Vinyl‐type polymerization of norbornene by nickel(II) bisbenzimidazole catalysts

Novel nickel(II) bisbenzimidazole complexes were prepared via a three‐step synthetic procedure consisting of aniline/diacid condensation, ligand N‐alkylation, and metal complexation. The complexes were characterized by X‐ray crystallography and found to possess a pseudotetrahedral geometry. Upon activation with methylaluminoxane, these nickel bisbenzimidazoles did not polymerize simple olefins (e.g., ethylene, propylene, and 1‐butene) but were found to carry out the rapid and efficient polymerization of norbornene. The polynorbornene products were characterized by gel permeation chromatography/light scattering, ¹³C NMR, and IR, and their Mark–Houwink and dn/dc parameters were determined. The molecular weights of the polynorbornenes were very high (weight‐average molecular weight = 587,000–797,000 g/mol). ¹³C NMR suggested that the polymerization occurred via vinyl addition (i.e., a 2,3‐linked polymer); no ring‐opened product was observed. Thermogravimetric analysis indicated that the polynorbornenes were stable up to 400 °C under nitrogen. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2095–2106, 2003     

Accelerated glycosylation under frozen conditions

O-Glycosylations using thiomethyl glycosides as donors were compared under both frozen and unfrozen conditions. In the presence of MeOTf as a promoter, enormous rate acceleration was observed when the glycosylation was conducted in p-xylene below its freezing point.     

Iterative Schemes for Nonconvex Variational Inequalities

In this paper, we suggest and analyze some iterative methods for solving nonconvex variational inequalities using the auxiliary principle technique, the convergence of which requires either only pseudomonotonicity or partially relaxed strong monotonicity. Our proofs of convergence are very simple. As special cases, we obtain earlier results for solving general variational inequalities involving convex sets.     

Introduction to Hardy Spaces

Basic material from the theory of Hardy spaces is presented. The principle of positive energy representations is used as motivation to introduce these spaces.     

Banach空间中拟-似变分包含解的存在与逼近问题

研究了Banach空间中拟-似变分包含解的存在与逼近问题.给出了一种寻求解的新的迭代算法,建立了具混合误差的Ishikawa型迭代序列强收敛到解的充要条件.所得结果推广了一些相关的结果.     

Intégalités de Sobolev et Temps d'Atteinte

We investigate the links between Sobolev and Nash inequalities, capacity and hitting times estimates and ultracontractive semigroups, in a non-symmetric setting.     

Preparation of Papers

We motivate the study of a vector variational inequality by a practical flow equilibrium problem on a network, namely a generalization of the well-known Wardrop equilibrium principle. Both weak and strong forms of the vector variational inequality are discussed and their relationships to a vector optimization problem are established under various convexity assumptions.     

The Equivalence of Several Basic Theorems for Subdifferentials

Several different basic tools are used for studying subdifferentials. They are a nonlocal fuzzy sum rule in (Borwein et al., 1996; Zhu, 1996), a multidirectional mean value theorem in (Clarke and Ledyaev, 1994; Clarke et al., 1998), local fuzzy sum rules in (Ioffe, 1984, 1990) and an extremal principle in (Kruger and Mordukhovich, 1980; Mordukhovich, 1976, 1980, 1994). We show that all these basic results are equivalent and discuss some interesting consequences of this equivalence.     

ON THE COHOMOLOGY OF GENERALIZED RESTRICTED LIE ALGEBRAS

0.IntroductionThispaperisaimedatdevelopingthecohomologytheoryofmodularLiealgebrasandthendeterminingthefirstcohomologygroupsofCartantypeLiealgebras.AsgeneralizationoftheconceptofrestrictedLiealgebras,ageneralizedrestrictedLiealgebra(GRLiealgebra)wasintroducedin[21],whichisassociatedwithabasisandamappingofthebasisintotheLiealgebrasatisfyingthegeneralized-restrictednessconditions.Generalizedrestrictedrepresentations(GRrepresentations)werethenintroduced,whichcanbereducedtotherepresentationsofa…     

Precise Asymptotics for Lévy Processes

Let {X（t）, t ≥ 0} be a Lévy process with EX（1） = 0 and EX^2（1） 〈 ∞. In this paper, we shall give two precise asymptotic theorems for {X（t）, t 〉 0}. By the way, we prove the corresponding conclusions for strictly stable processes and a general precise asymptotic proposition for sums of i.i.d. random variables.