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排序方式: 共有2175条查询结果,搜索用时 837 毫秒
31.
A. N. Ageev A. A. Aratskova L. D. Belyakova T. N. Gvozdovich A. V. Kiselev Ya. I. Yashin J. Kàlal F. Švec 《Chromatographia》1983,17(10):545-548
Summary The retention of benzene derivatives with nonpolar and polar substituents on a porous methacrylate copolymer containing epoxy groups using both nonpolar and polar eluents was investigated. When n-hexane is used as the eluent, the retention of n-alkylbenzenes and polymethylbenzenes is weaker than that of benzene. In the case of benzene derivatives containing polar functional groups their capacity ratios (k) on this porous polymer increases approximately linearly with the increase of the adsorbate molecules dipole moment. The retention characteristics of the methacrylate copolymer were compared with that of a styrene-divinylbenzene copolymer and silica gels with a hydroxylated surface and with a surface modified by chemically bonded alkylsilyl groups. 相似文献
32.
The relaxation properties of water saturated in porous core are discussed and the distribution of proton transverse relaxation time and bi-exponential model of longitudiual relaxation time are obtained, which provide an illustration for two-model of fluids saturated in porous media. The cutoff value of T_1 based on relaxation specific property of fluids in porous core is adopted to improve the correlation between permeability and ?4T1b2. 相似文献
33.
Summary A new expression which permits the prediction of the net retention volumes in gas chromatography with column packings of coated
porous polymers is reported. The porous polymers Chromosorb 101 and Chromosorb 102 were used as supports and squalane, Ethofat
and Carbowax 20M as stationary phases at three different column temperatures of 80°C, 100°C and 150°C. Several organic compounds
of various polarity were used as test compounds and the net retention volumes, VNtheor, have been calculated according to this new expression. The VNtheor values were compared with the experimental net retention volumes, VNexp, and it was found that the difference between these two values is dependent on the type of compound and column packing. Nevertheless,
the elution order could be predicted in most cases. 相似文献
34.
徐灿 《高等学校化学学报》1997,18(6):943-946
利用XeCl准分子激光烧蚀多种硅氧多孔结构材料,在负离子通道测得丰富的「(SiO2)nX」^-负离子团簇,并讨论了多孔网结构和表面活性基团的分布对激光能量的吸收,传输及团簇产生的重要作用。 相似文献
35.
K. E. Collins M. L. M. M. Granja R. G. Pereira Filho T. A. Anazawa I. C. S. F. Jardim 《Chromatographia》1997,45(1):99-103
Summary Poly(methyloctylsiloxane) (PMOS), sorbed into the pores of HPLC silica particles by solvent evaporation, can function as a
useful stationary phase for reversed-phase chromatography. The present work addresses the question of how the PMOS is distributed
in the pores. Measurements of the surface area (BET, N2) of a series of partially loaded samples (0–40% PMOS, m/m) using a typical batch of HPLC silica (10 μm irregular particles
with 6 nm pores) show that the specific surface area of the samples decreases linearly with the specific loading (mass of
PMOS per gram of silica). This result is not consistent with a “film” model in which the PMOS is deposited uniformly on the
pore walls, but is consistent with a model in which long segmented “plugs” of PMOS are deposited within the pore system.
Presented at the 21st ISC held in Stuttgart, Germany, 15th–20th September, 1996 相似文献
36.
Summary On-line coupled HPLC-GC has been used for the fractionation and analysis of polychlorobiphenyls (PCB) according to their planarity.
HPLC elution with porous graphitic carbon (PGC) as stationary phase, enables fractionation of PCB into classes according to
the amount ofortho-substitution, which is related to congener toxicity. This is a preliminary step before GC analysis, which enables complete
separation of PCB congeners according to vapour pressure. Conditions for HPLC-HRGC coupling were optimised, in particular
the appropriate proper HPLC solvent was selected, because it determines eluent strength and selectivity and the transfer conditions.
Different solvent were studied—n-hexane, dichloromethane, benzene, toluene, and their mixtures.
Samples containing PCB standards and the commercial mixtures Aroclor 1242 and 1254 were analysed. Dichloromethane-n-hexane, 1:1, was selected as mobile phase for separation of poly-ortho from mono-ortho PCB; benzene-dichloromethane 30:70 resulted in the best separation of the most retained non-ortho-substituted PCB. Under these conditions the co-solvent trapping procedure, performed by adding 4% ethylbenzene as co-solvent,
was used as transfer technique to overcome the drawback of losses of volatile congeners.
Appropriate analysis conditions were successfully used to fractionate the technical PCB formulations Aroclor 1242 and 1254. 相似文献
37.
