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21.
Carl M. Bender Fred Cooper Gerald Guralnik Harvey A. Rose David H. Sharp 《Journal of statistical physics》1980,22(6):647-660
We discuss the simple, randomly driven systemdx/dt = –x –x3 +f(t), wheref(t) is a Gaussian random function or stirring force with f(t)f(t) = (t – t). We show how to obtain approximately the coefficients of the expansion of the equal-time Green's functions as power series in (1/R)n, whereR is the internal Reynolds number ()1/2/, by using a new expansion for the path integral representation of the generating functional for the correlation functions. Exploiting the fact that the action for the randomly driven system is related to that of a quantum mechanical anharmonic oscillator with Hamiltonianp
2/2 +m
2
x
2/2 +vx
4 +x
6/2, we evaluate the path integral on a lattice by assuming that thex
6 term dominates the action. This gives an expansion of the lattice theory Green's functions as power series in 1/(a)1/3, wherea is the lattice spacing. Using Padé approximants to extrapolate toa = 0, we obtain the desired large-Reynolds-number expansion of the two-point function.Supported financially by the National Science Foundation and the U.S. Department of Energy. 相似文献
22.
This paper reports the results on a study of ion chromatography (IC) behaviour on strong cationic exchange column of CH3-(CH2)n−1-NH2 (n=1-6) type linear monoamines. The eluents were mixtures of HCl-NaCl, HNO3-NaNO3, HClO4-NaClO4, H2SO4-Na2SO4, HClO4-NaClO4-CH3CN. Amines were revealed with an amperometric detector. The influence of different counter-ions on retention factors, k′, is discussed. Relationships between k′ and pE (E=sum of Na+ and H+ concentrations), and length of alkylic chain, and sensitivity coefficient S, are reported and discussed. The addition of acetonitrile (ACN) in the eluent was also taken into account. Suitable considerations are derived from these data. An example of monoamines separation is given. 相似文献
23.
Bruce R. McGarvey 《Coordination chemistry reviews》1998,170(1):75-92
Using a newly proposed approach involving an internally consistent set of equations, the ligand field parameters Δ/ξ, V/ξ and k are obtained from literature values of the g matrix for strong field d5 systems of various conformations in which |Δ/ξ|≤10. Qualitative analysis of the observed results is done using the Angular Overlap Model, AOM. 相似文献
24.
The infrared spectra of phosphinic acid R2POOH dimers (R=CH3, CH2Cl, C6H5) have been studied in CCl4 and CH2Cl2 solutions (T=300 K). The infrared spectra of deuterated R2POOD dimers (R=CH3, CH2Cl) were also studied in the gas phase (T=400–550 K) and solid state (T=100–300 K). They are compared with previously studied spectra of the light (non-deuterated) dimers in the gas phase, in the solid state and in low-temperature argon matrices (T=12–30 K) in the 4000–400 cm−1 spectral region. It is found that the strong and broad ν(OH) dimer bands have similar shapes, nearly equal values of bandwidth and low-frequency shift, and possess the Hadzi ABC structure irrespective of the type of acid, significant differences of dimerization enthalpies, influence of solvent, the type of H-bonded complexes (cyclic dimers in the gas phase, in solutions, and in inert matrices, and infinite chains in the solid state), and temperature in the range 12–600 K. Isotopic ratio of the first moments of light and deuterated acid bands has been measured. Analysis of the ν(OH/OD) band of hydrogen bonded dimers of phosphinic acids shows that the interaction between the two intermolecular bonds O–HOP in a cyclic complex plays virtually no role in the mechanism of the ν(OH/OD) band formation; the shape of ν(OH/OD) band is controlled mainly by the POOH(D)O fragment; and the band shape of strong hydrogen bonded complexes is formed by a number of vibrational transitions from the ground state to different combination levels in the region 3500–1500 cm−1. 相似文献
25.
随机变量序列加权和的强收敛性 总被引:12,自引:0,他引:12
本文讨论了一般随机变量序列加权和的强收敛性.作为推论,得到一类鞅差序列加权和的收敛定理和若干经典的独立随机变量序列的强大数定律;已有的若干结论是本文结果的特例. 相似文献
26.
同分布NA列Jamison型加权和强稳定的充要条件 总被引:3,自引:1,他引:3
本文将Jamison等(1965)关于iid列加权和强稳定的充分性结果推广到NA列的场合并且得到了NA列Jamison型加权和强稳定的必要性结果。 相似文献
27.
The authors introduce a notion of a weak graph map homotopy (they call it
M-homotopy), discuss its properties and applications. They prove that the weak graph
map homotopy equivalence between graphs coincides with the graph homotopy equivalence
defined by Yau et al in 2001. The difference between them is that the weak graph map
homotopy transformation is defined in terms of maps, while the graph homotopy transformation is defined by means of combinatorial operations. They discuss its advantages over
the graph homotopy transformation. As its applications, they investigate the mapping
class group of a graph and the 1-order MP-homotopy group of a pointed simple graph.
Moreover, they show that the 1-order MP-homotopy group of a pointed simple graph is
invariant up to the weak graph map homotopy equivalence. 相似文献
28.
29.
Photons propagating in strong magnetic fields are subject to a phenomenon called the “vacuum birefringence” where refractive indices of two physical modes both deviate from unity and are different from each other. We compute the vacuum polarization tensor of a photon in a static and homogeneous magnetic field by utilizing Schwinger’s proper-time method, and obtain a series representation as a result of double integrals analytically performed with respect to proper-time variables. The outcome is expressed in terms of an infinite sum of known functions which is plausibly interpreted as summation over all the Landau levels of fermions. Each contribution from infinitely many Landau levels yields a kinematical condition above which the contribution has an imaginary part. This indicates decay of a sufficiently energetic photon into a fermion–antifermion pair with corresponding Landau level indices. Since we do not resort to any approximation, our result is applicable to the calculation of refractive indices in the whole kinematical region of a photon momentum and in any magnitude of the external magnetic field. 相似文献