Sensitive Amperometric Sensing of Hydrogen Peroxide Using Ag Nanowire Array Electrode

The amperometric sensor based on a silver nanowire (80 nm in diameter Ag NW) array electrode was fabricated and characterized with scanning electron microscope (SEM). The electrode showed good electrocatalytic activity for reduction of hydrogen peroxide. The effects of the applied polarization potential, pH, time interval between successive injections of analyte, injection volume and H₂O₂ concentration in a single injection on the electrochemical performance of the sensor were studied. It was found that the optimized operating conditions for the proposed sensor are: the potential of ?200 mV, pH between 7.4 and 9.0, 60 s time interval, 10 µL injection volume, and 500 µM H₂O₂ in single injection. The proposed Ag NW array sensor is free of interference from ascorbic acid, uric acid and glucose.     

Selective Template Removal by Thermal Depolymerization to Obtain Mesostructured Molybdenum Oxycarbide

The carbon content of mesostructured organic‐inorganic hybrid material of a cylindrical block copolymer template of poly(2‐vinylpyridine)‐block‐poly(allyl methacrylate) (P2VP‐b‐PAMA) and ammonium paramolybdate (APM) could be reduced by thermal depolymerization. By calcination in vacuo at 320 °C the PAMA core can be completely removed while the remaining P2VP brush preserves the mesostructure. The P2VP‐APM composite can then be carburized in‐situ to MoO_xC_y in a second pyrolysis step without any additional carbon source but P2VP. The molybdenum oxycarbide nanotubes obtained, form hierarchically porous non‐woven structures, which were tested as catalyst in the decomposition of NH₃. They proved to be catalytically active at temperatures above 450 °C. The activation energy was estimated from an Arrhenius Plot to be 127 kJ · mol^–1.     

Experimental evidence of energy pumping in acousticsMise en évidence expérimentale de pompage énergétique en acoustique

This Note presents an experimental vibro-acoustic set-up that aims to reproduce the energy pumping phenomenon between an acoustic medium and an essentially nonlinear oscillator. It shows a one-way irreversible transfer of energy between the first acoustic mode in a tube and a thin visco-elastic membrane. To cite this article: B. Cochelin et al., C. R. Mecanique 334 (2006).     

一类非齐次A-调和方程组很弱解的性质

该文应用Hodge分解定理，得到了非齐次A—调和方程组-Di(A^ij(x,Du)) Difj(i(x)=0,j=1,…，m的很弱解是弱解，进一步，利用Morrey空间法与Campanato空间法以及齐次化方法，作者得出了该方程的很弱解是局部Hoelder连续的，并且得出了Hoelder连续指数μ与λ之间的多值函数关系式．     

Influence of capillary effects on strength of non-saturated porous mediaInfluence des effets capillaires sur la résistance d'un milieu poreux non saturé

The mechanical behavior of a partially saturated porous medium is addressed by means of a micro-to-macro reasoning. First, an estimate of the quadratic average over the solid phase of the equivalent shear strain is proposed. The latter is used in the framework of a nonlinear homogenization technique (‘modified secant’ method) in order to model the nonlinear poroelastic behavior in partially saturated conditions. The determination of the macroscopic strength criterion is then considered. Finally, the influence of membrane tension effects on strength is investigated. To cite this article: L. Dormieux et al., C. R. Mecanique 334 (2006).     

大型稀疏矩阵的不完全因子分解法及预处理

本文对大型稀疏阵线性方程组的不完全因子分解及预处理法进行了研究。对对称正定阵和Ｌ阵分别提出了非对角元乘子不完全因子分解法的分解公式。对分解Ａ＝Ｍ－Ｎ，得到了当Ａ为对称正定时，Ｍ亦为对称正定，当Ａ为Ｌ阵时，分解为正规分裂等结果。并研究了预处理ＣＧ加速，最后的数值例子表明本文给出了的算法效果是良好的。     

A Non Homogeneous Riemann Solver for shallow water and two phase flows

In this work we consider a two steps finite volume scheme, recently developed to solve nonhomogeneous systems. The first step of the scheme depends on a diffusion control parameter which we modulate, using the limiters theory. Results on Shallow water equations and two phase flows are presented.     

A constructive semantics for non‐deducibility

This paper provides a constructive topological semantics for non‐deducibility of a first order intuitionistic formula. Formal topology theory, in particular the recently introduced notion of a binary positivity predicate, and co‐induction are two needful tools. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

无胶毛细管电泳分离碱基对范围宽的DNA片段

提出一种无胶毛细管电泳分离碱基对范围宽的ＤＮＡ片段的方法．用ＤＢ－１气相色谱毛细管柱，以羟乙基纤维素为筛分介质，研究了λＤＮＡ／ＥｃｏＲⅠ＋ＨｉｎｄⅢ限制性片段的分离，分离效率达１．２×１０６板／ｍ，检测限为２．１×１０－１７ｍｏｌ．应用于一种鲤鱼种族鉴别基因的聚合酶链反应（ＰＣＲ）扩增产物的分离鉴定，结果与实际相符，分离速度比传统电泳方法提高２０倍．     

一类非平稳m相依序列收敛于正态的非一致速率

本文在随机变量的矩母函数存在或者矩母函数不存在但各阶矩有限的条件下，讨论了一类非平稳ｍ相依的随机变量序列的标准化和分布收敛于正态分布的非一致速率。