首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   35795篇
  免费   3963篇
  国内免费   2326篇
化学   4018篇
晶体学   42篇
力学   3552篇
综合类   394篇
数学   24408篇
物理学   9670篇
  2024年   68篇
  2023年   344篇
  2022年   370篇
  2021年   590篇
  2020年   1032篇
  2019年   1045篇
  2018年   966篇
  2017年   936篇
  2016年   1066篇
  2015年   887篇
  2014年   1633篇
  2013年   3220篇
  2012年   1720篇
  2011年   2089篇
  2010年   1953篇
  2009年   2260篇
  2008年   2340篇
  2007年   2338篇
  2006年   1984篇
  2005年   1922篇
  2004年   1629篇
  2003年   1577篇
  2002年   1396篇
  2001年   1093篇
  2000年   1047篇
  1999年   986篇
  1998年   898篇
  1997年   783篇
  1996年   586篇
  1995年   475篇
  1994年   389篇
  1993年   261篇
  1992年   274篇
  1991年   242篇
  1990年   214篇
  1989年   138篇
  1988年   128篇
  1987年   122篇
  1986年   126篇
  1985年   134篇
  1984年   130篇
  1983年   67篇
  1982年   121篇
  1981年   108篇
  1980年   85篇
  1979年   85篇
  1978年   50篇
  1977年   50篇
  1976年   45篇
  1973年   17篇
排序方式: 共有10000条查询结果,搜索用时 108 毫秒
981.
This paper puts forward a new method to solve the electromagnetic parabolic equation (EMPE) by taking the vertically-layered inhomogeneous characteristics of the atmospheric refractive index into account. First, the Fourier transform and the convo- lution theorem are employed, and the second-order partial differential equation, i.e., the EMPE, in the height space is transformed into first-order constant coefficient differential equations in the frequency space. Then, by use of the lower triangular characteristics of the coefficient matrix, the numerical solutions are designed. Through constructing ana- lytical solutions to the EMPE, the feasibility of the new method is validated. Finally, the numerical solutions to the new method are compared with those of the commonly used split-step Fourier algorithm.  相似文献   
982.
In this paper uniform persistence is establised for kolmogorov type Prey‐Predator and competion models with per capitals ent growth rates that are dependent on time‐lagged population densities.  相似文献   
983.
Three new types of siloxane‐based photoactive liquid crystalline polymers containing azo side groups were synthesized through the click chemistry route. The polymers having molecular weight range of 14,000–34,000 g mol?1 were soluble in most of the polar solvents like chloroform, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, and dichloromethane. The photoresponsive trans–cis photoisomerization under UV radiation and cis–trans relaxation process in dark for the polymers were studied. The isomerization rate constants were found to be 0.01–0.04 sec?1 and 1.16*10?4–4.67*10?4 sec?1, respectively. It has been noted that the polymers showed high intensity absorption for n‐π* in chloroform. Both trans and cis forms of azide monomers having azo moiety exhibited molar extinction coefficient ( ? max) in the range of 22,000–33,000 L mol?1 cm?1. The thermotropic behavior of the polymers was studied by polarizing optical microscope (POM) and differential scanning calorimetry (DSC) experiments. Polymer P1 showed liquid crystalline textures of nematic droplets, whereas P2 showed smectic focal conic texture and nematic droplets. Polymer P1 was also studied for photomechanical bending on exposure to UV radiation. The polymers showed initial degradation temperature in the range of 210–275°C. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012  相似文献   
984.
Four linear polymers containing pendant azo moiety were synthesized through click chemistry for second‐order nonlinear optical study. The polymers were found soluble in most of the polar organic solvents such as tetrahydrofuran (THF), chloroform, and dimethyl formamide (DMF). The polymers showed thermal stability up to 300 °C and glass transition temperatures (Tg) in the range of 120–140 °C. The molecular weights (Mw) of these polymers (measured by gel permeation chromatography) were in the range 37,900–55,000 g/mol. The polymers were found to form optically transparent films by solution casting from THF solution. Order parameters were calculated from UV–vis absorption spectra. The morphology changes in the films after poling were characterized by atomic force microscopy. The angular dependence, temperature dependence, and time dependence of second harmonic generation (SHG) intensity were obtained by using 1064 nm Nd:YAG laser. The SHG intensity remained unchanged up to 95 °C. At room temperature, it remained stable up to 8 days after initial drop of about 14%. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012  相似文献   
985.
In this article, 10‐undecenoic acid, based on castor oil, was used a raw material for the synthesis of alternating copolymers. ω‐Unsaturated fatty esters as alkyl 10‐undecenoates were prepared by the esterification reaction of 10‐undecenoic acid with alkyl alcohol. A series of comb‐like copolymers were synthesized by free radical polymerization from maleic anhydride and alkyl 10‐undecenoates copolymers with different length of alkyl side chains in a toluene solution. These copolymers were investigated by 1H and 13C nuclear magnetic resonance, Fourier transform infrared spectroscopy, gel permeation chromatography, thermogravimetric analysis, differential scanning calorimetry (DSC). The copolymers were obtained in a low molecular weight in a range 3370–12,240 g mol−1 and their structural characterization indicated the formation of alternating copolymers. DSC characterization revealed that these comb‐like copolymers showed amorphous to semicrystalline behavior by increasing the length of side chains. The bio‐based comb‐like copolymers allow for the development of new polymeric materials for several applications. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 1039–1045  相似文献   
986.
Beta-type means     
Abstract

Based on the relationship between the Beta and the Euler Gamma function, beta-type functions of several variables, generated by a single variable function, are introduced. Applying the method of iterative functional equations, all means of beta-type are determined and some of their properties are discussed.  相似文献   
987.
988.
In his famous works of 1930 [1,2] Sergey L. Sobolev has proposed a construction of the solution of the Cauchy problem for the hyperbolic equation of the second order with variable coefficients in Rş. Although Sobolev did not construct the fundamental solution, his construction was modified later by Romanov (2002) and Smirnov (1964) to obtain the fundamental solution. However, these works impose a restrictive assumption of the regularity of geodesic lines in a large domain. In addition, it is unclear how to realize those methods numerically. In this paper a simple construction of a function, which is associated in a clear way with the fundamental solution of the acoustic equation with the variable speed in 3-d, is proposed. Conditions on geodesic lines are not imposed. An important feature of this construction is that it lends itself to effective computations.  相似文献   
989.
990.
《Optimization》2012,61(4):341-361
The ratio-conjugation-tool (RC) is constructed systematically, and its applicability for analysis of economic models is demonstrated. One of the main results establishes a general formula for RC of aggregative function. This tool is applied to the analysis of linear economic dynamics models of Neumann–Gale type which can be solved by a dynamic programming method: for each direct problem we construct the corresponding dual RC-problem. Moreover, we consider three examples of the most important economic dynamics models and look at these now from a unified general position.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号