N. Ibriş J. Mirza-Rosca A. Santana T. Vişan 《Journal of Solid State Electrochemistry》2002,6(2):119-125
The corrosion and passivation of Zn powder particles dispersed in a paste electrode immersed in 0.5 M Na2SO4 and 5×10–3 M Na2HPO4 solutions were studied mainly by electrochemical impedance spectroscopy. The role played by diffusion in the mechanism of
anodic oxidation of zinc powder particles has been shown. It was demonstrated that the anodic reactionof Zn powder in neutral
or near neutral media involves at least two adsorbed intermediates. By simulating the porous structure of the electrode, some
information about porous nature of zinc electrode could be extracted.
Electronic Publication 相似文献
38.
《中国化学快报》2020,31(4):988-991
Designing efficient electrocatalysts with low Pt loadings for hydrogen evolution reaction(HER) is urgently required for renewable and sustainable energy conversion.Here,we report a strategy that Pt nanoparticulates are spontaneously immobilized on porous MXene/MAX monolith as HER catalysts by utilizing the redox reaction between Ti_3C_2T_x MXene and [PtCl_4]~2 in H_2 PtCl_6 aqueous solution.By taking advantage of homogeneously distributed Pt nanoparticulates on highly electrically conductive porous Ti_3C_2T_x/Ti_3AlC_2 monolith,the as-prepared electrocatalysts show high catalytic performance for hydrogen evolution.Specifically,the binder-free electrocatalysts have Pt loadings as low as 8.9 μg/cm~2,with low overpotential of 43 mV at a curre nt density of 10 mA/cm~2 and low Tafel slope that three times lower than porous Ti_3C_2T_x/Ti_3AlC_2 without Pt loading.This strategy offers a new approach to constructing ultra-low Pt-loading HER catalysts on the basis of in situ redox reaction between noble metal ions and MXenes. 相似文献
39.
A simple theoretical model is described for deriving a 1-dimensional equation for the spreading of a tracer in a steady flow at the field scale. The originality of the model is to use a stochastic appoach not in the 3-dimensional space but in the 1-D space of the stream tubes. The simplicity of calculation comes from the local relationship between permeability and velocity in a 1-D flow. The spreading of a tracer front is due to local variations in the cross-sectional area of the stream tubes, which induces randomness in travel time. The derived transport equation is averaged in the main flow direction. It differs from the standard dispersion equation. The roles of time and space variables are exchanged. This result can be explained by using the statistical theory of Continuous Time Random Walk instead of a standard Random Walk. However, the two equations are very close, since their solutions have the same first and second moments. Dispersivity is found to be equal to the product of the correlation length by the variance of the logarithm of permeability, a result similar to Gelhar's macrodispersion.Nomenclature
A
total cross-section area of the sample
-
C
(resident) concentration of tracer
-
D,D
*
dispersion coefficient
-
F
flux of tracer
-
G
probability distribution function for permeability in the stream-tube segments
-
I
tracer intensity (mass crossing a surface per unit time)
-
K
permeability
-
L
length of the medium
-
M
number of stream tubes in the medium
-
N
number of segments along a stream tube
-
P
pressure
-
Q
total flow rate in the sample
-
a
length of an elementary stream-tube segment
-
g
probability distribution function for permeability in the space
-
i, j
indices, tube numbers
-
q
flow rate in each stream tube
-
s
variable cross-section area of a stream tube
-
t, t
time
-
u
front velocity
-
x
space variable in the flow direction
-
small local variation in time
-
,
t
longitudinal, transverse dispersivity
-
porosity of the porous medium
-
correlation length in the permeability field
-
viscosity of the fluid
-
time for filling an elementary stream tube segment
-
standard deviation of a stochastic variable
-
probability distribution of arrival times (Gaussian) 相似文献
40.
Summary Enantiomeric separation of (–)-menthyl chloroformate derivatives of some chiral cardioactive drugs, on porous graphitic carbon (PGC), Hypercarb-S, is described. Capacity and separation factors of derivatives of the calcium channel blockers; amlodipine and UK52.829, the -blockers; atenolol, sotalol and propranolol, and mexiletine were studied in different chromatographic systems based on dichloromethane. A high content of a carboxylic acid in the mobile phase was found to decrease the retention and positively affect the stereoselectivity of the derivatives. A mobile phase with dichloromethane, acetonitrile and formic acid gave baseline separation of the enantiomers of amlodipine in less than 8 minutes. Results show that acetic acid and formic acid, may be regarded as strong organic solvents in PGC chromatography with nearly the same elution power as dichloromethane. 相似文献