全文获取类型
收费全文 | 26211篇 |
免费 | 1963篇 |
国内免费 | 2142篇 |
专业分类
化学 | 6487篇 |
晶体学 | 317篇 |
力学 | 2620篇 |
综合类 | 340篇 |
数学 | 14783篇 |
物理学 | 5769篇 |
出版年
2024年 | 45篇 |
2023年 | 227篇 |
2022年 | 335篇 |
2021年 | 407篇 |
2020年 | 542篇 |
2019年 | 561篇 |
2018年 | 469篇 |
2017年 | 583篇 |
2016年 | 618篇 |
2015年 | 480篇 |
2014年 | 866篇 |
2013年 | 1709篇 |
2012年 | 1136篇 |
2011年 | 1352篇 |
2010年 | 1304篇 |
2009年 | 1928篇 |
2008年 | 2112篇 |
2007年 | 1986篇 |
2006年 | 1725篇 |
2005年 | 1353篇 |
2004年 | 1151篇 |
2003年 | 1215篇 |
2002年 | 1075篇 |
2001年 | 870篇 |
2000年 | 776篇 |
1999年 | 710篇 |
1998年 | 677篇 |
1997年 | 530篇 |
1996年 | 430篇 |
1995年 | 357篇 |
1994年 | 333篇 |
1993年 | 243篇 |
1992年 | 241篇 |
1991年 | 195篇 |
1990年 | 155篇 |
1989年 | 112篇 |
1988年 | 132篇 |
1987年 | 109篇 |
1986年 | 100篇 |
1985年 | 160篇 |
1984年 | 170篇 |
1983年 | 86篇 |
1982年 | 160篇 |
1981年 | 143篇 |
1980年 | 92篇 |
1979年 | 83篇 |
1978年 | 83篇 |
1977年 | 55篇 |
1976年 | 44篇 |
1974年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
Summary Three aspects with respect to the selection of solvents for static coating of capillary columns, i.e. coating speed, occurrence of bumping and solubility of stationary phases are discussed. Hypotheses are proposed in an attempt to explain the observed facts that mixed solvents result in much higher coating speeds than those obtained from pure solvents, that a proper choice of solvents together with a good and uniform deactivitation of the column inner wall is needed to prevent bumping. Stationary phase solubility vs. solvent composition is also briefly discussed. 相似文献
72.
Quan Zheng 《European Polymer Journal》2006,42(4):807-814
Two dendritic reversible addition-fragmentation transfer (RAFT) agents with 8 and 16 terminal dithiobenzoate (DTB) groups on the surface of poly(propylene imine) (PPI) dendrimers (generation 2.0 and 3.0, respectively) were successively prepared, and they were used in the RAFT polymerization of N-isopropylacrylamide (NIPAAM). The polymerization kinetics was confirmed to pseudo-first-order behavior. The 1H NMR and GPC analyses show that the dendrimer-star den (NIPAAM)x (x = 8 or 16) prepared by RAFT method has well-defined structure, controlled molecular weight and low polydispersities (PDI < 1.3). The aqueous solution prepared from dendrimer-star PNIPAAM showed reversible changes in optical properties: transparent below a lower critical solution temperature (LCST) and opaque above the LCST. 相似文献
73.
Tianhu Hao 《Acta Mechanica Sinica》2006,22(5):455-468
This paper presents an exact solution for the transverse interface crack in the plane strain case. The crack is perpendicular to the interface and in one material. The exact complex stress functions are first obtained with some unknown constants. The satisfactions of all boundary conditions are then checked, the condition at infinity is considered and the unknown constants are determined. Further study may focus on the case with different shear moduli and the influence of the large deformation.The English text was polished by Keren Wang. 相似文献
74.
Heat exchange plays an important role in hydrodynamical systems, which is
an interesting topic in theory and application. In this paper, the authors consider the
global stability of steady supersonic Rayleigh flows for the one-dimensional compressible
Euler equations with heat exchange, under the small perturbations of initial and boundary
conditions in a finite rectilinear duct. 相似文献
75.
