全文获取类型
收费全文 | 25978篇 |
免费 | 2000篇 |
国内免费 | 2108篇 |
专业分类
化学 | 6402篇 |
晶体学 | 317篇 |
力学 | 2590篇 |
综合类 | 340篇 |
数学 | 14769篇 |
物理学 | 5668篇 |
出版年
2024年 | 40篇 |
2023年 | 208篇 |
2022年 | 261篇 |
2021年 | 391篇 |
2020年 | 528篇 |
2019年 | 544篇 |
2018年 | 461篇 |
2017年 | 578篇 |
2016年 | 615篇 |
2015年 | 478篇 |
2014年 | 858篇 |
2013年 | 1704篇 |
2012年 | 1134篇 |
2011年 | 1345篇 |
2010年 | 1302篇 |
2009年 | 1928篇 |
2008年 | 2109篇 |
2007年 | 1983篇 |
2006年 | 1720篇 |
2005年 | 1348篇 |
2004年 | 1149篇 |
2003年 | 1212篇 |
2002年 | 1073篇 |
2001年 | 867篇 |
2000年 | 772篇 |
1999年 | 705篇 |
1998年 | 674篇 |
1997年 | 528篇 |
1996年 | 427篇 |
1995年 | 357篇 |
1994年 | 333篇 |
1993年 | 243篇 |
1992年 | 241篇 |
1991年 | 195篇 |
1990年 | 155篇 |
1989年 | 112篇 |
1988年 | 132篇 |
1987年 | 109篇 |
1986年 | 100篇 |
1985年 | 160篇 |
1984年 | 170篇 |
1983年 | 86篇 |
1982年 | 160篇 |
1981年 | 143篇 |
1980年 | 92篇 |
1979年 | 83篇 |
1978年 | 83篇 |
1977年 | 55篇 |
1976年 | 44篇 |
1974年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Christopher J. Nichols 《Tetrahedron letters》2004,45(40):7469-7473
A number of new functionalised bridged indolocarbazole systems have been prepared by ring-opening reactions of a key cyclic sulfate intermediate, prepared from the corresponding diol by the action of sulfuryl diimidazole and DBU. The same cyclic sulfate also undergoes an unprecedented asymmetric rearrangement to a chiral ketone, on treatment with a chiral lithium amide base. 相似文献
82.
The problem of investigation of the amplitude and phase structure of a time-varying probing optical signal and the structure of time-varying inhomogeneities of a substance tested by this signal is considered. The analysis is concerned, in particular, with determination of the structure of signals and processes with resolution in the pico- and femtosecond range. The scheme used for the analysis is based on registration of four spatially separated spectra of the studied radiation. The spectra are formed in a four-channel scheme with a twin-wave Michelson interferometer and a spectral device. Modulators based on electrooptical crystals (perovskites) are placed in the channels. The sum spectra are formed: without modulators, with the effect of either of the modulators, and with both of them affecting the radiation. The effect of the studied substance implies either modulating the radiation (in this case it is described by multiplication) or redistributing the radiation (then it is described by convolution). 相似文献
83.
EXAFS study of liposome-encapsulated cisplatin 总被引:1,自引:0,他引:1
《Colloids and surfaces. B, Biointerfaces》2004,33(3-4):199-204
The anticancer agent cisplatin encapsulated in sterically stabilized liposomes is studied with extended X-ray absorption fine structure (EXAFS) method. Analysis of local atomic structure around Pt atoms clearly indicates that the liposome-encapsulated drug is chemically stable and does not hydrolyze. Cisplatin forms a supersaturated solution in the liposome interior at a concentration about eight-fold above its aqueous solubility. 相似文献
84.
Yaron Paz Ellina Kesselman Lulu Fahoum Irina Portnaya Ory Ramon 《Journal of Polymer Science.Polymer Physics》2004,42(1):33-46
The effect of two strong salting-out salts (Na2SO4 and K2SO4) on the temperature-induced phase-separation process in aqueous solutions of poly(N-isopropylacrylamide) (PNIPA) was examined by attenuated total reflectance/Fourier transform infrared spectroscopy, differential scanning calorimetry, and viscosity measurements. On the basis of these measurements, a detailed scenario of the phase-separation process was deduced. The phase-separation scenario of solutions containing PNIPA and water was altered in the presence of sulfate ions. Here, the sulfate ions induced partial intrachain collapse, manifested by a relatively compact structure well below the lower critical solution temperature. This led to a more gradual, smooth phase transition, with temperature-resolved intrachain collapse and interchain aggregation and a lesser extent of hysteresis. Although at the macrolevel one may not be able to differentiate among various scenarios altering the solvent into a poor solvent, the aforementioned microlevel measurements provided a way to expose the difference between raising the temperature and adding cosolutes. Follow-up studies on the effect of salting-in salts will be presented. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 33–46, 2004 相似文献
85.
