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31.
Microwave Activation of Processes in Mesopores: The Thiourea Electrooxidation at Mesoporous Platinum
《Electroanalysis》2006,18(8):793-800
In situ microwave activation is applied to the electrochemical oxidation of thiourea at low surface area (polished polycrystalline) and at high surface area (electrodeposited mesoporous platinum coated) platinum microelectrodes. The one electron oxidation of thiourea to formamidine disulfide is monitored as a function of the different activation parameters. In the absence of microwaves (ambient temperature, low mass transport) increasing the surface area (roughness) increases the thiourea oxidation response predominantly due to adsorption effects. In the presence of high microwave intensities, high mass transport and thermal effects further increase the oxidation current at mesoporous platinum. The most effective thickness of the mesoporous platinum film for the thiourea oxidation process is estimated as 3 μm independent of electrode diameter, temperature, or mass transport effects. 相似文献
32.
This study analyzes the economics of transshipping biomass from truck to train in a North American setting. Transshipment
will only be economic when the cost per unit distance of a second transportation mode is less than the original mode. There
is an optimum number of transshipment terminals which is related to biomass yield. Transshipment incurs incremental fixed
costs, and hence there is a minimum shipping distance for rail transport above which lower costs/km offset the incremental
fixed costs. For transport by dedicated unit train with an optimum number of terminals, the minimum economic rail shipping
distance for straw is 170 km, and for boreal forest harvest residue wood chips is 145 km. The minimum economic shipping distance
for straw exceeds the biomass draw distance for economically sized centrally located power plants, and hence the prospects
for rail transport are limited to cases in which traffic congestion from truck transport would otherwise preclude project
development. Ideally, wood chip transport costs would be lowered by rail transshipment for an economically sized centrally
located power plant, but in a specific case in Alberta, Canada, the layout of existing rail lines precludes a centrally located
plant supplied by rail, whereas a more versatile road system enables it by truck. Hence for wood chips as well as straw the
economic incentive for rail transport to centrally located processing plants is limited. Rail transshipment may still be preferred
in cases in which road congestion precludes truck delivery, for example as result of community objections. 相似文献
33.
E.D. Aydin C.R.E. de Oliveira 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,84(3):247-260
In this paper, we solve the steady-state form of the Boltzmann transport equation in homogeneous and heterogeneous tissue-like media with a finite element-spherical harmonics (FE-PN) radiation transport method. We compare FE-transport and diffusion solutions in terms of the ratio of absorption to reduced scattering coefficient, (μa/μs′) and the anisotropy factor g. Two different scattering phase function formulas are employed to model anisotropic scattering in the slab media with high g-value. Influence of void-like heterogeneities, and of their boundaries with the surrounding medium on the transport of photons are also examined. 相似文献
34.
Mechanisms of ‘environmental decoherence’ such as surface scattering, Elliot–Yafet process and precession mechanisms, as well as their influence on the spin phase relaxation are considered and compared. It is shown that the ‘spin ballistic’ regime is possible, when the phase relaxation length for the spin part of the wave function (L(s)) is much greater than the phase relaxation length for the ‘orbital part’ (L(e)). In the presence of an additional magnetic field, the spin part of the electron's wave function (WF) acquires a phase shift due to additional spin precession about that field. If the structure length L is chosen to be L(s)>L>L(e), it is possible to ‘wash out’ the quantum interference related to the phase coherence of the ‘orbital part’ of the WF, retaining at the same time that related to the phase coherence of the spin part and, hence, to reveal corresponding conductance oscillations. 相似文献
35.
X.X. Guo 《Surface science》2004,549(3):211-216
We studied parallel conductivities of pure BaF2 films with thicknesses ranging from 35 to 300 nm, epitaxially grown on Al2O3(0 1 2) substrates by molecular beam epitaxy technique. The overall conductivities of the films are found to increase with decreasing thickness. The detailed investigation of the overall conductance as a function of the thickness permits the deconvolution of bulk and boundary effects, the latter being attributed to distinct space charge effects in the interface between BaF2 film and Al2O3 substrate. The (extrinsic) Debye length (λ) is estimated to be about 8 nm at T=593 K, which corresponds to an impurity content of 1018/cm3 (singly ionized dopant assumed). This is consistent with the fact that we observed a constant boundary contribution for all investigated films (film thickness >4λ). It is also consistent with the Debye length observed in a previous report on CaF2/BaF2 heterolayers fabricated by the same technique, in which the low temperature enhancement was also attributed to space charges in BaF2 [Nature 408 (2000) 946]. Only at low temperatures (below 370 °C), the conductance seems to be influenced by strain effect. 相似文献
36.
