Conductance of KCI-Glycerol Solutions: Test of the Fuoss Paired Ion Model

Abstract

The electrical conductance of KC1 in glycerol solutions has been measured at concentrations between 1.5 mol m^?3 and 353 mol m^?3 at 22°C. The results are compared with the Fuoss paired ion model and fits to the data are obtained assuming a Gurney co-sphere having a radius in the approximate range 6 ± 10^?10 m to 9 ± 10^?10 m. The model leads to an estimate of ionic association which is less than that given by the theory of Bjerrum.     

Radiation-Induced Graft Copolymerization of Styrene to Polyvinyl Chloride) Latex in a Pilot Plant System

A pilot plant study of the radiation grafting of styrene to polyvinyl chloride) (PVC) latex is described. When correct extraction conditions are used less than 3% grafting took place. This is shown to be due to the low total radiation doses needed to polymerize the styrene in an emulsion system. A parallel study with PVC film did, however, lead to substantial true grafting. The G (radical) value for PVC film as determined by ESR was found to be 4.6.     

Existence and Uniqueness of Solutions for a Class of Reaction-diffusion Systems

61.Intr0ducti0nInthispaper,wediscussareactionnetinacombusti0nmodel:V={R,,R2},whereR,andR2aredistinctreacti0nprocesses:Rl:A1+A,-A,,R2:A2+A3-P,A,(j=1,2,3)denotesthereactant,andPdenotestheinertproduct.Thesereactionsareexothermicreactions-LetQ,,Q2standforheatenergiesandU=(U,,U,,U,,U,)forstatevariablesdescribingreactions,whereUoisreactiontemporature,andU,(j=1,2,3)isthemolarityofthej-threactant.AssumethatV,(i=1,2)isthereactantvariablefortheithreactionpr0cess:V,=(Q,,1,-l,l)",V2=(Q,,O,-l,-…     

Finding an efficient solution to linear bilevel programming problem: An effective approach

Multilevel programming is developed to solve the decentralized problem in which decision makers (DMs) are often arranged within a hierarchical administrative structure. The linear bilevel programming (BLP) problem, i.e., a special case of multilevel programming problems with a two level structure, is a set of nested linear optimization problems over polyhedral set of constraints. Two DMs are located at the different hierarchical levels, both controlling one set of decision variables independently, with different and perhaps conflicting objective functions. One of the interesting features of the linear BLP problem is that its solution may not be Paretooptimal. There may exist a feasible solution where one or both levels may increase their objective values without decreasing the objective value of any level. The result from such a system may be economically inadmissible. If the decision makers of the two levels are willing to find an efficient compromise solution, we propose a solution procedure which can generate effcient solutions, without finding the optimal solution in advance. When the near-optimal solution of the BLP problem is used as the reference point for finding the efficient solution, the result can be easily found during the decision process.     

Backbone-only restraints for fast determination of the protein fold: the role of paramagnetism-based restraints. Cytochrome b562 as an example

CH(alpha) residual dipolar couplings (Deltardc's) were measured for the oxidized cytochrome b562 from Escherichia coli as a result of its partial self-orientation in high magnetic fields due to the anisotropy of the overall magnetic susceptibility tensor. Both the low spin iron (III) heme and the four-helix bundle fold contribute to the magnetic anisotropy tensor. CH(alpha) Deltardc's, which span a larger range than the analogous NH values (already available in the literature) sample large space variations at variance with NH Deltardc's, which are largely isooriented within alpha helices. The whole structure is now significantly refined with the chemical shift index and CH(alpha) Deltardc's. The latter are particularly useful also in defining the molecular magnetic anisotropy parameters. It is shown here that the backbone folding can be conveniently and accurately determined using backbone restraints only, which include NOEs, hydrogen bonds, residual dipolar couplings, pseudocontact shifts, and chemical shift index. All these restraints are easily and quickly determined from the backbone assignment. The calculated backbone structure is comparable to that obtained by using also side chain restraint. Furthermore, the structure obtained with backbone only restraints is, in its whole, very similar to that obtained with the complete set of restraints. The paramagnetism based restraints are shown to be absolutely relevant, especially for Deltardc's.     

Optimal control of coupled spin dynamics: design of NMR pulse sequences by gradient ascent algorithms

In this paper, we introduce optimal control algorithm for the design of pulse sequences in NMR spectroscopy. This methodology is used for designing pulse sequences that maximize the coherence transfer between coupled spins in a given specified time, minimize the relaxation effects in a given coherence transfer step or minimize the time required to produce a given unitary propagator, as desired. The application of these pulse engineering methods to design pulse sequences that are robust to experimentally important parameter variations, such as chemical shift dispersion or radiofrequency (rf) variations due to imperfections such as rf inhomogeneity is also explained.     

Cofolga: a genetic algorithm for finding the common folding of two RNAs

In order to predict non-coding RNA genes and functions on the basis of genome sequences, accurate secondary structure prediction is useful. Although single-sequence folding programs such as mfold have been successful, it is of great importance to develop a novel approach for further improvement of the prediction performance. In the present paper, a secondary structure prediction method based on genetic algorithm, Cofolga, is proposed. The program developed performs folding and alignment of two homologous RNAs simultaneously. Cofolga was tested with a dataset composed of 13 tRNAs, seven 5S rRNAs, five RNase P RNAs, and five SRP RNAs; as a result, it turned out that the average prediction accuracies for the tRNAs, 5S rRNAs, RNase P RNAs, and SRP RNAs obtained by Cofolga with an optimal weight factor and default parameters were 83.6, 81.8, 73.5, and 67.7%, respectively. These results were superior to those obtained by a single-sequence folding based on free-energy minimization in which corresponding average prediction accuracies were 52.4, 47.4, 57.7, and 52.3%, respectively. Cofolga has a post-processing in which a single-sequence folding is performed after fixation of a predicted common structure; this post-processing enables Cofolga to predict a structure that is present in one of two RNAs alone. The executable files of Cofolga (for Windows/Unix/Mac) can be obtained by an e-mail request.     

Random coil phosphorus chemical shift of deoxyribonucleic acids

Random coil phosphorus chemical shift has been studied using 16 17-nucleotide DNA sequences. Due to the presence of residual base stacking in these sequences, the temperature and sequence effects were investigated at 50 and 55 degrees C. The phosphorus chemical shifts of random coil DNA sequences have been found to be independent of temperature. Sequence effect analysis shows that the phosphorus chemical shift of a nucleotide in a random coil DNA sequence depends on both its 5'- and 3'-nearest neighbors. A trimer model has been used to establish the random coil 31P chemical shift prediction protocol which shows an accuracy of 0.02 ppm.     

Exact multiplicity and ordering properties of positive solutions of a p-Laplacian Dirichlet problem and their applications

We study the exact multiplicity and ordering properties of positive solutions of the p-Laplacian Dirichlet problem

     

Comparison Theorems for Four Dimensional Regular Matrices

A four dimensional summability matrix is stronger than convergence in the Pringsheim sense if it sums a divergent double sequence. Presented in this paper are sufficient conditions on a four dimensional matrix transformation which ensure that the summability matrix is stronger than convergence in the Pringsheim sense. Also other sufficient conditions will be presented to ensure the failure of inclusion between two summability matrices.AMS Subject Classification (2000): Primary 40B05.