an additional sensitisation from a Fe-μ3-oxo cluster that had vibrantly enhanced the light uptake activity. The vacancy created in the 6s, 5d orbital of Ce in Ce-Fe MOF contributed to the photo-excitation of electrons and reduced the recombination time. This distinct intramolecular arrangement assisted the exciton trapping characteristic. Also, the presence of multiple metal cores in the framework aided to confine the increased number of excitons for a redox reaction. The solar photocatalysis study with acetaminophen revealed these improved materialistic features by degrading it 94.6% with a rate constant of 0.0137 min⁻¹. The recycle studies confirmed the robust stability of the synthesised MOF.     

Firms can benefit from inaccurate market beliefs

A supplier sells to a retailer who serves a market with uncertain demand. Before the season starts, the retailer preorders from the supplier, who stocks to satisfy at least the preorder. After the actual demand is realized, the retailer can place an at-once order, which is satisfied up to stock availability. Market demand, as perceived by a firm, can differ from what it actually is. We find that a firm can benefit from holding an inaccurate market belief.     

Cycloparaphenylene and their radicals anchored to a metal−organic framework

Cycloparaphenylene (CPP) shows modulated photophysical and electronic properties due to its strained structure and radially oriented π-electron system. Incorporation of CPP into metal-organic frameworks (MOFs) could transfer its extensive properties in solution to porous solids. Moreover, with the unique arrangement of the macrocycles and their interactions with the framework, emerging characteristics are anticipated. As an example of “robust dynamics”, we synthesized the first MOF structure (FDM-1001) with CPP precisely anchored to the ordered framework by employing a [8]CPP-containing linear dicarboxylate linker. Metric relationship between the dynamic macrocycles and the robust backbone creates ideal π-π interactions between them, which leads to an essentially directional arrangement of [8]CPP in the three-dimensional space. Furthermore, the MOF with [8]CPP could be successfully oxidized to generate an infinite array of radicals that show enhanced air stability compared to its molecular analogue.     

The band gap and transmission characteristics investigation of local resonant quaternary phononic crystals with periodic coating

In this article, the investigation of the Lamb wave propagation in two-dimensional phononic crystals (PCs) composed of an array of periodic coating on a thin plate is presented. Compared with the traditional PCs usually consist of cylindrical scatters with uniform coatings in their exterior structure, the newly exterior coating structures with periodic alternant arrangement of two different materials are proposed. The band structures are calculated using finite element method. We discover that a complete band gap can be exhibited at low frequency. Furthermore, for a finite PCs plate, the computed transmission and resonance spectra shown an evident resonance nature which can be directly related to formation of the low-frequency gaps. The effects of different material parameters and arrangement mode of coating on the acoustic energy transmission and attenuation are also studied. Finally, the experimental transmission spectrum of the periodic coating PCs are also presented and compared with the numerical results. This study will provide useful support to the design of tuning band gaps and isolators in the low-frequency range.     

长链烷基季铵盐插层氧化石墨的结构变化

基于改进的Hummers法制备氧化石墨(GO),并以长链烷基季铵盐(C_nTAB)对其进行插层处理;通过改变C_nTAB的链长、浓度,得到系列C_nTAB/GO插层复合物。采用XRD和元素分析对产物的最大底面间距及C_nTAB插入量进行表征。结果表明,随着C_nTAB链长的增长、C_nTAB浓度的增大,C_nTAB/GO插层复合物的最大底面间距逐渐增大。C_nTAB通过离子键作用和疏水键作用插入到GO层间,在GO片层上的吸附规律符合修正型(Modified)Langmuir模型,即C_nTAB以单分子层吸附在GO片层上。根据C_nTAB/GO插层复合物最大底面间距及C_nTAB插入量的变化规律分析,得出C_nTAB在GO层间的排布模式有单层平躺模式、类双层平躺模式、单层倾斜模式和单层直立模式。     

Aligning retention time shifts in HPLC three‐dimensional spectra by icoshift approach combined with data arrangement methods and the release of a graphical user interface

High‐performance liquid chromatography coupled with photodiode array detection has been extensively applied in many fields and the peaks among the analyzed samples can be shifted due to the variations of instrumental and experimental conditions. In multivariate analysis, retention time alignment is an important pretreatment step. Hence, the shifted peaks in high‐performance liquid chromatography coupled with photodiode array detection three‐dimensional spectra should be aligned for further analysis. Being motivated by this purpose, the interval correlated shifting method combined with the proposed data arrangement methods are recommended and employed on high‐performance liquid chromatography coupled with photodiode array detection data as a demonstration. We validate the alignment performance of the proposed method through comparison the consistency of the retention time before and after alignment. The obtained results demonstrated that the proposed method is capable of successful aligning the employed data. Additionally, the interval correlated shifting method combined with the data arrangement modes is implemented in an easy‐to‐use graphical user interface environment and so can be operated easily by users not familiar with programming languages.     

降低轴流风机噪声的两种方法

本文对轴流风机的噪声源进行了理论和实验分析,对降低风机噪声的方法进行了总结。在此基础上,研究了降低风机噪声的两种新方法——叶片不等距分布方法和叶片穿孔方法。理论分析和实验结果表明,这两种方法为降低轴流风机噪声提供了新的途径。     

Minimal cutwidth linear arrangements of abelian Cayley graphs

We find the minimal cutwidth and bisection width values for abelian Cayley graphs with up to 4 generators and present an algorithm for finding the corresponding optimal ordering. We also find minimal cuts of each order.     

Interference effect of two equal‐sized square cylinders in tandem arrangement: With planar shear flow

Numerical simulations have been performed for flow past two equal‐sized square cylinders in tandem arrangement subjected to incoming planar shear flow. Effect of L/d ratio and the shear parameter has been studied. The range of L/d ratio (ratio of center‐to‐center distance (L) to cylinder width (d)) is varied from 2 to 7 and the non‐dimensional shear parameter (K) is varied from 0.0 to 0.4 in steps of 0.1. For all the cases the Reynolds number (Re) based on centerline velocity and cylinder width is fixed at 100. The results are compared with that of isolated square cylinder with uniform flow. Strouhal number decreases with increasing shear parameter. There are more than one shedding frequency at high shear parameters and L/d ratios. The mean drag coefficient is decreased with shear parameter and lesser than that of the single cylinder. The root mean square (RMS) value of both lift and drag coefficients is higher for the downstream cylinder for all values of shear parameter. With increasing L/d ratio, for both lift and drag, the RMS value increases and then decreases for upstream cylinder, whereas it continuously increases for the downstream cylinder. The stagnation point is moved towards the top leading edge with increasing shear. The critical L/d ratio, which is defined as the distance between two cylinders, beyond which the vortex shedding from the upstream cylinder occurs, decreases with increasing shear parameter. Copyright © 2007 John Wiley & Sons, Ltd.