环境温度和湿度对96-Al2O3陶瓷电阻率的影响

采用无压烧结技术,以0.25wt;CaO、1wt;MgO、2.75wt;SiO2为添加剂,在1500 ℃、1550 ℃、1600 ℃下烧结制备了Al2O3陶瓷,分别在150~400 ℃温度范围内和40;~100;的相对湿度环境下,对Al2O3陶瓷的直流电阻率进行检测.样品的相组成和显微结构通过X-ray衍射分析(XRD)和扫描电子显微镜(SEM)表征.结果表明,环境温度由150 ℃上升到400 ℃,样品的直流电阻率降低了约2~2.5个数量级;环境相对湿度从40;上升到100;,样品的直流电阻下降了约3~4个数量级.在相同测试条件下,1500 ℃烧结的Al2O3陶瓷样品由于小的晶粒尺寸和高的孔隙率,从而导致其具有更高的电阻率.     

规划搜索与代数方程求根

规划搜索是从初始状态S。经过中间目标S1,S2……,S1达到目标状态S9=Sf+1的搜索方法,用于求n次代数方程的实根时S0是根模上,下界所划的区间,S0是宽度小于允许误差的有根区间。这样的有根区间上、下限的平均值是根的较准确的近似值。为了使搜索方法可靠,在预处理中用Sturm定理判     

A Series of Novel Pentagonal-Bipyramidal Erbium(III) Complexes with Acyclic Chelating N3O2 Schiff-Base Ligands: Synthesis,Structure, and Magnetism

A series of six seven-coordinate pentagonal-bipyramidal (PBP) erbium complexes, with acyclic pentadentate [N₃O₂] Schiff-base ligands, 2,6-diacetylpyridine bis-(4-methoxybenzoylhydrazone) [H₂DAPMBH], or 2,6-diacethylpyridine bis(salicylhydrazone) [H₄DAPS], and various apical ligands in different charge states were synthesized: [Er(DAPMBH)(C₂H₅OH)Cl] (1); [Er(DAPMBH)(H₂O)Cl]·2C₂H₅OH (2); [Er(DAPMBH)(CH₃OH)Cl] (3); [Er(DAPMBH)(CH₃OH)(N₃)] (4); [(Et₃H)N]⁺[Er(H₂DAPS)Cl₂]⁻ (5); and [(Et₃H)N]⁺[Y₀.₉₅Er₀.₀₅(H₂DAPS)Cl₂]⁻ (6). The physicochemical properties, crystal structures, and the DC and AC magnetic properties of 1–6 were studied. The AC magnetic measurements revealed that most of Compounds 1–6 are field-induced single-molecule magnets, with estimated magnetization energy barriers, U_eff ≈ 16–28 K. The experimental study of the magnetic properties was complemented by theoretical analysis based on ab initio and crystal field calculations. An experimental and theoretical study of the magnetism of 1–6 shows the subtle impact of the type and charge state of the axial ligands on the SMM properties of these complexes.     

中国隐性养老金债务精算模型及其应用研究

根据当前中国养老金发放的实际情况 ,利用生存年金理论 ,改进了国外传统生存年金系数模型 ,得到测算‘老人’养老金债务和‘中人’过渡性养老金债务的精算模型 .利用该模型 ,测算出 2 0 0 0年中国隐性养老金债务规模 ,并对影响养老金债务的因素进行敏感性分析 ,提出缩减隐性养老金债务规模的思路 .     

Electrohydrodynamic behaviors of droplet under a uniform direct current electric field

The electrohydrodynamic behaviors and evolution processes of silicone oil droplet in castor oil under uniform direct current(DC)electric field are visually observed based on a high-speed microscopic platform.Subsequently,the effects of different working conditions,such as electric field strength,droplet size,etc.,on droplet behaviors are roundly discussed.It can be found that there are four droplet behavior modes,including Taylor deformation,typical oblique rotation,periodic oscillation,and fracture,which change with the increase of electric field strength.It is also demonstrated that the degree of flat ellipse deformation gets larger under a stronger electric field.Moreover,both of the stronger electric field and smaller droplet size lead to an increase in the rotation angle of the droplet.     

格子玻尔兹曼法多块网格的交界结构优化研究

基于格子玻尔兹曼方法LBM(Lattice Boltzmann Method)对多块网格方法(Multi-Block)的粗细网格交界结构进行了研究,提出了一种新的优化处理方案。解决了原有网格交界结构存在的三个问题,即两套插值运算造成的程序结构复杂的问题,存储前几个时间步的节点流场数据以备插值运算造成内存浪费的问题和基于时间插值结果进行空间插值计算造成插值误差积累的问题。用一次多点二维空间插值的方式,将原方法的空间和时间双插值,简并成一次空间插值。通过对经典的非定常的圆柱绕流算例和定常的标准顶盖方腔驱动流算例的仿真模拟,验证了交界面处质量、动量及应力的连续性以及网格交界面数据过渡的流畅度,最终验证了改进方法的正确性。数值模拟结果表明,改进后多块算法可实现局部网格细化,进一步推动LBM方法在实际工程问题中的应用。     

化学学历案促进深度学习的发生——化学平衡移动复习课

学历案是关于学习经历或过程的方案，利用学历案构建一个“以学为主、以教促学”的教学模式，改变了教师的主导地位，凸显了学生的主体地位。笔者尝试借助学历案，以花青素为载体，通过生活化的化学实验，将化学平衡常数K作为分析工具，进行证据推理，以外界条件使花青素溶液颜色变化，到花青素的工业合成为明线；以化学平衡移动的本质到化学平衡移动原理的应用为暗线，双线结合，学生自主建构“化学平衡移动”的认知模型，从而促进深度学习的发生。