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991.
本文通过模拟纯谱及非零截距的引入,改进了因子分析-光度法。用该法探讨了以对硝基苯基荧光酮及溴代十六烷基三甲铵作为试剂的多元络合物体系同时测定锗、钼、钨、锡的最佳条件。实验证实用该法测定合成样品及钢样,结果满意。 相似文献
992.
The aim of this paper is to study numerical realization of the conditions of Max Nther's residual intersection theorem. The numerical realization relies on obtaining the intersection of two algebraic curves by homotopy continuation method, computing the approximate places of an algebraic curve, getting the exact orders of a polynomial at the places, and determining the multiplicity and character of a point of an algebraic curve. The numerical experiments show that our method is accurate, effective and robust without using multiprecision arithmetic,even if the coefficients of algebraic curves are inexact. We also conclude that the computational complexity of the numerical realization is polynomial time. 相似文献
993.
Summary: The conformational behavior of a polymer in a critical binary solvent confined in a porous medium is studied. The size of the polymer in bulk, which is mainly governed by the correlation length of the solvent density fluctuations, depends on the proximity to the critical point of the binary mixture. We find that in contrast to the bulk behavior, the conformational properties of the polymer in a porous medium depends strongly on the pore size. The latter controls the correlation length of the solvent density fluctuations and thus determines the polymer size. 相似文献
994.
Dongmei Tang Jiaping Lin Shaoliang Lin Suning Zhang Tao Chen Xiaohui Tian 《Macromolecular rapid communications》2004,25(13):1241-1246
Summary: Self‐association behaviors of poly(γ‐benzyl L ‐glutamate)‐graft‐poly(ethylene glycol) (PBLG‐graft‐PEG) and its mixtures with PBLG homopolymer in aqueous media were investigated by fluorescence spectroscopy, transmission electron microscopy (TEM), and nuclear magnetic resonance (NMR) spectroscopy. It was revealed that PBLG‐graft‐PEG could self‐assemble to form polymeric micelles with a core‐shell structure in the shape of spindle. The introduction of PBLG homopolymer not only decreases the critical micelle concentration, but also changes the morphology of the micelles.
995.
B. Lobe W. Janke K. Binder 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,7(2):283-291
We analyze recently extended high-temperature series expansions for the “Edwards-Anderson” spin-glass susceptibility of the
p-state Potts glass model on d-dimensional hypercubic lattices for the case of a symmetric bimodal distribution of ferro- and antiferromagnetic nearest-neighbor
couplings . In these star-graph expansions up to order 22 in the inverse temperature , the number of Potts states p and the dimension d are kept as free parameters which can take any value. By applying several series analysis techniques to the new series expansions,
this enabled us to determine the critical coupling Kc and the critical exponent of the spin-glass susceptibility in a large region of the two-dimensional (p,d)-parameter space. We discuss the thus obtained information with emphasis on the lower and upper critical dimensions of the
model and present a careful comparison with previous estimates for special values of p and d.
Received: 25 May 1998 / Revised and Accepted: 11 August 1998 相似文献
996.
The neutron response of electrochemically etched (ECE) CR-39 detectors is determined by the energy and angular dependence of the response to neutron-induced charged particles. This response has been measured for the example of protons with various initial energies and angles of incidence. Besides, some studies were made for modeling the mechanism of ECE of the proton trajectories with the aim of deriving the critical angle of incidence. 相似文献
997.
A.K. Hartmann U. Nowak 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,7(1):105-109
We investigate the critical behavior of three-dimensional random-field Ising systems with both Gauss and bimodal distribution
of random fields and additional the three-dimensional diluted Ising antiferromagnet in an external field. These models are
expected to be in the same universality class. We use exact ground-state calculations with an integer optimization algorithm
and by a finite-size scaling analysis we calculate the critical exponents , , and . While the random-field model with Gauss distribution of random fields and the diluted antiferromagnet appear to be in same
universality class, the critical exponents of the random-field model with bimodal distribution of random fields seem to be
significantly different.
Received: 9 July 1998 / Received in final form: 15 July 1998 / Accepted: 20 July
1998 相似文献
998.
F. Decker K.-P. Holzer P. Mischo J. Petersson D. Schüßler 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,8(4):507-510
The NMR satellite frequencies were measured as a function of temperature in the normal high-temperature phase for 87Rb in Rb2ZnBr4 and Rb2ZnCl4 and for 35Cl in betaine calciumchloride dihydrate. Approaching the respective normal-incommensurate phase transition an anomalous shift
of the NMR frequency is observed for the first two cases. This effect is ascribed to the increasing order parameter fluctuations.
The experimental data are compared to calculations which relate the observed behaviour of the NMR frequencies to the non-classical
critical behaviour of the substances under investigation.
Received 6 August 1998 相似文献
999.
H. Feldmann R. Oppermann 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,10(3):429-445
We analyse the competition between spin glass (SG) order and local pairing superconductivity (SC) in the fermionic Ising spin
glass with frustrated fermionic spin interaction and nonrandom attractive interaction. The phase diagram is presented for
all temperatures T and chemical potentials μ. SC-SG transitions are derived for the relevant ratios between attractive and frustrated-magnetic
interaction. Characteristic features of pairbreaking caused by random magnetic interaction and/or by spin glass proximity
are found. The existence of low-energy excitations, arising from replica permutation symmetry breaking (RPSB) in the Quantum
Parisi Phase, is shown to be relevant for the SC-SG phase boundary. Complete 1-step RPSB-calculations for the SG-phase are
presented together with a few results for -step breaking. Suppression of reentrant SG-SC-SG transitions due to RPSB is found and discussed in context of ferromagnet-SG
boundaries. The relative positioning of the SC and SG phases presents a theoretical landmark for comparison with experiments
in heavy fermion systems and high superconductors. We find a crossover line traversing the SG-phase with as its quantum critical (end)point in complete RPSB, and scaling is proposed for its vicinity. We argue that this line indicates
a random field instability and suggest Dotsenko-Mézard vector replica symmetry breaking to occur at low temperatures beyond.
Received 26 November 1998 and Received in final form 25
January 1999 相似文献
1000.
H.K. Janssen K. Oerding F. van Wijland H.J. Hilhorst 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,7(1):137-145
We consider two stochastic processes, the Gribov process and the general epidemic process, that describe the spreading of
an infectious disease. In contrast to the usually assumed case of short-range infections that lead, at the critical point,
to directed and isotropic percolation respectively, we consider long-range infections with a probability distribution decaying
in d dimensions with the distance as . By means of Wilson's momentum shell renormalization-group recursion relations, the critical exponents characterizing the
growing fractal clusters are calculated to first order in an -expansion. It is shown that the long-range critical behavior changes continuously to its short-range counterpart for a decay
exponent of the infection .
Received: 17 July 1998 / Revised: 20 July 1998 / Accepted: 28 July 1998 相似文献