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161.
A.F. Mesquita A.O. Porto G.M. de Lima J.M. Delgado F.S. Lameiras 《Solid State Communications》2005,136(3):133-137
Hexagonal and cubic cadmium selenide were prepared from a chemical route by using cadmium chloride and potassium selenium hydride obtained from reaction of selenium powder and potassium boron hydride. The product obtained was thermally treated under argon flux at 300, 500 and 600 °C for 2 h and characterized by X-ray photoelectron spectroscopy and X-ray diffraction. The X-ray diffraction data were refined by Rietveld method and the structural parameters were determined for the phases of each annealed samples. At 300 °C five phases were identified: Cubic and hexagonal cadmium selenides and the contaminants: Potassium chloride, boron oxide and cadmium boron oxide. At 500 and 600 °C only the hexagonal cadmium selenide phase was identified besides the other above mentioned contaminant. 相似文献
162.
A homologous series of azomesogens, 2″-[4-(4′-n-alkoxybenzoyloxy)-2-chlorophenylazo] naphthalenes, with lateral chloro groups was synthesised. All the homologues synthesized
exhibit enantiotropic nematic mesophase. The mesomorphic properties of the present series are compared with other structurally
related series to evaluate the effect of lateral chloro group and its position on mesomorphism
This paper was presented at the 10th National Conference on Liquid Crystals held at Bangalore, India during 9–11 October 2003. 相似文献
163.
电子束流品质对自由电子激光小信号增益影响的计算 总被引:1,自引:0,他引:1
对电子束有一定初始能量分散或角度分散时的自由电子激光小信号增益用较简便的方法进行了分析计算,并给出了一个渐近公式,结果与用计算机模拟解自由电子激光微分方程组得到的结果一致。 相似文献
164.
S. Guizard D. Chapoulard M. Horani D. Gauyacq 《Applied physics. B, Lasers and optics》1989,48(6):471-477
Resonantly enhanced multiphoton ionization (REMPI) is proposed as an ultrasensitive detection method forreal-time monitoring of atmospheric pollutants in situ. The technique is demonstrated in the laboratory for NO diluted in pure nitrogen at 560 mbar. The MPI current resulting from (2+1) photon ionization of NO via the resonantC
2
H (v=0) state has been measured for several NO concentrations. Detection levels as low as 50 ppt have been obtained.Laboratoire associé à l'Université de Paris-Sud 相似文献
165.
Electron beam induced quantitative X-ray mapping has become a very useful characterisation tool for determining the elemental
distribution in materials, whether using energy dispersive spectroscopy or wavelength dispersive spectroscopy. The X-ray intensity
distributions of the elements from an X-ray map allow us to generate two dimensional and ternary scatter diagrams thus converting
spatial information into concentration dimensions, which is an important tool for displaying the spatial relationships of
elements or correlated elements (phases) in materials. To best understand how to use this tool, we need to understand the
production and features of the scatter diagram. The type of clustering observed in the scatter diagram, whether oval, linear
or spherical, can give the major and trace element distributions within phases as well as qualitative and quantitative phase
information. This paper demonstrates the generation of scatter diagrams, properties of scatter diagrams, interpretation of
scatter diagrams and the advantages of scatter diagrams through the use of examples. 相似文献
166.
P.A. Grillet 《Acta Mathematica Hungarica》2005,106(4):301-315
Summary Three weak variants of compactness which lie strictly between compactness and quasicompactness, are introduced. Their basic properties are studied. The interplay with mapping and their direct and inverse preservation under mappings are investigated. In the process three decompositions of compactness are observed. 相似文献
167.
Comprehensive studies of X-ray diffraction, oxygen content, superconductivity and Mössbauer effect have been made on FexCu1−xBa2YCu2O7+y superconductors (0.00≤x≤0.70) synthesized by ambient (AM) and high pressure (HP). Results indicate that all the HP-samples have tetragonal structure, smaller lattice parameter c and unit-cell volume than the AM-samples. The studies of oxygen content, and Mössbauer spectroscopy indicate that the HP-samples have higher oxygen content, carrier concentration and average valence of Fe than the AM-samples. Moreover, for the HP-samples more Fe atoms located in CuOx chains have fivefold-oxygen coordination. These are important reasons for the enhancement of Tc in the HP-samples. 相似文献
168.
Wincenty Turek Mieczyslaw Lapkowski Agnieszka Stolarczyk 《Applied Surface Science》2005,252(3):801-806
The goal of our studies was to determine the nature of interactions between catalytic active samples, such as polypyrrole (PPy) doped with: chloride anions, heteropolyacids such as H5PMo10V2O40, or H4SiW12O40, and oxygen particles. In order to reveal the mechanism of the linkage between the catalysts and oxygen we provided the electron paramagnetic resonance (EPR) measurements of synthesized samples in O2 and N2 flow. Moreover, the X-ray photoelectron spectroscopy (XPS) measurements were performed to show the properties of doped heteropolyacids and the state of nitrogen in polypyrrole matrix. The results of EPR studies of PPy(Cl), PPy(H4SiW12O40), PPy(H5PMo10V2O40) samples, show that the polypyrrole doped with chloride anions interacts much easier with oxygen than polypyrrole doped with heteropolyacids (in the above given order, of preference with the most active polypyrrole system first). It correlates with XPS results, which show that a molybdenium-vanadium anion is more reduced than a silicon-tungsten one. The redox reactions of heteropolyacids involve the oxidation-reduction of the conjugated polymer chain, leaving no or little place for interactions with oxygen. Polypyrrole doped with H4SiW12O40 shows some oxygen sensitivity as observed in the EPR studies, as opposed to polypyrrole doped with H5PMo10V2O40, which is in line with the XPS results. 相似文献
169.
Dan Voiculescu 《Reports on Mathematical Physics》2005,55(1):127-133
This short note summarizes the circumstances of the birth of free probability theory andsome of the recent achievements. 相似文献
170.