Effect of Deborah number and phase difference on peristaltic transport of a third-order fluid in an asymmetric channel 总被引:1,自引:0,他引:1
The effect of a third-order fluid on the peristaltic transport in an asymmetric channel is studied. The wavelength of the peristaltic waves is assumed to be large compared to the varying channel width, whereas the wave amplitudes need not be small compared to the varying channel width. The channel asymmetry is produced by choosing the peristaltic wave train on the walls to have different amplitudes and phase. The flow is investigated in a wave frame of reference moving with velocity of the wave. The effects of Deborah number, phase difference, varying channel width and wave amplitudes on the pumping characteristics, streamline pattern and trapping phenomena are investigated. It is observed that the trapping regions increase as the channel becomes more and more symmetric and the trapped bolus volume decreases for increasing Deborah number, phase difference and varying channel width whereas it increases for increasing flow rate and wave amplitudes. Furthermore, the obtained results could also have applications to a range of peristaltic flows for a variety of non-Newtonian fluids such as aqueous solutions of high-molecular weight polyethylene oxide and polyacrylamide. 相似文献
37.
Liquid chromatography-electrospray ionisation mass spectrometry was evaluated in the high-throughput analysis of microcystins and nodularins, cyanobacterial peptide hepatotoxins. Extracts originating from cyanobacterial strains and field material were separated on a 30 mm × 4 mm I.D. Merck Purospher STAR RP-18e column using a rapid gradient of aqueous formic acid and acetonitrile, ionised by electrospray technique and analysed on a Micromass Quattro II triple-quadrupole mass spectrometer operated in the selected ion recording (SIR) mode. The total analysis time per sample was 2.8 min corresponding to 514 samples a day. The system showed good robustness during a series of 320 repetitive injections of a field sample containing three major microcystins. 相似文献
38.
在LP(1 P<∞)空间研究了板模型中一类带广义边界条件具各向异性、连续能量、均匀介质迁移算子的谱,证明了该迁移算子生成C0半群的D yson—Ph illips展开式的二阶余项在LP(1
相似文献
39.
A fully coupled formulation combining reactive transport and an existing thermo-hydro-mechanical (THM) code is presented.
Special attention has been given to phenomena likely to be encountered in clay barriers used as part of containment systems
of nuclear waste. The types of processes considered include hydrolysis, complex formation, oxidation/reduction reactions,
acid/base reactions, precipitation/dissolution of minerals and cation exchange. Both kinetically-controlled and equilibrium-controlled
reactions have been incorporated. The total analytical concentrations (including precipitated minerals) are adopted as basic
transport variables and chemical equilibrium is achieved by minimizing Gibbs Free Energy. The formulation has been incorporated
in a general purpose computer code capable of performing numerical analysis of engineering problems. A validation exercise
concerning a laboratory experiment involving the heating and hydration of an expansive compacted clay is described. 相似文献
40.
Stability of tokamak plasmas with internal transport barriers against high n ideal magnetohydrodynamic ballooning mode 下载免费PDF全文
A ballooning mode equation for tokamak plasma, with the toroidicity and the Shafranov shift effects included, is derived for a shift circular flux tokamak configuration. Using this equation, the stability of the plasma configuration with an internal transport barrier (ITB) against the high n (the toroidal mode number) ideal magnetohydrodynamic (MHD) ballooning mode is analysed. It is shown that both the toroidicity and the Shaftanov shift effects are stabilizing. In the ITB region, these effects give rise to a low shear stable channel between the first and the second stability regions. Out of the ITB region towards the plasma edge, the stabilizing effect of the Shaftanov shift causes the unstable zone to be significantly narrowed. 相似文献