氘化聚酯型聚脲氨酯弹性体的红外光谱研究

用红外光谱法对基于4,4′－二苯基甲烷二异氰酸酯（MDI）、乙二胺（ED）和聚己二酸丁二醇酯（PBA）的嵌段聚酯型聚脲氨酯（PUU）弹性体及其氚化产物进行了研究。结果表明氚化反应对PUU中涉及PUU中涉及氢键化N－H振动红外吸收光谱带的影响较大,受氚化影响较大的那些谱带分别在3332,3190,1600,1539,1317,1257和1230cm^-1附近。另外也发现不同硬段含量和不同聚酯软段分子量的PUU受氚化影响的程度基本相似。     

基于矩和小波变换的目标图象识别

在图象目标的识别中,目标图象的不变矩对于具有旋转、尺度变换特性的目标具有良好特征匹配性能,但其识别准确度直接受到不变矩计算区域内的目标个数的影响.本文首先采用一维小波变换降噪并获取图象边缘,结合轮廓跟踪法(“爬虫法”)与投影法对图象进行区域分割获取各目标存在区域,再利用目标图象的不变矩进行目标识别,最后通过利用目标的主轴特性及质心变化计算目标的旋转角度及尺度变换倍率.通过仿真实验,证明方案可行且具有良好的识别性能.     

Analysis of dynamical buckling and post buckling for beams by finite segment method

IntroductionThe stability or dynamical buckling of structures is the parametrically exacted vibration ofstructures,and itis a nonlinear vibration problem[1].Dynamical stabilityof beams was studiedusing Galerkin variation method by Russian scholar,and B.B.…     

Spectral–Luminescence Properties of Molecular Complexes of Photoconductive Polymers with Neutral Organic Acceptors

It has been found that in films of aryl– and alkyl–substituted polysilanes -- poly(methylphenylsilane) and poly(dihexylsilanes) -- the molecules of electron acceptors of tetracyanoquinodimethane, dinitrofluorenone, and trinitrofluorenone form weak complexes with charge transfer from the longest segments of the polymeric chain. The absorption and luminescence spectra of these complexes are similar to the spectra of complexes formed by the carbonyl groups of poly–N–epoxypropyl carbazole with the above acceptors and consist of wide bands situated in the visible range of wavelengths.     

聚氨酯硬链段球晶生长与软硬链锻混容性的关系

线型可溶性聚氨酯的硬链段结晶难以长成球晶 ,然而本实验室已经证明即使从熔体结晶硬链段也是能够长成球晶的 .研究了聚酯与聚醚型聚氨酯硬链段长球晶的规律 ,并发现聚氨酯硬链段长球晶的难易与聚氨酯软硬链段混容性密切相关 .动态力学分析 (DMA)与示差扫描量热 (DSC)实验表明聚ε 已内酯 (PCL)、聚已二酸丁二醇酯 (PTMA)、聚四氢呋喃 (PTMO)及聚环氧丙烷 (PPO)型聚氨酯的软硬链段混容性从前至后递减 .从熔体退火结晶时 ,聚氨酯硬链段长成球晶的退火温度范围是有限的 ,软硬链段混容性越好 ,聚氨酯硬链段能长成球晶的温度范围越窄 ,所需长的时间越长 .聚氨酯硬链段长球晶的下限温度取决于软硬链段间所存在的氢键作用 ,聚氨酯硬链段长球晶的上限温度与软硬链段混容性直接相关 .     

不同软段聚氨酯的透气性研究

热塑性聚氨酯弹性体是一种包含有软、硕段的多嵌段聚合物,有关其结构与性质的研究已有很多报道^[1,2],但对它的透气性质研究尚少.McBride^[3]和 Knight^[4]等曾对不同硬段含量、不同扩链剂的聚氨酯透气性质作过研究.本工作着重研究不同软段结构和软段长度对聚氨酯透气性的影响,以及含混合软段的聚氨酯的透气性.     

一种证明二次有理Bézier曲线曲率分布特征的新方法

本文给出了一种证明二次有理Bézier曲线曲率分布特征的新方法.该方法主要通过利用圆锥曲线的几何特征,得到圆锥曲线段的对称轴方程;并基于控制顶点和对称轴的位置,给出了二次有理Bézier曲线的曲率分布特征定理.这个方法与其他学者提出的方法相比更简单,更容易理解.     

Cell theory and equation‐of‐state of chain molecular systems: Application to polymer solids

We use the Lennard‐Jones and Devonshire cell theory without any ad hoc simplification of the cell potential to obtain the equation‐of‐state (EOS) for chain molecular systems. The interactions of the central segment with second and third shells of neighbors are taken into account. Numerical values of the cell integrals are given in tabular form along with interpolation expressions that cover the range of PVT variables appropriate to polymers. Results of comparison with EOS based on square‐well form are also discussed. Application of the theory to polymer glasses of diverse structures is found to be quite successful in explaining the PVT behavior over a wide range of temperatures both at atmospheric and elevated pressures. Further, scaled volume at the glass‐transition temperature is discovered to be a corresponding state property. Turning to crystals, the theory is generally in good accordance with the PVT data of three well‐studied polymers both at atmospheric and elevated pressures. For linear polyethylene the agreement is good up to 42 kbar for the room‐temperature isotherm. On the other hand, at higher temperatures where the data are limited to 5 kbar, the agreement is determined to be satisfactory for the three polymers. © 2001 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 515–530, 2001     

Attempt to control monomer sequences in copolycondensations of IPA,TPA, BPA,and PHB

Copolycondensations of IPA, TPA, BPA, and PHB were studied to investigate how PHB, which can form mesogenic segments, should be incorporated into the amorphous IPA/TPA–BPA polyester to obtain the thermotropic copolyester, unlike other copolymerizations studied so far by randomly introducing nonmesogenic components into the liquid crystalline polyesters. Random and controlled copolycondensations were attempted to regulate the segment length of mesogenic PHB units by stepwise addition of BPA and PHB through the two- and three-stage reactions using TsCl/DMF/Py as a condensing agent. Thermotropic copolyesters with ca. 40 mol % PHB could be obtained by a three-stage reaction, despite that more than 70 mol % PHB is needed to prepare by usual random copolymerization with PHB. The segment length of the PHB unit was indirectly studied from IPA/TPA–BPA oligomer distribution at initial reaction by means of GPC and from the NMR analysis of the resulting copolymers. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 2371–2377, 1999