Jie Wang Yuntian Xing Yang Dai Yingnan Li Wenyan Xiang Jianrong Dai Fei Xu 《Molecules (Basel, Switzerland)》2022,27(13)
Pomacea canaliculata, one of the 100 most destructive invasive species in the world, and it is an important intermediate host of Angiostrongylus cantonensis. The molluscicides in current use are an effective method for controlling snails. However, most molluscicides have no slow-release effect and are toxic to nontarget organisms. Thus, these molluscicides cannot be used on a large scale to effectively act on snails. In this study, gelatin, a safe and nontoxic substance, was combined with sustained-release molluscicide and was found to reduce the toxicity of niclosamide to nontarget organisms. We assessed the effects of gelatin and molluscicide in controlling P. canaliculata snails and eggs. The results demonstrated that the niclosamide retention time with 1.0% and 1.5% gelatin sustained-release agents reached 20 days. Additionally, the mortality rate of P. canaliculata and their eggs increased as the concentration of the niclosamide sustained-release agents increased. The adult mortality rate of P. canaliculata reached 50% after the snails were exposed to gelatin with 0.1 mg/L niclosamide for 48 h. The hatching rate of P. canaliculata was only 28.5% of the normal group after the treatment was applied. The sustained-release molluscicide at this concentration was less toxic to zebrafish, which means that this molluscicide can increase the safety of niclosamide to control P. canaliculata in aquatic environments. In this study, we explored the safety of using niclosamide sustained-release agents with gelatin against P. canaliculata. The results suggest that gelatin is an ideal sustained-release agent that can provide a foundation for subsequent improvements in control of P. canaliculata. 相似文献
76.
LIU Cheng-Shi 《理论物理通讯》2006,45(3):395-397
As an improved version of trial equation method,
a new trial equation method is proposed. Using this method,
abundant new exact traveling
wave solutions to a high-order KdV-type equation are obtained. 相似文献
77.
以N,N-二甲基甲酰胺(DMF)为溶剂,通过改变铜源和表面活性剂,调控反应参数,溶剂热条件下制备了三维十字形、空心及实心的Cu2O球晶。利用XRD、SEM等表征手段,分析探讨了工艺条件变化对Cu2O球晶形貌的影响。研究表明,随着DMF浓度的增大,体系的还原能力增强,Cu+增多,溶液的过饱和度增大,Cu2O晶体集合体形态由晶体结构控制的各向异性与对称性的球晶逐渐向各向同性球晶演变。十二烷基硫酸钠(SDS)、十六烷基三甲基溴化铵(CTAB)、聚乙烯吡咯烷酮(PVP)等表面活性剂有助于降低溶液的过饱和度,增加结晶质的表面扩散能力,有利于规则形态Cu2O晶粒的形成。反应体系中,Cu(Ac)2·H2O水解生成的羧基与DMF中的甲酰基在高温下发生脱羧反应产生CO2气体以及SDS发泡作用产生的气体是形成空心Cu2O球晶的重要原因。 相似文献
78.
La2Zr2O7(LZO)过渡层以其独特的物理化学性质越来越受到人们的关注。本文以乙酰丙酮镧和乙酰丙酮锆为前驱盐,丙酸为溶剂配置前驱液,用化学溶液方法(CSD)在具有立方织构的Ni-5at%W基底上制备了LZO过渡层薄膜。研究了前驱液成分、性质以及退火温度对LZO成相以及取向的影响。用常规XRD和X射线四环衍射仪分析了LZO薄膜的相成分和织构。结果显示,在1050℃下退火可以获得强立方织构的LZO薄膜,其中(222)峰的Phi扫描半高宽值为8.95°;(400)峰的Chi扫描半高宽值为6.8°。用高分辨扫描电子显微镜(FE-SEM)观察到LZO薄膜表面均匀致密,没有裂纹和空洞。 相似文献
79.
An analytical solution is obtained for transient torsional vibration of a finite hollow cylinder with initial axial stress. The cylinder is subjected to dynamic shearing stress at the internal surface and is fixed at the external surface. The basic equations are presented and the solution is obtained by means of Fourier series expansion technique and the separation of variables method. The effects of the initial stress on the natural frequencies and transient torsional responses are presented and discussed. 相似文献
80.