Behavior of cellulose in NaOH/Urea aqueous solution characterized by light scattering and viscometry
Cellulose was dissolved in 6 wt % NaOH/4 wt % urea aqueous solution, which was proven by a 13C NMR spectrum to be a direct solvent of cellulose rather than a derivative aqueous solution system. Dilute solution behavior of cellulose in a NaOH/urea aqueous solution system was examined by laser light scattering and viscometry. The Mark–Houwink equation for cellulose in 6 wt % NaOH/4 wt % urea aqueous solution at 25 °C was [η] = 2.45 × 10?2 weight‐average molecular weight (Mw)0.815 (mL g?1) in the Mw region from 3.2 × 104 to 12.9 × 104. The persistence length (q), molar mass per unit contour length (ML), and characteristic ratio (C∞) of cellulose in the dilute solution were 6.0 nm, 350 nm?1, and 20.9, respectively, which agreed with the Yamakawa–Fujii theory of the wormlike chain. The results indicated that the cellulose molecules exist as semiflexible chains in the aqueous solution and were more extended than in cadoxen. This work provided a novel, simple, and nonpollution solvent system that can be used to investigate the dilute solution properties and molecular weight of cellulose. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 347–353, 2004 相似文献
86.
对于超细长弹性杆静力学的Kirchhoff方程,用动力学的概念和方法研究其常值特解 和稳定性问题.计算了Kirchhoff方程相对固定坐标系、截面主轴坐标系以及中心线Frenet 坐标系的常值特解,进行了Kirchhoff动力学比拟,用一次近似理论分别讨论了它们的Lyapu nov稳定性,导出了若干稳定性判据,并在参数平面上绘出了稳定域.
关键词:
超细长弹性杆
Kirchhoff方程
常值特解
Lyapunov稳定性 相似文献
87.
对Cl/HN3/I2产生NCl(a)/I激光的过程进行了化学动力学计算,主要考察了Cl,HN3和I2的初始粒子数密度及其配比对小信号增益系数的影响。结果发现,当温度为400K, 初始Cl粒子数密度为1×1015,1×1016和1×1017cm-3时,小信号增益系数分别达到1.6×10-4,1.1×10-3和1.1×10-2cm-1,获得最佳小信号增益系数的HN3和I2的初始粒子数密度分别为初始Cl粒子数密度的1~2倍和2%~4%。同时,对Cl,HN3和I2配比对小信号增益系数和增益持续时间的影响进行了讨论。 相似文献
88.
For vector quasivariational inequalities involving multifunctions in topological vector spaces, an existence result is obtained without a monotonicity assumption and with a convergence assumption weaker than semicontinuity. A new type of quasivariational inequality is proposed. Applications to quasicomplementarity problems and traffic network equilibria are considered. In particular, definitions of weak and strong Wardrop equilibria are introduced for the case of multivalued cost functions. 相似文献
89.
Wolfgang Knirsch 《Mathematische Nachrichten》2004,265(1):15-23
On weighted spaces with strictly plurisubharmonic weightfunctions the canonical solution operator of and the ‐Neumann operator are bounded. In this paper we find a class of strictly plurisubharmonic weightfunctions with certain growth conditions, so that they are Hilbert‐Schmidt operators between weighted spaces with different weightfunctions, if they are restricted to forms with holomorphic coefficients. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
90.
M. A. Efendiev J. Fuhrmann S. V. Zelik 《Mathematical Methods in the Applied Sciences》2004,27(8):907-930
For the Boussinesq approximation of the equations of coupled heat and fluid flow in a porous medium we show that the corresponding system of partial differential equations possesses a global attractor. We give lower and upper bounds of the Hausdorff dimension of the attractor depending on a physical parameter of the system, namely the Rayleigh number of the flow. Numerical experiments confirm the theoretical findings and raise new questions on the structure of the solutions of the system. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献